1,1,3-Triphenylindane | 73010-42-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 1,1,3-Triphenylindane
• 英文别名: 1,1,3-Triphenyl-indan；1,1,3-Triphenylindan；1,3,3-Triphenyl-1,2-dihydroindene
• CAS: 73010-42-1
• 化学式: C₂₇H₂₂
• 分子量: 346.472
• InChiKey: KDGBYEGXWQIXNR-UHFFFAOYSA-N

物化性质

• 沸点：
  471.6±45.0 °C(Predicted)
• 密度：
  1.119±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1,2,2-tetraphenylcyclopropane 以 苯 为溶剂， 生成 1,1,3-Triphenylindane
  参考文献：
  名称：

  1,1,2,2-四苯基环丙烷的热重排

  摘要：

  1,1,2,2-四苯基环丙烷（1）的热重排为1,1,3-三苯基茚满（2）涉及形成中间体三烯（3），该中间体已通过uv光谱法检测到并通过与亲酸剂反应而被捕集。

  DOI：

  10.1039/c39790000793

文献信息

• Ethics and Foreign Policy: The Antinomies of New Labour's ‘Third Way’ in Sub-Saharan Africa
  作者：Rita Abrahamsen、Paul Williams

  DOI：10.1111/1467-9248.00312

  日期：2001.6

  This article explores how New Labour has attempted to implement its ideas about a ‘third way’ foreign policy in sub-Saharan Africa. Through an examination of British foreign policy practices, we explore whether New Labour has succeeded in finding a ‘third way’ between traditional views of socialism and capitalism in Africa. In particular, the article focuses on New Labour's attempts to build peace, prosperity and democracy on the African continent. We conclude that although New Labour's claims to add an ‘ethical dimension’ to foreign policy have succeeded in giving Britain a higher profile in the international arena, the implementation of such a policy is intrinsically difficult. These difficulties in turn arise from the antinomies embodied in New Labour's policy, or more specifically from the tension between the liberal internationalism of the third way and traditional concerns for the national interest, as well as the contradictions inherent in a commitment to both political and economic liberalism.

  这篇文章探讨了新工党如何试图在撒哈拉以南非洲实施其关于“第三条道路”外交政策的想法。通过对英国外交政策实践的审查，我们探讨新工党是否成功地在非洲传统社会主义和资本主义观念之间找到了一种“第三条道路”。特别是，文章关注新工党在非洲大陆上建立和平、繁荣和民主的努力。我们得出结论，尽管新工党声称在外交政策中增加了“道德维度”成功地使英国在国际舞台上更加引人注目，但这种政策的实施本质上是困难的。这些困难反过来源于新工党政策所体现的矛盾，更具体地说，源于第三条道路的自由国际主义与对国家利益的传统关注之间的紧张关系，以及对政治和经济自由主义的承诺中固有的矛盾。
• Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes
  作者：Blanca Inés、David Palomas、Sigrid Holle、Sebastian Steinberg、Juan A. Nicasio、Manuel Alcarazo

  DOI：10.1002/anie.201205348

  日期：2012.12.3

  The poorer, the better: A metal‐free catalytic procedure for the reduction of electron‐poor allenes and alkenes has been developed. The method employs a frustrated Lewis pair based catalyst. 1,4‐Diazabicyclo[2.2.2]octane (DABCO)/B(C6F5)3 was shown to be the best combination in optimization studies.

  越差越好：已开发出一种用于减少电子贫乏的烯和烯烃的无金属催化方法。该方法使用沮丧的路易斯对基催化剂。1,4-二氮杂双环[2.2.2]辛烷（DABCO）/ B（C 6 F 5）3被证明是优化研究的最佳组合。
• Cooperative Lewis acidity in borane-substituted fluorophosphonium cations
  作者：Juri Möbus、Thorsten vom Stein、Douglas W. Stephan

  DOI：10.1039/c6cc02607a

  日期：——

  A series of aryl-difluorophosphoranes are converted to give fluorophosphonium salts [C6X4(BR2)Ph2PF]+ (X = H, F; R = Cy, Mes). The proximity of the two weakly Lewis acidic fluorophosphonium and borane...

  一系列芳基-二氟膦酸酯被转化为氟phosph盐[C6X4（BR2）Ph2PF] +（X = H，F; R = Cy，Mes）。两个弱路易斯酸性氟phosph和硼烷的相近...
• Organopromoted Direct Synthesis of 1,1-Diphenyl-3-arylindanes via Formal [3+2] Cycloadditions of Triphenylcarbenium Tetrafluoroborate with Styrenes
  作者：Nakin Surapanich、Patcharin Chaisuwan、Chutima Kuhakarn、Vichai Reutrakul

  DOI：10.1055/s-0036-1588302

  日期：——

  A formal [3+2] cycloaddition of triphenylcarbenium tetrafluoroborate with structurally different styrene derivatives has been developed. A combination of benzophenone and Et 3 N is key for promoting a formal [3+2] cycloaddition of triphenylcarbenium tetrafluoroborate with styrenes affording 1,1-diphenyl-3-arylindanes in moderate to good yields. The reaction mechanism of this transformation is also

  已开发出三苯基碳鎓四氟硼酸盐与结构不同的苯乙烯衍生物的正式 [3+2] 环加成反应。二苯甲酮和 Et 3 N 的组合是促进四氟硼酸三苯基碳鎓与苯乙烯的正式 [3+2] 环加成反应的关键，以中等至良好的产率得到 1,1-二苯基-3-芳基烷。还讨论了这种转变的反应机理。
• Schlenk; Bergmann, Justus Liebigs Annalen der Chemie, 1928, vol. 463, p. 208
  作者：Schlenk、Bergmann

  DOI：——

  日期：——