propyl 3-phenyl-(E)-2-propenyl ether | 14593-45-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: propyl 3-phenyl-(E)-2-propenyl ether
• 英文别名: 3-phenyl-(E)-2-propenyl n-propyl ether；(E)-(3-propoxyprop-1-en-1-yl)benzene；trans-Cinnamyl-propyl-ether；propyl-trans-cinnamyl ether；Propyl-trans-cinnamyl-aether；Cinnamyl propyl ether；[(E)-3-propoxyprop-1-enyl]benzene
• CAS: 14593-45-4
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: FOULKAPJVUMBTM-RMKNXTFCSA-N

物化性质

• 沸点：
  271.7±19.0 °C(Predicted)
• 密度：
  0.946±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  propyl 3-phenyl-(E)-2-propenyl ether 以77%的产率得到
  参考文献：
  名称：

  CERVENY L.; MARHOUL A.; RUZICKA V., CHEM. PRUM., 1980, 30, NO 3, 127-131

  摘要：

  DOI：
• 作为产物：
  描述：

  原甲酸三丙酯 、 3-苯基丙-2-烯-1-醇 在 碘 作用下， 反应 0.5h， 以85%的产率得到propyl 3-phenyl-(E)-2-propenyl ether
  参考文献：
  名称：

  Kumar; Anjaneyulu; Joyasawal, Sipak, Journal of the Indian Chemical Society, 2007, vol. 84, # 2, p. 189 - 192

  摘要：

  DOI：

文献信息

• Diastereoselective synthesis of tetrahydropyranes <i>via</i> Ag(<scp>i</scp>)-initiated dimerization of cinnamyl ethers
  作者：Davide Ruggeri、Elena Motti、Nicola Della Ca’、Giovanni Maestri

  DOI：10.1039/d2ob01876d

  日期：——

  We present herein the first synthesis of tetrahydropyranes promoted by a silver salt. Cinnamyl ethers undergo a formal dimerization affording the target heterocycle via sequential C–O bond cleavage/C–H bond functionalization. The cascade allows one to assemble three new bonds and to establish up to four stereocenters. The reaction likely proceeds through a cationic manifold that forms the target in

  我们在此介绍了由银盐促进的四氢吡喃的首次合成。肉桂基醚通过连续的 C-O 键断裂/C-H 键功能化进行形式二聚，得到目标杂环。级联允许一个人组装三个新键并建立多达四个立体中心。反应可能通过以非对映选择性方式形成目标的阳离子歧管进行。
• Electrohydrodynamically Enhanced Convective Boiling of Alternative Refrigerants: Fundamental Understanding and Applicability
  作者：James Bryan、Jamal Seyed-Yagoobi

  DOI：10.1080/10789669.2002.10391294

  日期：2002.10.1

  Electrohydrodynamically (EHD) enhanced convective boiling, based on the extraction phenomenon, is experimentally investigated. The working fluids are R-134a and R404A refrigerants. Both smooth and enhanced tubes are investigated in a horizontal configuration. The heat transfer enhancement and suppression with the corresponding pressure-drop data are presented. The ratio of EHD power consumption relative to the heat transferred was less than 1.5% for the data presented A theoretical analysis is presented to determine the contributing terms of the EHD power consumption, and it was determined that the electric conduction mechanism was the primary contributing factor to current flow. The transient application of EHD, in the case that resulted in the suppression of the heat transfer under steady-state conditions, provided transient enhancements for convective boiling of R-404A in a horizontal smooth tube. Additional, applicability of the EHD extraction phenomenon to convective boiling is discussed.
• Sampath Kumar; Joyasawal, Sipak; Reddy, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2005, vol. 44, # 8, p. 1686 - 1692
  作者：Sampath Kumar、Joyasawal, Sipak、Reddy、Pawan Chakravarthy、Krishna、Yadav

  DOI：——

  日期：——
• Clay catalyzed highly selective O-alkylation of primary alcohols with orthoesters
  作者：H.M. Sampath Kumar、B.V. Subba Reddy、Pradyumna.K. Mohanty、J.S. Yadav

  DOI：10.1016/s0040-4039(97)00684-9

  日期：1997.5
• Preparation of unsaturated ethers
  申请人：SHELL DEV

  公开号：US02042219A1

  公开（公告）日：1936-05-26