2-氨基-1-羟基蒽醌 | 568-99-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 2-氨基-1-羟基蒽醌
• 英文名称: 2-amino-1-hydroxyanthracene-9,10-dione
• 英文别名: 2-amino-1-hydroxyanthraquinone；1-Hydroxy-2-amino-anthrachinon；2-Amino-1-hydroxy-anthrachinon；2-Amino-erythrooxyanthrachinon；2-amino-1-hydroxy-9,10-anthracenedione；β-Alizarinamid；2-Amino-1-hydroxy-anthraquinone
• CAS: 568-99-0
• 化学式: C₁₄H₉NO₃
• 分子量: 239.23
• InChiKey: WBBFBHOZKCHJHN-UHFFFAOYSA-N

物化性质

• 熔点：
  258°C
• 沸点：
  381.88°C (rough estimate)
• 密度：
  1.2326 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.4
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2922509090

反应信息

• 作为反应物：
  描述：

  2-氨基-1-羟基蒽醌 在 硫酸 、 potassium iodide 、 sodium nitrite 作用下， 生成 1-hydroxy-2-iodoanthraquinone
  参考文献：
  名称：

  Galevskaya, T. P.; Moroz, A. A.; Myasnikova, R. N., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 2, p. 358 - 362

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二羟基蒽醌 在 sodium hydroxide 、 氨 作用下， 生成 2-氨基-1-羟基蒽醌
  参考文献：
  名称：

  Scholl; Parthey, Chemische Berichte, 1906, vol. 39, p. 1201

  摘要：

  DOI：

文献信息

• Selective colorimetric sensor for cyanide anion based on 1-hydroxyanthraquinone
  作者：Timofey P. Martyanov、Alexandra A. Kudrevatykh、Evgeny N. Ushakov、Denis V. Korchagin、Ilia V. Sulimenkov、Sergey G. Vasil'ev、Sergey P. Gromov、Lyubov S. Klimenko

  DOI：10.1016/j.tet.2021.132312

  日期：2021.7

  The article addresses the synthesis, structure and properties of 2-benzoylamino-1-hydroxyanthraquinone (1a), which can function as a selective colorimetric sensor for the cyanide anion in aqueous media. Compound 1a was prepared in two simple steps in good yield and its structure was confirmed by X-ray diffraction analysis. UV–Vis and NMR spectroscopy, mass spectrometry and quantum chemistry studies

  该文章讨论了 2-苯甲酰氨基-1-羟基蒽醌 ( 1a )的合成、结构和性质，它可以作为水性介质中氰化物阴离子的选择性比色传感器。通过两个简单的步骤以良好的收率制备了化合物1a，并通过 X 射线衍射分析证实了其结构。UV-Vis 和 NMR 光谱、质谱和量子化学研究表明，在 MeCN-H 2 O 混合物 (95:5, v/v) 中，氰化物使蒽醌的羟基电离，从而产生强烈的红移效应。氰化物阴离子与1a的缔合常数测得为 10 4.88  M –1; 检测限约为 0.22 μM。由于酰胺氢原子与离子化羟基的氧原子之间的氢键，蒽醌核心的2位苯甲酰氨基的存在对1a的阴离子形式具有稳定作用。
• Selective photoalkylamination and photohydroxylation of aminoanthraquinones and their N-acylated derivatives
  作者：Katsuhira Yoshida、Masahiro Hikasa、Katsutoshi Ishii、Hisa Kadota、Yoshio Yamashita

  DOI：10.1039/c39860000758

  日期：——

  The selective introduction of hydroxy and Alkylamino groups into the anthraquinone nucleus was achieved by the photochemical reaction of some aminoanthraquinones and their N-acylated derivatives with alkylamines under aerobic conditions.

  通过在好氧条件下一些氨基蒽醌及其N-酰化衍生物与烷基胺的光化学反应，将羟基和烷基氨基选择性引入蒽醌核中。
• ELECTRON TRANSPORT MATERIAL, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
  申请人：FUJI XEROX CO., LTD.

  公开号：US20160085164A1

  公开（公告）日：2016-03-24

  Provided is an electron transport material represented by formula (1): wherein X represents an oxygen atom or ═C(CN) 2 ; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, an alkoxy group, an aryl group, or an aralkyl group; R 8 , R 9 , and R 10 each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, an aralkyl group, an aryl group, —R 11 —O—R 12 , or —R 13 —CO—O—R 14 ; R 11 represents a linear or branched alkylene group; R 12 represents a linear or branched alkyl group; R 13 represents a single bond or a linear or branched alkylene group; and R 14 represents a linear or branched alkyl group, an aryl group, or an aralkyl group, provided that at least two or more groups of R 8 , R 9 , and R 10 represent a group other than a hydrogen atom.

  提供的是一种由公式（1）表示的电子传输材料：其中X代表氧原子或═C（CN）2；R1、R2、R3、R4、R5、R6和R7分别独立地表示氢原子、卤素原子、直链或支链烷基、烷氧基、芳基或芳基烷基；R8、R9和R10分别独立地表示氢原子、卤素原子、直链或支链烷基、芳基烷基、芳基、—R11—O—R12或—R13—CO—O—R14；R11表示直链或支链烷基；R12表示直链或支链烷基；R13表示单键或直链或支链烷基；R14表示直链或支链烷基、芳基或芳基烷基，但至少有两个或更多的R8、R9和R10代表除氢原子外的一种基团。
• ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS CARTRIDGE, IMAGE FORMING APPARATUS, AND IMIDE COMPOUND
  申请人：FUJI XEROX CO., LTD.

  公开号：US20190317415A1

  公开（公告）日：2019-10-17

  An electrophotographic photoreceptor includes a conductive substrate; a photosensitive layer provided on the conductive substrate; and an undercoating layer that is provided between the conductive substrate and the photosensitive layer and includes a charge transport material containing at least one of imide compounds represented by Formula (1) or (2): (in Formulas (1) and (2), R 10 , R 11 , R 20 , or R 21 independently represents a group represented by Formula (3) or (4) where X represents a monovalent organic group having at least one of an alkyl group, an alkylene group, an ether group, an ester group, and a keto group, a halogen atom, a nitro group, an aralkyl group, or an aryl group, Y represents a sulfur atom or an oxygen atom, n represents an integer of 0 to 2, and when n represents 2, two X's may be the same or different), and an imide compound is represented by Formula (1A) where Ar represents an aromatic group having 6 to 18 carbon atoms except for a tetravalent perylene group, X 1 and X 2 each independently represent a nitrogen atom or a substituted or unsubstituted carbon atom, Y 1 and Y 2 each independently represent an oxygen atom, a sulfur atom, a selenium atom, or NH, and R 1 and R 2 each independently represent a hydrogen atom or a monovalent organic group:

  一种电子照相光导体，包括导电基板；设置在导电基板上的感光层；以及设置在导电基板和感光层之间的底涂层，其中包括一种至少含有由式（1）或（2）表示的咪唑酰衍生物的电荷传输材料的底涂层： （在式（1）和（2）中，R10、R11、R20或R21各自独立地表示由式（3）或（4）表示的基团，其中X表示具有至少一种烷基，烷基烯基，醚基，酯基和酮基的单价有机基团，卤素原子，硝基，芳基烷基或芳基基团，Y表示硫原子或氧原子，n表示0到2的整数，当n表示2时，两个X可以相同或不同），咪唑酰衍生物由式（1A）表示，其中Ar表示除四价苝并基团外具有6到18个碳原子的芳香基团，X1和X2各自独立地表示氮原子或取代或未取代的碳原子，Y1和Y2各自独立地表示氧原子，硫原子，硒原子或NH，R1和R2各自独立地表示氢原子或单价有机基团：
• Process for the preparation of N,N' -disubstituted 1,4-diaminoanthraquinones
  申请人：——

  公开号：US20030225294A1

  公开（公告）日：2003-12-04

  Process for the preparation of N,N′-disubstituted 1,4-diaminoanthraquinones 1 in which R is an aliphatic or aromatic radical, characterized in that 1,4-dihydroxyanthraquinones are reacted with aliphatic or aromatic amines in the presence of a readily water-soluble, dipolar-aprotic solvent (e.g. NMP) and of a second solvent, different from the first.

  制备N，N'-二取代1,4-二氨基蒽醌1的过程，其中R是脂肪族或芳香族基团，其特征在于在易溶于水的双极-无质子溶剂（例如NMP）和第二种不同于第一种的溶剂存在下，将1,4-二羟基蒽醌与脂肪族或芳香族胺反应。