phenyliminocyanamide | 64661-86-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyliminocyanamide
• 英文别名: benzenediazocyanide；phenyl-trans-diazenecarbonitrile；Phenyl-trans-diazencarbonitril
• CAS: 64661-86-5
• 化学式: C₇H₅N₃
• 分子量: 131.137
• InChiKey: QGWQTKPYQSONBC-MDZDMXLPSA-N

物化性质

• 熔点：
  29 °C
• 沸点：
  60-65 °C(Press: 0.1 Torr)
• 密度：
  1.06±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.25
• 重原子数：
  10.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  48.51
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  phenyliminocyanamide 在 platinum(IV) oxide 氢气 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 48.0h， 生成 2-Phenyl-tetrahydro-pyridazine-1-carbonitrile
  参考文献：
  名称：

  通过1,3,4-tri-aza-Cope重排，从1,3-二烯和苯二氮杂氰化物生成苯并咪唑二氮杂。

  摘要：

  由芳烃重氮氰化物和1，3-二烯制备环状和双环的1-氰基-2-芳基肼。其中一些在室温下通过1,3,4-tri-aza-Cope重排进行重排，然后进行分子内环化，从而以中等收率提供苯并咪唑-二氮杂s。当通过减少环加合物使竞争性逆狄尔斯-阿尔德反应无法进行时，重排发生在较高的温度下，收率极高，达到了以前未知的苯并咪唑-二氮杂s。

  DOI：

  10.1016/s0040-4020(01)89022-0
• 作为产物：
  描述：

  氰化钾 、 benzenediazonium tetrafluoroborate 在 18-冠醚-6 作用下， 以 二氯甲烷 为溶剂， 反应 18.0h， 以15%的产率得到phenyliminocyanamide
  参考文献：
  名称：

  Crown cation complex effects. 15. Phase-transfer synthesis of arenediazocyanides and synthesis of arenediazosulfones from arenediazonium cations and the formation of reduced pyridazines by 2 + 4 cycloaddition reactions

  摘要：

  DOI：

  10.1021/ja00366a030

文献信息

• Photoresponsive Heterocyclic Azo Compound, Method for Producing the Same, and Optical Information Recording Medium
  申请人：Fukuda Takashi

  公开号：US20070242322A1

  公开（公告）日：2007-10-18

  There are provided a novel optical information recording material or medium excellent in various holographic optical information recording properties such as sensitivity, response speed, long-term storage stability, and repeatability, and a substance therefor. A photoresponsive heterocyclic azo compound contains an oligomer or polymer having a photoresponsive moiety in at least one of the main chain and side chain, and the photoresponsive moiety is a building block represented by the following formula (1): wherein HC 1 and HC 2 each represent a ring structure, at least one of them being a heterocyclic structure containing 1 or more heteroatom in the ring, R 1 and R 2 each represent a hydrogen atom or a substituent connected to the ring structure and may be the same or different ones, s and t each represent the number thereof, and X 1 and X 2 each represent a terminal group or a linking group, at least one of them being a linking group connected to the main chain of the oligomer or polymer and the terminal group being a hydrogen atom or a substituent.

  提供了一种新型的光学信息记录材料或介质，具有各种全息光学信息记录性能，如灵敏度、响应速度、长期存储稳定性和重复性，以及一种物质。一种光响应杂环偶氮化合物包含在主链和侧链中至少有一个具有光响应基团的寡聚物或聚合物，其中光响应基团是由以下公式（1）表示的构建块：其中HC1和HC2各代表一个环结构，其中至少一个是含有1个或多个杂原子的杂环结构，R1和R2各代表氢原子或连接到环结构的取代基，可以是相同或不同的，s和t各代表其数量，X1和X2各代表端基或连接基团，其中至少一个是连接到寡聚物或聚合物的主链的连接基团，而端基是氢原子或取代基。
• Photo-responsive high-molecular compound, photo-responsive high-molecular composition, dicarboxylic acid monomer, polyester, optical recording medium and optical record reproducing device
  申请人：FUJI XEROX CO., LTD.

  公开号：US20040029038A1

  公开（公告）日：2004-02-12

  In the present invention, a photosensitive layer of an optical recording medium includes a photo-responsive high-molecular compound comprising a photo-responsive group (e.g., an azobenzene derivative) which is geometrically isomerized by light radiation, and a liquid crystal linear mesogen group (e.g., a biphenyl derivative), wherein the photo-responsive group and the linear mesogen group are respectively bonded as side chains. The invention provides an optical recording medium enabling large scale recording by making the photosensitive layer thick without impairing recording characteristics. The photo-responsive high-molecular compound preferably comprises an aromatic ring on a main chain. Further, the photo-responsive high-molecular compound preferably comprises a structural unit which is capable of forming a liquid-crystalline or crystalline polymer and a structural unit which is capable of forming an amorphous polymer.

  在本发明中，光学记录介质的光敏层包括一种光响应高分子化合物，其中包括一种光响应基团（例如偶氮苯衍生物），该基团通过光辐射几何异构化，以及一种液晶线性介质基团（例如联苯衍生物），其中光响应基团和线性介质基团分别作为侧链键合。本发明提供了一种光学记录介质，使光敏层变厚而不影响记录特性，从而实现大规模记录。光响应高分子化合物最好包括主链上的芳香环。此外，光响应高分子化合物最好包括能够形成液晶或结晶聚合物的结构单元和能够形成非晶聚合物的结构单元。
• Optical recording medium and method for producing the same
  申请人：FUJI XEROX CO., LTD.

  公开号：US20040191684A1

  公开（公告）日：2004-09-30

  An optical recording medium including a recording layer which is formed into a predetermined shape with a thickness of 0.1 mm to 5 mm and which contains a polyester represented by the following formula (1). 1

  一种光学记录介质，包括一个以0.1毫米至5毫米厚度形成为预定形状的记录层，该层包含下式（1）所表示的聚酯。
• PHOTO-RESPONSIVE HIGH-MOLECULAR COMPOUND, PHOTO-RESPONSIVE HIGH-MOLECULAR COMPOSITION, DICARBOXYLIC ACID MONOMER, POLYESTER, OPTICAL RECORDING MEDIUM AND OPTICAL RECORD REPRODUCING DEVICE
  申请人：Minabe Jiro

  公开号：US20070184234A1

  公开（公告）日：2007-08-09

  In the present invention, a photosensitive layer of an optical recording medium includes a photo-responsive high-molecular compound comprising a photo-responsive group (e.g., an azobenzene derivative) which is geometrically isomerized by light radiation, and a liquid crystal linear mesogen group (e.g., a biphenyl derivative), wherein the photo-responsive group and the linear mesogen group are respectively bonded as side chains. The invention provides an optical recording medium enabling large scale recording by making the photosensitive layer thick without impairing recording characteristics. The photo-responsive high-molecular compound preferably comprises an aromatic ring on a main chain. Further, the photo-responsive high-molecular compound preferably comprises a structural unit which is capable of forming a liquid-crystalline or crystalline polymer and a structural unit which is capable of forming an amorphous polymer.

  在本发明中，光学记录介质的感光层包括一种光响应高分子化合物，其中包括一个光响应基团（例如，偶氮苯衍生物），该基团可以通过光辐射几何异构化，以及一种液晶线性介质基团（例如，联苯衍生物），其中光响应基团和线性介质基团分别作为侧链结合。该发明提供了一种光学记录介质，使感光层变厚而不影响记录特性，从而实现大规模记录。光响应高分子化合物最好包括一个主链上的芳香环。此外，光响应高分子化合物最好包括一种能够形成液晶或结晶聚合物的结构单元和一种能够形成非晶聚合物的结构单元。
• Method for providing a substrate structure for oriented neuron growth, substrate structure, and device for monitoring neurons
  申请人：Sony International (Europe) GmbH

  公开号：EP1054055A1

  公开（公告）日：2000-11-22

  The invention relates to a method for providing a substrate structure for oriented neuron growth, wherein a basic substrate is provided, characterized in that at least one alignment layer is deposited on said substrate and a mono- or multi-layer of a liquid crystal material is deposited on said at least one alignment layer or a combined alignment layer comprising liquid crystal material is deposited on said basic substrate, thereby providing a structured surface.

  本发明涉及一种为定向神经元生长提供基底结构的方法，其中提供一个基本基底，其特征在于在所述基底上沉积至少一个配位层，并在所述至少一个配位层上沉积单层或多层液晶材料，或在所述基本基底上沉积包含液晶材料的组合配位层，从而提供一个结构化表面。