5-硫烷基己酸 | 100523-79-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 5-硫烷基己酸
• 英文名称: 5-Mercapto-capronsaeure
• 英文别名: 5-Sulfanylhexanoic acid
• CAS: 100523-79-3
• 化学式: C₆H₁₂O₂S
• mdl: MFCD19230279
• 分子量: 148.226
• InChiKey: YMWIFMOWFYNQMF-UHFFFAOYSA-N

物化性质

• 沸点：
  140 °C(Press: 15 Torr)
• 密度：
  1.084±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.833
• 拓扑面积：
  38.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  5-氧代己酸 在 Raney-Co 氢气 、 sulfur 作用下， 以 水 为溶剂， 反应 8.0h， 生成 5-硫烷基己酸
  参考文献：
  名称：

  Korte,F.; Christoph,H., Chemische Berichte, 1961, vol. 94, p. 1966 - 1976

  摘要：

  DOI：

文献信息

• LOW VISCOSITY, LOW VOLATILITY LUBRICATING OIL BASESTOCKS
  申请人：Patil Abhimanyu O.

  公开号：US20150275117A1

  公开（公告）日：2015-10-01

  A composition containing one or more sulfur-containing compounds represented by the formula (R 1 ) a (X)(R 2 ) b wherein R 1 and R 2 are the same or different and are the residue of an olefin (e.g., aliphatic, aromatic or cycloaliphatic olefin) having from 4 to 40 carbon atoms, X is the residue of a thiol or polythiol, a is a value from 1 to 6, and b is a value from 0 to 6. The composition has a kinematic viscosity at 100° C. (Kv 100 ) from 2 to 300 cst, a kinematic viscosity at 40° C. (Kv 40 ) from 5 to 4000 cst, a viscosity index (VI) from −100 to 300, and a Noack volatility of no greater than 90 percent. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of solubility and dispersancy of polar additives in a lubricating oil containing the composition.

  该组成物包含一个或多个含硫化合物，其表示为(R1)a(X)(R2)b，其中R1和R2相同或不同，是具有4至40个碳原子的烯烃（例如脂肪族、芳香族或环烷烃）的残基，X是硫醇或多硫醇的残基，a的值为1至6，b的值为0至6。该组成物在100℃下的运动粘度（Kv100）为2至300 cst，在40℃下的运动粘度（Kv40）为5至4000 cst，粘度指数（VI）为-100至300，Noack挥发度不大于90％。一种生产该组成物的方法，一种润滑油基础油和含有该组成物的润滑油，以及一种用于改善润滑油中极性添加剂的溶解性和分散性的方法。
• External modification of composite organic inorganic nanoclusters
  申请人：Zhang Jingwu

  公开号：US20060073336A1

  公开（公告）日：2006-04-06

  Modified and functionalized metallic nanoclusters capable of providing an enhanced Raman signal from an organic Raman-active molecule incorporated therein are provided. For example, modifications include coatings and layers, such as adsorption layers, metal coatings, silica coatings, and organic layers. The nanoclusters are generally referred to as COINs (composite organic inorganic nanoparticles) and are capable of acting as sensitive reporters for analyte detection. A metal that enhances the Raman signal from the organic Raman-active compound is inherent in the nanocluster. A variety of organic Raman-active compounds and mixtures of compounds can be incorporated into the nanocluster.

  本研究提供了经过修饰和功能化的金属纳米团簇，这些团簇能够从其中结合的有机拉曼活性分子中提供增强的拉曼信号。例如，修饰包括涂层和层，如吸附层、金属涂层、二氧化硅涂层和有机层。纳米团簇通常被称为 COINs（复合有机无机纳米颗粒），能够作为灵敏的报告器用于分析物检测。纳米团簇中固有的金属可增强有机拉曼活性化合物的拉曼信号。各种有机拉曼活性化合物和化合物混合物都可以加入纳米团簇中。
• Bacterium for producing polyhydroxyalkanoate having polyhydroxyalkanoate depolymerase gene disrupted and method for producing polyhydroxyalkanoate using the same
  申请人：Nomoto Tsuyoshi

  公开号：US20060172400A1

  公开（公告）日：2006-08-03

  The objective of the present invention is to provide a bacterium for producing polyhydroxyalkanoate with improved productivity. To achieve above objective, the gene coding for the polyhydroxyalkanoate depolymerase of the bacterium for producing polyhydroxyalkanoate is disrupted to improve the productivity of polyhydroxyalkanoate.

  本发明的目的是提供一种提高生产率的生产聚羟基烷酸的细菌。为实现上述目标，本发明破坏了生产聚羟基烷酸的细菌的聚羟基烷酸解聚酶的编码基因，以提高聚羟基烷酸的生产率。
• Composite organic inorganic nanoclusters
  申请人：Sun Lei

  公开号：US20060234248A1

  公开（公告）日：2006-10-19

  Metallic nanoclusters capable of providing an enhanced Raman signal from an organic Raman-active molecule incorporated therein are provided. The nanoclusters may be further functionalized, for example, with coatings and layers, such as adsorption layers, metal coatings, silica coatings, probes, and organic layers. The nanoclusters are generally referred to as COINs (composite organic inorganic nanoparticles) and are capable of acting as sensitive reporters for analyte detection. A variety of organic Raman-active compounds and mixtures of compounds can be incorporated into the nanocluster.

  本研究提供了能够从掺入其中的有机拉曼活性分子中提供增强拉曼信号的金属纳米团簇。这些纳米团簇可以进一步功能化，例如使用涂层和层，如吸附层、金属涂层、二氧化硅涂层、探针和有机层。这种纳米团簇通常被称为 COINs（复合有机无机纳米颗粒），能够作为灵敏的报告器用于分析物检测。各种有机拉曼活性化合物和化合物混合物都可以加入纳米簇中。
• SULFUR COMPOUNDS FOR ENHANCING COFFEE AROMA AND RESULTANT PRODUCTS CONTAINING SAME
  申请人：Nestec S.A.

  公开号：EP1679979B1

  公开（公告）日：2008-11-26