2,3,6,7-Tetrakis-octyloxy-1,5-bis-[2-(tetrahydro-pyran-2-yloxy)-ethoxy]-anthraquinone | 344741-11-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3,6,7-Tetrakis-octyloxy-1,5-bis-[2-(tetrahydro-pyran-2-yloxy)-ethoxy]-anthraquinone
• 英文别名: 2,3,6,7-Tetraoctoxy-1,5-bis[2-(oxan-2-yloxy)ethoxy]anthracene-9,10-dione；2,3,6,7-tetraoctoxy-1,5-bis[2-(oxan-2-yloxy)ethoxy]anthracene-9,10-dione
• CAS: 344741-11-3
• 化学式: C₆₀H₉₆O₁₂
• 分子量: 1009.42
• InChiKey: CBGAAIILLWOLDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.8
• 重原子数：
  72
• 可旋转键数：
  42
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  126
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  2,3,6,7-Tetrakis-octyloxy-1,5-bis-[2-(tetrahydro-pyran-2-yloxy)-ethoxy]-anthraquinone 在 4-甲基苯磺酸吡啶 作用下， 以 甲醇 为溶剂， 生成 1,5-Bis-(2-hydroxy-ethoxy)-2,3,6,7-tetrakis-octyloxy-anthraquinone
  参考文献：
  名称：

  Synthesis and Mesomorphic Properties of Some Anthraquinone Derivatives: New Difunctionalised Discotic Monomers

  摘要：

  Some new 9,10-anthraquinone (rufigallol) derivatives have been prepared and their mesomorphic properties have been studied. The unsymmetrically substituted tetrahydropyranyloxy-ethers (THP-ethers), exhibited columnar mesomorphism at fairly low temperatures and the xray studies carried out for one of the homologues confirmed the hexagonal nature of the mesophase. The deprotected derivatives of these THP-ethers, also form columnar mesophases. All these derivatives are very good candidates for polymerisation studies.

  DOI：

  10.1080/10587250008025232
• 作为产物：
  描述：

  六羟基蒽醌 在 sodium hydroxide 、 四丁基溴化铵 、 potassium carbonate 、 potassium iodide 作用下， 以 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 反应 0.25h， 生成 2,3,6,7-Tetrakis-octyloxy-1,5-bis-[2-(tetrahydro-pyran-2-yloxy)-ethoxy]-anthraquinone
  参考文献：
  名称：

  Synthesis and Mesomorphic Properties of Some Anthraquinone Derivatives: New Difunctionalised Discotic Monomers

  摘要：

  Some new 9,10-anthraquinone (rufigallol) derivatives have been prepared and their mesomorphic properties have been studied. The unsymmetrically substituted tetrahydropyranyloxy-ethers (THP-ethers), exhibited columnar mesomorphism at fairly low temperatures and the xray studies carried out for one of the homologues confirmed the hexagonal nature of the mesophase. The deprotected derivatives of these THP-ethers, also form columnar mesophases. All these derivatives are very good candidates for polymerisation studies.

  DOI：

  10.1080/10587250008025232

文献信息

• Synthesis and Mesomorphic Properties of Some Anthraquinone Derivatives: New Difunctionalised Discotic Monomers
  作者：Veena Prasad、D. S. Shankar Rao

  DOI：10.1080/10587250008025232

  日期：2000.10.1

  Some new 9,10-anthraquinone (rufigallol) derivatives have been prepared and their mesomorphic properties have been studied. The unsymmetrically substituted tetrahydropyranyloxy-ethers (THP-ethers), exhibited columnar mesomorphism at fairly low temperatures and the xray studies carried out for one of the homologues confirmed the hexagonal nature of the mesophase. The deprotected derivatives of these THP-ethers, also form columnar mesophases. All these derivatives are very good candidates for polymerisation studies.