2-(1-甲乙基)-3-恶唑啉乙醇 | 28770-01-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 中文名称: 2-(1-甲乙基)-3-恶唑啉乙醇
• 英文名称: 2-isopropyl-3-hydroxyethyl-1,3-oxazolidine
• 英文别名: 3-Oxazolidineethanol, 2-(1-methylethyl)-；2-(2-propan-2-yl-1,3-oxazolidin-3-yl)ethanol
• CAS: 28770-01-6
• 化学式: C₈H₁₇NO₂
• 分子量: 159.228
• InChiKey: DZARITHRMKPIQB-UHFFFAOYSA-N

物化性质

• 沸点：
  241.8±25.0 °C(Predicted)
• 密度：
  1.007±0.06 g/cm3(Predicted)
• LogP：
  0.06 at 25℃
• 物理描述：
  Liquid; OtherSolid

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  32.7
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2934999090
• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为反应物：
  描述：

  2-(1-甲乙基)-3-恶唑啉乙醇 、 碳酸二甲酯 在 sodium methylate 作用下， 以94 g的产率得到bis[2-(2-isopropyloxazolidin-3-ethyl)] carbonate
  参考文献：
  名称：

  一种双噁唑烷潜固化剂及其制备方法

  摘要：

  一种双噁唑烷潜固化剂及其制备方法，其由符合通式（II）的3‑羟乙基‑1,3‑噁唑烷和二元酯酯交换反应所得到，其特点是分子结构中含有两个噁唑烷环，且噁唑烷取代基上的活泼羟基被隐藏，密封条件下储存稳定性好；开封使用时遇湿气生成更多的活泼基团，进而与异氰酸酯基发生扩链交联反应，形成三维网状结构。该类双噁唑烷潜固化剂应用于单组分聚氨酯材料中，不仅可以从源头上避免体系在固化过程中产生气泡，还可大幅提高聚氨酯制品的使用性能。

  公开号：

  CN115353494A
• 作为产物：
  描述：

  二乙醇胺 、 异丁醛 以 环己烷 为溶剂， 以210 mg的产率得到2-(1-甲乙基)-3-恶唑啉乙醇
  参考文献：
  名称：

  一种双噁唑烷潜固化剂及其制备方法

  摘要：

  一种双噁唑烷潜固化剂及其制备方法，其由符合通式（II）的3‑羟乙基‑1,3‑噁唑烷和二元酯酯交换反应所得到，其特点是分子结构中含有两个噁唑烷环，且噁唑烷取代基上的活泼羟基被隐藏，密封条件下储存稳定性好；开封使用时遇湿气生成更多的活泼基团，进而与异氰酸酯基发生扩链交联反应，形成三维网状结构。该类双噁唑烷潜固化剂应用于单组分聚氨酯材料中，不仅可以从源头上避免体系在固化过程中产生气泡，还可大幅提高聚氨酯制品的使用性能。

  公开号：

  CN115353494A

文献信息

• Aldehydes containing hydroxl groups
  申请人：Burckhardt Urs

  公开号：US08389772B2

  公开（公告）日：2013-03-05

  The present invention relates to aldehydes of the formula (I) which contain tertiary amino groups and at least one hydroxyl group. Aldehydes of this kind can be utilized broadly. Aldehydes of particular advantage can be incorporated into a polymer, and find use as curing agents and/or catalysts. Preferably they find use in adhesives and sealants.

  本发明涉及通式(I)的醛类，其含有叔氨基团和至少一个羟基团。此类醛类具有广泛的应用。特别有利的醛类可被并入聚合物中，用作固化剂和/或催化剂。它们尤其适用于粘合剂和密封剂。
• LATENT CURING AGENT AND CURABLE POLYURETHANE COMPOSITION
  申请人：SIKA TECHNOLOGY AG

  公开号：US20200140599A1

  公开（公告）日：2020-05-07

  A compound of formula (I) having advantageous properties when used as a latent curing agent for compositions containing isocyanate groups, and to compositions containing the compound of formula (I). The compound of formula (I) is odourless, is liquid and has comparatively low viscosity at room temperature and is stable in storage together with isocyanates. It makes possible odourless single-component polyurethane compositions which have good stability in storage, do not produce bubbles when cured in the presence of moisture, and cause no problematic odour emissions, giving a cured elastic material having good mechanical properties, good heat stability, a surprisingly non-adhesive surface and little tendency towards plasticizer migration.

  具有优越特性的化合物，其化学式为（I），在含异氰酸基团的组合物中作为潜在固化剂使用时具有优势，并且包含化合物（I）的组合物。化合物的化学式（I）无味，液态，在室温下粘度相对较低，在与异氰酸酯一起储存时稳定。它使得可能制备无味的单组分聚氨酯组合物，在储存中具有良好稳定性，在存在湿气时固化时不产生气泡，并且不会产生有问题的气味排放，从而获得具有良好机械性能、良好热稳定性、惊人的非粘附表面和少量塑化剂迁移倾向的固化弹性材料。
• Urethane oxazolidines
  申请人：Bayer Aktiengesellschaft

  公开号：US04002601A1

  公开（公告）日：1977-01-11

  This invention relates to compounds corresponding to the following general formula: ##STR1## wherein M REPRESENTS AN INTEGER OF FROM 1 TO 6; N represents an integer of from 0 to 4; R.sub.1 represents an aliphatic hydrocarbon group containing from 2 to 6 carbon atoms; R.sub.2 and R.sub.3 which may be the same or different, each represents hydrogen, an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, a cycloaliphatic hydrocarbon group containing from 5 to 7 carbon atoms, or an aromatic hydrocarbon group containing from 6 to 10 carbon atoms, or when taken together with the ring carbon atom they may form a 5- or 6-membered cycloaliphatic hydrocarbon ring; R.sub.4 represents an aliphatic hydrocarbon group containing from 2 to 6 carbon atoms; and R.sub.5 represents a residue of the type which may be obtained by removing the isocyanate groups from an organic (n + m)-valent polyisocyanate. The invention also relates to a process for preparing urethanes which contain oxazolidine groups and optionally isocyanate groups, characterized in that N-hydroxyalkyl-oxazolidines are reacted with organic polyisocyanates at an OH/NCO ratio of from 1:1 to 1:6.

  本发明涉及与以下一般式相对应的化合物：##STR1## 其中，M代表1至6的整数；N代表0至4的整数；R.sub.1代表含有2至6个碳原子的脂肪烃基；R.sub.2和R.sub.3可以相同也可以不同，分别代表氢、含有1至4个碳原子的脂肪烃基、含有5至7个碳原子的环脂肪烃基或含有6至10个碳原子的芳香烃基，或者与环上的碳原子结合形成5-或6-成员的环脂肪烃环；R.sub.4代表含有2至6个碳原子的脂肪烃基；R.sub.5代表从有机（n+m）-价多异氰酸酯中去除异氰酸基后得到的残基。本发明还涉及一种制备含有噁唑烷基和可选异氰酸酯基的脲的方法，其特征在于在OH/NCO比为1:1至1:6的条件下，将N-羟基烷基噁唑烷与有机多异氰酸酯反应。
• ONE-COMPONENT TYPE POLYURETHANE RESIN COMPOSITION FOR PREVENTING DETACHMENT OF CONCRETE PIECES AND TILES AND METHOD FOR PREVENTING DETACHMENT OF CONCRETE PIECES AND TILES USING SAME
  申请人：Dyflex Corporation

  公开号：US20130101744A1

  公开（公告）日：2013-04-25

  A one-component type polyurethane resin composition for preventing detachment of concrete pieces and tiles containing an isocyanate group-containing urethane prepolymer (A) and a thixotropy-imparting agent (B), and a method for forming a reinforcing layer on a surface of a concrete structure or tiled wall containing a resin coated film composed thereof, in order to provide a one-component type polyurethane resin composition for preventing detachment of concrete pieces and tiles, which has improved workability by being able to be applied with a trowel or brush, forms a transparent resin coated film after reactive curing that has improved weather resistance without applying a top coat, facilitates diagnosis of deterioration of concrete by being carried out visually during maintenance of concrete structures, is able to maintain the existing appearance of the tiled exteriors of buildings and other structures and eliminates dispersion to surrounding areas during application.

  一种单组分型聚氨酯树脂组合物，用于防止混凝土块和瓷砖的脱落，其中包含含有异氰酸基的聚氨酯预聚体（A）和增稠剂（B），以及一种在混凝土结构表面或瓷砖墙面形成加固层的方法，该方法包括使用由该组合物组成的树脂涂层膜，以提供一种单组分型聚氨酯树脂组合物，用于防止混凝土块和瓷砖的脱落，具有改善的可操作性，可以使用抹子或刷子施工，反应固化后形成透明的树脂涂层膜，具有改善的耐候性，无需施加面漆，可以在混凝土结构维护期间进行目视诊断混凝土的状况，能够保持建筑物和其他结构的瓷砖外观，施工时不会对周围环境造成扩散。
• Hydrocurable compositions containing epoxy and oxazolidine or oxazine groups, their use as or in coating and impregnating compositions and polymer containing such groups
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0033515A1

  公开（公告）日：1981-08-12

  Hydrocurable compositions are provided containing a plurality of epoxy groups and oxazolidine or oxazine groups which are storage stable for at least one month under anhydrous conditions. This stability is achieved by selecting oxazolidines or oxazines in which the 2-position carbon atom in the ring is free of hydrogen atoms and substituted by alkyl groups or an alkylene group which forms a hydrocarbon ring with that carbon atom. Upon exposure to moisture the oxa-groups ring open for reaction with the epoxy groups. The groups may be in the same or different components and thus the composition may comprise polyepoxide and a compound or polymer containing a plurality of the oxa-groups or a polymer containing both classes of groups. The latter polymer is one embodiment of the invention. The compositions may be used for coating, impregnating and adhesive purposes.

  本发明提供了含有多个环氧基团和噁唑烷或噁嗪基团的水固化组合物，这些组合物在无水条件下至少可稳定贮存一个月。这种稳定性是通过选择环中 2 位碳原子不含氢原子并被烷基或与该碳原子形成烃环的亚烷基取代的噁唑烷或噁嗪来实现的。当暴露在潮湿环境中时，羰基环会打开，与环氧基团发生反应。这些基团可以是相同或不同的组分，因此组合物可以包括聚环氧化物和含有多个氧杂基团的化合物或聚合物，或含有这两类基团的聚合物。后一种聚合物是本发明的一个实施方案。组合物可用于涂层、浸渍和粘合。