coniferyl alcohol dimethyl ether | 84782-37-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: coniferyl alcohol dimethyl ether
• 英文别名: 3,4-dimethoxycinnamylalcohol methyl ether；trans-1,2-dimethoxy-4-(3'-methoxy-1'-propenyl)benzene；(E)-1,2-dimethoxy-4-(3-methoxyprop-1-enyl)benzene；1,2-Dimethoxy-4-(3-methoxy-1-propenyl)benzene；1,2-dimethoxy-4-[(E)-3-methoxyprop-1-enyl]benzene
• CAS: 84782-37-6
• 化学式: C₁₂H₁₆O₃
• 分子量: 208.257
• InChiKey: LRQNQHSEOIQDTL-SNAWJCMRSA-N

物化性质

• 沸点：
  321.9±37.0 °C(Predicted)
• 密度：
  1.034±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-甲基芸香碱 、 coniferyl alcohol dimethyl ether 以 乙腈 为溶剂， 反应 72.0h， 以11%的产率得到melicodenine D
  参考文献：
  名称：

  ico烯C，D和E的合成

  摘要：

  描述了通过分子间的[2 + 2]环加成反应合成不寻常的环丁烷-喹啉酮生物碱ico烯C，D和E。

  DOI：

  10.1016/j.tetlet.2012.10.087
• 作为产物：
  描述：

  ethyl (E)-3,4-dimethoxycinnamate 在 sodium hydride 、 二异丁基氢化铝 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 20.0h， 生成 coniferyl alcohol dimethyl ether
  参考文献：
  名称：

  ico烯C，D和E的合成

  摘要：

  描述了通过分子间的[2 + 2]环加成反应合成不寻常的环丁烷-喹啉酮生物碱ico烯C，D和E。

  DOI：

  10.1016/j.tetlet.2012.10.087

文献信息

• Novel synthetic method for N-allylcarbamates from allyl ethers using chlorosulfonyl isocyanate
  作者：Ji Deuk Kim、Min Hee Lee、Min Jung Lee、Young Hoon Jung

  DOI：10.1016/s0040-4039(00)00776-0

  日期：2000.6

  Various allyl ethers were converted into the corresponding N-allylcarbamates using chlorosulfonyl isocyanate (CSI) via the stable allylic carbocation rather than β-lactam through [2+2] cycloaddition. The reaction of cinnamyl methyl ether with CSI afforded only methyl N-cinnamylcarbamate at 0°C, but at 20°C, it produced a mixture of methyl N-cinnamylcarbamate and methyl N-(1-phenylprop-2-enyl)carbamate

  使用氯磺酰基异氰酸酯（CSI）通过稳定的烯丙基碳正离子化而不是β-内酰胺通过[2 + 2]环加成将各种烯丙基醚转化为相应的N-烯丙基氨基甲酸酯。肉桂基甲基醚与CSI的反应在0°C时仅提供N-肉桂酸氨基甲酸酯，但在20°C时，生成了N-（肉桂基氨基甲酸甲酯）和N-（1-苯基丙-2-烯基）氨基甲酸甲酯的混合物。比例为2.7：1。
• New phenolic ethers from essential oils of some rutaceae
  作者：William E. Campbell、Peter George

  DOI：10.1016/0031-9422(82)80169-6

  日期：1982.1

  Abstract Two phenolic ethers were isolated from the essential oils of some Agathosma species. Structures elucidated by spectral analysis and synthesis were

  摘要 从一些Agathosma 物种的精油中分离出两种酚醚。通过光谱分析和合成阐明的结构是
• METHOD TO UPGRADE BIO-OILS TO FUEL AND BIO-CRUDE
  申请人：Steele Philip H.

  公开号：US20110192072A1

  公开（公告）日：2011-08-11

  This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.
• US8603199B2
  申请人：——

  公开号：US8603199B2

  公开（公告）日：2013-12-10
• [EN] METHOD TO UPGRADE BIO-OILS TO FUEL AND BIO-CRUDE<br/>[FR] PROCÉDÉ DE VALORISATION D'HUILES BIO EN CARBURANT ET HUILE BRUTE BIO
  申请人：UNIV MISSISSIPPI STATE

  公开号：WO2011041732A2

  公开（公告）日：2011-04-07

  This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.