4,13-dioxo-3,14 dioxa-5,12-diazahexadecane-1,16-diol dimethacrylate | 34100-36-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4,13-dioxo-3,14 dioxa-5,12-diazahexadecane-1,16-diol dimethacrylate
• 英文别名: 2-Propenoic acid, 2-methyl-, 4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl ester；2-[6-[2-(2-methylprop-2-enoyloxy)ethoxycarbonylamino]hexylcarbamoyloxy]ethyl 2-methylprop-2-enoate
• CAS: 34100-36-2
• 化学式: C₂₀H₃₂N₂O₈
• 分子量: 428.483
• InChiKey: PYBWEPXWJPJXAA-UHFFFAOYSA-N

物化性质

• 沸点：
  578.0±45.0 °C(Predicted)
• 密度：
  1.127±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  30
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  129
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,6-己二胺 在 4-二甲氨基吡啶 、 三乙胺 作用下， 反应 24.0h， 生成 4,13-dioxo-3,14 dioxa-5,12-diazahexadecane-1,16-diol dimethacrylate
  参考文献：
  名称：

  Developing non-isocyanate urethane-methacrylate photo-monomers for 3D printing application

  摘要：

  通过非异氰酸酯途径合成脲酯-甲基丙烯酸酯光敏单体，用于柔性生物医用材料的3D打印。

  DOI：

  10.1039/d0ra06388f

文献信息

• Carbamate-methacrylate monomers and their use in dental applications
  申请人：Trujillo-Lemon Marianela

  公开号：US08513326B2

  公开（公告）日：2013-08-20

  The present invention relates, generally, to monomers containing carbamate-methacrylates or derivatives of carbamate-methacrylates, processes for making the monomers, and compositions comprising the monomers. The present invention also relates to methods of using the monomers, such as in dental applications, and in particular, dental restorative resins.

  本发明涉及含有氨基甲酸酯-甲基丙烯酸酯或氨基甲酸酯-甲基丙烯酸酯衍生物的单体，制备该单体的方法以及包含该单体的组合物。本发明还涉及使用该单体的方法，例如在牙科应用中，特别是在牙科修复树脂中的应用。
• CARBAMATE-METHACRYLATE MONOMERS AND THEIR USE IN DENTAL APPLICATIONS
  申请人：Trujillo-Lemon Marianela

  公开号：US20100307378A1

  公开（公告）日：2010-12-09

  The present invention relates, generally, to monomers containing carbamate-methacrylates or derivatives of carbamate-methacrylates, processes for making the monomers, and compositions comprising the monomers. The present invention also relates to methods of using the monomers, such as in dental applications, and in particular, dental restorative resins.

  本发明涉及含有碳酸酯-甲基丙烯酸酯或碳酸酯-甲基丙烯酸酯衍生物的单体，制备该单体的方法以及包含该单体的组合物。本发明还涉及使用该单体的方法，例如在牙科应用中，特别是在牙科修复树脂中的应用。
• HIGH STRENGTH DENTAL MATERIAL
  申请人：SUN BENJAMIN J.

  公开号：US20120129973A1

  公开（公告）日：2012-05-24

  The invention provides a high strength dental composition including polymerizable dental resins. The dental composition is useful as restorative material and for making various dental devices, such as artificial teeth, crowns and bridges of high strength dental polymeric material.

  本发明提供了一种高强度的牙科组合物，包括可聚合的牙科树脂。该牙科组合物可用作修复材料，并用于制造各种高强度牙科聚合材料的人工牙齿，冠和桥。
• Three-dimensional fabricating material systems and methods for producing layered dental products
  申请人：DENTSPLY SIRONA Inc.

  公开号：US10299896B2

  公开（公告）日：2019-05-28

  This invention designs and builds multiple layers (two layers or more) of various dental devices, specifically denture base or denture, where printed multiple layered denture base with teeth cavities to receive artificial denture tooth materials to form final dental devices, such as partial and full dentures. It can also print denture teeth. This invention also designs and prints multiple layers (two layers or more) of denture base with artificial denture teeth to form final dental devices, such as partial and full dentures. A method for manufacturing a layered denture is provided. The invention provides a multiple layered denture base materials for printing a denture base. The invention also provides a multiple layered denture tooth materials for printing artificial denture teeth. Highly shape adjustable or shape memory polymer layer(s) may be used in these multiple layered denture base forms. Different layer of material has different mechanical and physical properties to meet different need, which provide added benefits to the patients, dental professional and dental laboratory.

  本发明设计和制造多层（两层或更多层）的各种牙科装置，特别是义齿基托或义齿，其中打印的多层义齿基托带有齿腔，可接收人工义齿牙齿材料，形成最终的牙科装置，如局部义齿和全口义齿。它还可以打印假牙。本发明还可以设计和打印带有人工义齿的多层（两层或更多层）义齿基托，以形成最终的牙科装置，如局部义齿和全口义齿。本发明提供了一种制造分层义齿的方法。本发明提供了一种用于印刷义齿基托的多层义齿基托材料。本发明还提供了一种多层义齿牙材料，用于印刷人工义齿牙。高度形状可调或形状记忆聚合物层可用于这些多层义齿基托形式中。不同的材料层具有不同的机械和物理特性，以满足不同的需求，从而为患者、牙科专业人员和牙科实验室带来更多的益处。
• High strength three dimensional fabricating material systems and methods for producing dental products
  申请人：DENTSPLY SIRONA Inc.

  公开号：US10849724B2

  公开（公告）日：2020-12-01

  This invention relates to printable high strength/toughness polymerizable material systems for making dental products such as artificial teeth, dentures, splints, veneers, inlays, onlays, orthodontic appliances, aligners, copings, frame patterns, crowns and bridges and the like. A DLP, stereolithography, modified or their modification and combination based printer is used to cure polymerizable material in several different methods of this invention to build-up the object. The resulting three-dimensional object has good dimensional stability.

  本发明涉及可打印的高强度/韧性可聚合材料系统，用于制造牙科产品，如人造牙、假牙、夹板、贴面、嵌体、镶嵌体、正畸器械、矫正器、盖板、框架图案、牙冠和牙桥等。在本发明的几种不同方法中，使用基于 DLP、立体光刻、改良或它们的改良和组合的打印机来固化可聚合材料，以构建物体。由此产生的三维物体具有良好的尺寸稳定性。

表征谱图