2,3-Diethylbernsteinsaeurediethylester | 32884-98-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2,3-Diethylbernsteinsaeurediethylester
• 英文别名: 1,2-Diethyl-bernsteinsaeure-diethylester；Diethyl 2,3-diethylsuccinate；diethyl 2,3-diethylbutanedioate
• CAS: 32884-98-3
• 化学式: C₁₂H₂₂O₄
• 分子量: 230.304
• InChiKey: PYQDOTSNFYFMQJ-UHFFFAOYSA-N

物化性质

• 沸点：
  252.6±8.0 °C(Predicted)
• 密度：
  0.982±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,3-Diethylbernsteinsaeurediethylester 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 生成 (+/-)-2,3-diethylsuccinic acid
  参考文献：
  名称：

  Beckwith,A.L.J., Australian Journal of Chemistry, 1960, vol. 13, p. 244 - 255

  摘要：

  DOI：
• 作为产物：
  描述：

  丁酸乙酯 生成 2,3-Diethylbernsteinsaeurediethylester
  参考文献：
  名称：

  锂酯烯醇化物的电化学氧化

  摘要：

  不含活化基团的酯的烯醇锂在低温下的电化学氧化以相当好的产率产生相应的取代琥珀酸酯。苯乙酸乙酯烯醇的电解也产生了氧化二聚体的定量产率，电流效率为 100%。

  DOI：

  10.1246/cl.1975.621

文献信息

• Electrochemical synthesis of compounds of general formula (R¹CH₂·CR²·Y)₂
  作者：M. Chkir、D. Lelandais

  DOI：10.1039/c29710001369

  日期：——

  The anodic oxidation of organic acids, R1CO2H, in the presence of substrates of the type CH2= CR2·Y (Y = CHO, COMe, CO2Et, and CN) leads with good yields to duplication products of general formula (R1·CH2·CR2·Y)2.

  在具有CH2=CR2·Y型底物（Y = CHO、COMe、CO2Et和CN）存在下，有机酸R1CO2H的阳极氧化反应以良好的产率生成通式为(R1·CH2·CR2·Y)2的二聚产物。
• Propylene polymers
  申请人：Morini Giampiero

  公开号：US20050032633A1

  公开（公告）日：2005-02-10

  The present invention relates to a solid catalyst component for the polymerization of olefins CH 2 ═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from substituted succinates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

  本发明涉及一种用于聚合烯烃CH2═CHR（其中R为氢或具有1-12个碳原子的碳氢基团）的固体催化剂组分，包括镁、钛、卤素和从特定公式的取代琥珀酸酯中选择的电子给体。当在聚合烯烃，特别是丙烯的聚合中使用该催化剂组分时，能够以高收率和以高二甲苯不溶性表示的高同构指数给出聚合物。
• Components and catalysts for the polymerization of olefins
  申请人：Basell Poliolefine Italia S.p.A.

  公开号：US06818583B1

  公开（公告）日：2004-11-16

  The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from substituted succinates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

  本发明涉及一种用于聚合烯烃CH2═CHR的固体催化剂组分，其中R为氢或1-12个碳原子的碳氢基团，包括Mg、Ti、卤素和从特定公式的取代琥珀酸酯中选择的电子给体。当用于烯烃的聚合，特别是丙烯的聚合时，所述催化剂组分能够以高收率和高异构指数的形式给出聚合物，其以高二甲苯不溶性表示。
• OLEFIN POLYMERIZATION CATALYST, PROCESS FOR PRODUCING OLEFIN POLYMER, POLYPROPYLENE RESIN COMPOSITION AND ARTICLE COMPRISING THE SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20130109789A1

  公开（公告）日：2013-05-02

  An olefin polymerization catalyst is obtained by bringing the following components (A), (B) and (C) into contact with one another: (A) a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom and a halogen atom; (B) an organoaluminum compound; and (C) a triether represented by formula (I). An olefin polymerization solid catalyst can be provided having a sufficiently high polymerization activity and an ability to produce an olefin polymer with a low content of low-molecular weight components and amorphous components.

  一种烯烃聚合催化剂是通过将以下组分（A）、（B）和（C）彼此接触而获得的：（A）用于烯烃聚合的固体催化剂组分，其中包含钛原子、镁原子和卤素原子；（B）有机铝化合物；以及（C）由式（I）表示的三醚。可以提供具有足够高的聚合活性和能够产生低分子量成分和非晶态成分含量低的烯烃聚合物的固体聚合催化剂。
• SOLID CATALYST COMPONENT AND CATALYST FOR POLYMERIZATION OF OLEFINS, AND PROCESS FOR PRODUCTION OF OLEFIN POLYMERS USING SAME
  申请人：Toho Titanium CO., LTD.

  公开号：EP2360190A1

  公开（公告）日：2011-08-24

  A solid catalyst component for olefin polymerization is produced by causing (a) a solid component that includes magnesium, titanium, a halogen, and an electron donor, (b) an aminosilane compound shown by the following general formula (1), and (c) at least one organosilicon compound selected from an organosilicon compound shown by the following general formula (2-A) and an organosilicon compound shown by the following general formula (2-B) to come in contact with each other. A polymer having high stereoregularity is produced in high yield while achieving a high melt flow rate due to hydrogen by polymerizing an olefin in the presence of a catalyst that includes the solid catalyst component.         R1nSi(NR2R3)4-n     (1)         [CH2=CH-(CH2)1]qSiR44-q     (2-A)         R5Si(OR6)4-s     (2-B)

  一种用于烯烃聚合的固体催化剂组分是通过使(a)一种包括镁、钛、卤素和电子供体的固体组分，(b)如下通式(1)所示的氨基硅烷化合物，和(c)至少一种选自如下通式(2-A)所示的有机硅化合物和如下通式(2-B)所示的有机硅化合物的有机硅化合物相互接触而制得的。在含有固体催化剂组分的催化剂存在下，通过聚合烯烃，可以高产率地生产出具有高立体规整度的聚合物，同时由于氢气的存在，可以达到较高的熔体流动速率。 R1nSi(NR2R3)4-n (1) [CH2=CH-(CH2)1]qSiR44-q (2-A) R5Si(OR6)4-s (2-B)