16,17-dihexyloxyviolanthrone | 25637-03-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 16,17-dihexyloxyviolanthrone
• 英文别名: 16,17-Dihexyloxyviolanthron；16,17-bis(hexyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione；16,17-Bis(hexyloxy)anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-dione；30,34-dihexoxynonacyclo[18.10.2.22,5.03,16.04,13.06,11.017,31.022,27.028,32]tetratriaconta-1(30),2(34),3(16),4(13),5(33),6,8,10,14,17(31),18,20(32),22,24,26,28-hexadecaene-12,21-dione
• CAS: 25637-03-0
• 化学式: C₄₆H₄₀O₄
• 分子量: 656.821
• InChiKey: KNVDQIUJXLJASN-UHFFFAOYSA-N

物化性质

• 密度：
  1.263±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.6
• 重原子数：
  50
• 可旋转键数：
  12
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  还原绿1 在 18-冠醚-6 、 potassium carbonate 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 29.0h， 生成 16,17-dihexyloxyviolanthrone
  参考文献：
  名称：

  一种16，17-双烷氧基蒽酮紫衍生物的制备方法

  摘要：

  本发明公开了一种16，17-双烷氧基蒽酮紫衍生物的制备方法，采用易得的染料16，17-二甲氧基蒽酮紫为起始原料，通过脱甲基化反应制备出16，17-双羟基蒽酮紫中间体，再通过Williamson醚合成反应，合成了对应的16，17-双烷氧基蒽酮紫类衍生物。本发明具有整体反应路线短，收率高，反应条件温和，成本低廉的特点。

  公开号：

  CN103804163B

文献信息

• METHOD OF CHEMILUMINESCENCE-UTILIZING MAKEUP AND BEAUTIFICATION, LUMINANT FOR SKIN IRRADIATION BEAUTIFICATION AND MAKEUP/ BEAUTIFICATION EQUIPMENT
  申请人：Fancl Corporation

  公开号：EP1721634A1

  公开（公告）日：2006-11-15

  Presentation of the methods for makeup and beauty treatment by chemical luminescence, luminous bodies for beauty treatment by exposure to skin, and tools for makeup and beauty treatment

  介绍利用化学发光进行化妆和美容的方法、暴露在皮肤上进行美容的发光体以及化妆和美容工具
• METHOD OF DETECTING RESIDUAL DETERGENT AND DEVICE FOR DETECTING RESIDUAL DETERGENT
  申请人：Lumica Co., Ltd.

  公开号：EP2028477A1

  公开（公告）日：2009-02-25

  It is intended to provide a method whereby residual detergent (surfactant) can be conveniently and accurately detected in the step of washing or rinsing dishes or clothes, and a test device usable in examining the rinsed conditions. Namely, a method characterized by comprising bringing a test substance with a composition (test agent) comprising an oxalic acid ester, a fluorescent substance, hydrogen peroxide and a strong acid and thus easily detecting the residual detergent sticking to the surface of the test subject from the chemiluminescence thus caused; and a test device which is most suitable for storing the test agent as described above.

  本发明的目的是提供一种在清洗或漂洗餐具或衣物的步骤中可以方便而准确地检测残留洗涤剂（表面活性剂）的方法，以及一种可用于检测漂洗条件的检测装置。也就是说，这种方法的特点是：将一种测试物质与一种由草酸酯、荧光物质、过氧化氢和强酸组成的组合物（测试剂）放在一起，这样就可以很容易地从由此产生的化学发光中检测出粘附在测试对象表面的残留洗涤剂；以及一种最适合储存上述测试剂的测试装置。
• OXIDIZING LIQUID FOR CHEMILUMINESCENCE AND CHEMILUMINESCENCE SYSTEM USING SAME
  申请人：Lumica Corporation

  公开号：EP2535391A1

  公开（公告）日：2012-12-19

  Provided are an oxidizing liquid for a chemiluminescent material, which has a flash point higher than that of a conventional oxidizing liquid and also has high safety while maintaining the level of chemiluminescent performance; and a chemiluminescence system. Disclosed are an oxidizing liquid for a chemiluminescent material, which produces a chemiluminescence phenomenon when mixed with a fluorescent liquid containing an oxalic acid ester and a fluorescent substance, includes hydrogen peroxide and a solvent and has a flash point of 60°C or higher, wherein a solvent to be contained in the oxidizing liquid is a mixture of at least two compounds other than phthalate compounds; and a chemiluminescence system using the oxidizing liquid and a fluorescent liquid.

  本发明提供了一种用于化学发光材料的氧化液，其闪点高于传统氧化液的闪点，并且在保持化学发光性能水平的同时还具有较高的安全性；还提供了一种化学发光系统。本发明公开了一种用于化学发光材料的氧化液，该氧化液与含有草酸酯和荧光物质的荧光液混合时会产生化学发光现象，它包括过氧化氢和溶剂，闪点为 60°C 或更高，其中氧化液中含有的溶剂是除邻苯二甲酸酯化合物之外的至少两种化合物的混合物；以及一种使用该氧化液和荧光液的化学发光系统。
• Device for dispensing chemiluminescent solution
  申请人：Imperial Toy LLC

  公开号：US10118433B2

  公开（公告）日：2018-11-06

  Devices have a flexible housing with an inside chamber having a closed and open end. A first chemiluminescent fluid is disposed in a breakable container in the chamber, and a second chemiluminescent fluid is in the chamber. A tip assembly is attached to the housing and includes a nib movably disposed in the body, and a filter element may be positioned within the body to prevent passage of broken particles from the container to the nib tip. A resilient element is used to impose an outward biasing force on the nib. A porous material is disposed over an outer surface of the nib tip and securely held in place. The device is activated for use by bending the housing to break the container causing the first and second chemiluminescent fluids to mix and react, providing a chemiluminescent solution that flows to the tip assembly for dispensing onto a desired surface.

  设备有一个柔性外壳，内腔有封闭端和开放端。第一种化学发光流体放置在腔室中的可破损容器中，第二种化学发光流体放置在腔室中。笔尖组件连接到外壳上，包括可移动地设置在主体内的笔尖，过滤元件可设置在主体内，以防止破碎的颗粒从容器进入笔尖。弹性元件用于在笔尖上施加向外的偏压力。多孔材料被放置在笔尖的外表面并牢牢固定。通过弯曲外壳使容器破裂，使第一种和第二种化学发光液体混合并发生反应，从而提供化学发光溶液，该溶液流向笔尖组件，以便分配到所需的表面上。
• Apparatus and method for treating atherosclerotic vascular disease through light sterilization
  申请人：——

  公开号：US20020147443A1

  公开（公告）日：2002-10-10

  A method and apparatus is described for eliminating atherosclerotic vascular disease by exposing the interior of an artery or vein to visible or ultraviolet light of a selected spectrum to thereby sterilize the artery, eradicating infectious pathogens and reverse the pathogenesis of atherosclerotic artery disease. The light energy can be supplied through a fiber optic bundle positioned via an intra-arterial catheter that is connected to an appropriate light radiation source located outside of the body during treatment. In another form of the invention, the light energy is produced by means of a light energy source located at the distal tip of the instrument shaft positioned centrally within the atherosclerotic plaque formation during treatment. In this case, the power source at the distal tip of the instrument can, for example, be a light emitting diode (LED) or a transparent tube containing a chemical or chemilumlumenescent substance for producing cool light energy within the vessel to destroy the pathogenic microorganisms in the surrounding plaque or vessel without damage to the body issue of the patient.

  本文描述了一种消除动脉粥样硬化性血管疾病的方法和设备，其方法是将动脉或静脉内部暴露于选定光谱的可见光或紫外线中，从而对动脉进行消毒，消灭感染性病原体，并逆转动脉粥样硬化性疾病的发病机制。光能可通过光纤束提供，光纤束通过动脉内导管定位，导管在治疗过程中与位于体外的适当光辐射源相连。在本发明的另一种形式中，光能是通过位于治疗过程中动脉粥样硬化斑块形成中心的器械轴远端产生的。在这种情况下，位于器械远端顶端的电源可以是发光二极管（LED）或含有化学或化学发光物质的透明管，用于在血管内产生冷光能，以消灭周围斑块或血管中的病原微生物，而不会对患者的身体问题造成损害。