N-溴-4-甲基苯甲酰胺 | 33322-33-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N-溴-4-甲基苯甲酰胺
• 英文名称: 4-methyl-benzoic acid bromoamide
• 英文别名: 4-Methyl-benzoesaeure-bromamid；N-bromo-4-methyl-benzamide；N-Bromo-p-methylbenzamid；N-Bromo-4-methylbenzamide
• CAS: 33322-33-7
• 化学式: C₈H₈BrNO
• 分子量: 214.062
• InChiKey: VEOMYXPLAPITHG-UHFFFAOYSA-N

物化性质

• 熔点：
  131-133 °C (decomp)
• 密度：
  1.499±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-溴-4-甲基苯甲酰胺 在 二氯化硫 作用下， 以 苯 为溶剂， 生成 N-p-Toluoyl-dichlorsulfimid
  参考文献：
  名称：

  Borovikova,G.S. et al., Journal of Organic Chemistry USSR (English Translation), 1979, vol. 15, p. 2245 - 2249

  摘要：

  DOI：
• 作为产物：
  描述：

  对甲苯酰胺 在 sodium bromite 作用下， 以 溶剂黄146 为溶剂， 反应 4.0h， 以75%的产率得到N-溴-4-甲基苯甲酰胺
  参考文献：
  名称：

  A CONVENIENT SYNTHESIS OFN-BROMOAMIDES BY USE OF SODIUM BROMITE

  摘要：

  在温和条件下，脂肪族和芳香族酰胺在乙酸中与水溶液的亚溴酸钠（NaBrO2）反应，能够以相当不错的收率得到N-溴代酰胺。

  DOI：

  10.1246/cl.1984.2045

文献信息

• A CONVENIENT SYNTHESIS OF<i>N</i>-BROMOAMIDES BY USE OF SODIUM BROMITE
  作者：Shoji Kajigaeshi、Takashi Nakagawa、Shizuo Fujisaki

  DOI：10.1246/cl.1984.2045

  日期：1984.12.5

  Reaction of aliphatic and aromatic amides in acetic acid with aqueous sodium bromite (NaBrO2) under mild conditions gave N-bromoamides in fairly good yields.

  在温和条件下，脂肪族和芳香族酰胺在乙酸中与水溶液的亚溴酸钠（NaBrO2）反应，能够以相当不错的收率得到N-溴代酰胺。
• Use of N-haloamides as photoinitiators for free-radical polymerizations
  申请人：MINISTERO DELL' UNIVERSITA' E DELLA RICERCA SCIENTIFICA E TECNOLOGICA

  公开号：EP0458197A2

  公开（公告）日：1991-11-27

  Disclosed are N-haloamide photoinitiator compositions for free-radical polymerizations, comprising at least one compound of general formula (I):         R - CO - NHX   (I) wherein Rrepresents an optionally substituted alkyl, cycloalkyl, aryl, alkyl-aryl or aryl-alkyl or heterocyclic group and Xis Cl, Br or I.

  公开了用于自由基聚合的 N-卤酰胺光引发剂组合物，其中包含至少一种通式 (I) 的化合物： R - CO - NHX (I) 其中 R 代表任选取代的烷基、环烷基、芳基、烷基芳基或芳基烷基或杂环基团，以及 Xis Cl、Br 或 I。
• Descriptive anatomy of the femoral portion of the iliopsoas muscle. Anatomical basis of anterior snapping of the hip
  作者：L. Tatu、B. Parratte、F. Vuillier、M. Diop、G. Monnier

  DOI：10.1007/s00276-001-0371-9

  日期：2002.4

  Anterior hip snapping is a rare clinical observation. The physiopathological hypothesis currently held is a sudden slip of the iliopsoas tendon over the iliopectineal eminence. For symptomatic cases, a surgical technique is proposed. The aim of this work is to describe the anatomy of the femoral portion of the iliopsoas, which is the target of surgery. We have studied, through dissection of embalmed cadavers, the different components of the musculotendinous complex forming the femoral portion of the muscle and the gliding apparatus associated with it. The psoas major tendon exhibited a characteristic rotation. The iliacus tendon, more lateral, received the most medial iliacus muscular fibers, then fused with the main tendon. The most lateral fibers, starting in particular from the ventral portion of the iliac crest, ended up without any tendon on the anterior surface of the lesser trochanter and in the infratrochanteric region. The most inferior muscular fibers of the iliacus, starting from the arcuate line, joined the principal tendon of the psoas major passing around it by its ventromedial surface. An ilio-infratrochanteric muscular bundle was observed, in a deeper position, under the iliopsoas tendon; it arose from the interspinous incisure and on the anterior inferior iliac spine, ran along the anterolateral edge of the iliacus and inserted without any tendon onto the anterior surface of the lesser trochanter of the femur and in the infratrochanteric area. The iliopectineal bursa was studied on horizontal cross sections of a frozen pelvis and on 5 of the non-frozen preparations after dividing the iliopsoas tendon. The iliopectineal bursa had the shape of a 5 to 6-cm high and 3-cm wide cavity; in its upper part, it was divided into 2 compartments: a medial compartment for the main tendon and a lateral compartment for the accessory tendon.
• Facile conversion of amides to the acids and/or anhydrides using dinitrogen tetroxide
  作者：Hae Kim Yong、Kim Kweon、Jun Park Young

  DOI：10.1016/s0040-4039(00)97498-7

  日期：1990.1
• BOROVIKOVA G. S.; LEVCHENKO E. S.; BOROVIK E. I., ZH. ORGAN. XIMII, 1979, 15, HO 12, 2485-2490
  作者：BOROVIKOVA G. S.、 LEVCHENKO E. S.、 BOROVIK E. I.

  DOI：——

  日期：——