methyl 2-methyl-3-phenoxypropanoate | 138842-47-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: methyl 2-methyl-3-phenoxypropanoate
• 英文别名: β-phenoxy-isobutyric acid methyl ester；β-Phenoxy-isobuttersaeure-methylester
• CAS: 138842-47-4
• 化学式: C₁₁H₁₄O₃
• 分子量: 194.23
• InChiKey: YVILSYSFITYLEI-UHFFFAOYSA-N

物化性质

• 沸点：
  281.1±23.0 °C(Predicted)
• 密度：
  1.059±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  甲基丙烯酸甲酯 、 苯酚 在 potassium phenolate 作用下， 生成 methyl 2-methyl-3-phenoxypropanoate
  参考文献：
  名称：

  Bieber, Annales de Chimie (Cachan, France), 1954, vol. <12>9, p. 674,676

  摘要：

  DOI：

文献信息

• Selective Mono- and Bis(alkoxycarbonylation)s of Olefins Catalyzed by Palladium in the Presence of Cu(I) or Cu(II) Chloride under Remarkably Mild Conditions. Application to the Synthesis of γ-Butyrolactone Derivatives
  作者：Shiho Toda、Masanori Miyamoto、Hideki Kinoshita、Katsuhiko Inomata

  DOI：10.1246/bcsj.64.3600

  日期：1991.12

  Palladium-catalyzed mono- and bis(alkoxycarbonylation)s of olefins were controlled by the use of copper(II) and copper(1) chloride, respectively, in alcohol under normal pressure of carbon monoxide and oxygen at room temperature without any other additives. 3-Buten-1-ols gave the corresponding γ-butyrolactones and 2-oxotetrahydrofuran-3-acetic acid esters, respectively, in high yields.

  在室温下、正常压力的二氧化碳和氧气环境下，使用铜(II)和铜(I)氯化物分别控制钯催化的单和双(烷氧基羰基化)反应，无需其他添加剂即可使烯烃产生反应。3-丁烯-1-醇则分别高效地生成相应的γ-丁酰内酯和2-氧杂四氢呋喃-3-乙酸酯。
• CURABLE COMPOSITION AND PROCESS FOR PRODUCING CURED COATING
  申请人：KUNITA Kazuto

  公开号：US20080200581A1

  公开（公告）日：2008-08-21

  A process for producing a cured coating is provided that includes a step of forming on a substrate a layer of a curable composition that includes at least one compound represented by Formula (I) and a step of curing the layer of the curable composition by irradiating with an electron beam. In Formula (I), Q 1 denotes a cyano group or a —COX 2 group, X 1 denotes a hydrogen atom, organic residue, or polymer chain bonded to carbon atom C A via a heteroatom, or a halogen atom, X 2 denotes a hydrogen atom, organic residue, or polymer chain bonded to the carbonyl group via a heteroatom, or a halogen atom, R a and R b independently denote a hydrogen atom, a halogen atom, a cyano group, or an organic residue, and X 1 and X 2 , R a and R b , and X 1 and R a or R b may be bonded to each other to form a cyclic structure. There is also provided an electron beam-curable composition that includes a compound represented by Formula (I).
• US8008366B2
  申请人：——

  公开号：US8008366B2

  公开（公告）日：2011-08-30