4-hydroxymethylphenylsulfonic acid | 122855-96-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-hydroxymethylphenylsulfonic acid
• 英文别名: 4-(Hydroxymethyl)benzenesulfonic acid
• CAS: 122855-96-3
• 化学式: C₇H₈O₄S
• 分子量: 188.204
• InChiKey: VVQVMHASNBSOOC-UHFFFAOYSA-N

物化性质

• 密度：
  1.493±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  83
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  一氧化二硫 、 氯化苄 生成 4-hydroxymethylphenylsulfonic acid
  参考文献：
  名称：

  �ber das Schwefelmonoxyd

  摘要：

  DOI：

  10.1007/bf00899332

文献信息

• MICROORGANISMS AND METHODS FOR PRODUCTION OF 4-HYDROXYBUTYRATE, 1,4-BUTANEDIOL AND RELATED COMPOUNDS
  申请人：Genomatica, Inc.

  公开号：US20150148513A1

  公开（公告）日：2015-05-28

  The invention provides non-naturally occurring microbial organisms having a 4-hydroxybutyrate, 1,4-butanediol, or other product pathway and being capable of producing 4-hydroxybutyrate, 1,4-butanediol, or other product, wherein the microbial organism comprises one or more genetic modifications. The invention additionally provides methods of producing 4-hydroxybutyrate, 1,4-butanediol, or other product or related products using the microbial organisms.

  该发明提供了具有4-羟基丁酸、1,4-丁二醇或其他产物途径并能够产生4-羟基丁酸、1,4-丁二醇或其他产物的非自然微生物生物体，其中该微生物生物体包括一个或多个基因修饰。该发明还提供了利用这些微生物生物体生产4-羟基丁酸、1,4-丁二醇或其他产物或相关产品的方法。
• [EN] METHOD FOR THE SYNTHESIS OF CHIRAL ALPHA-ARYL PROPIONIC ACID DERIVATIVES<br/>[FR] PROCÉDÉ POUR LA SYNTHÈSE DE DÉRIVÉS CHIRAUX D'ACIDE ALPHA-ARYLPROPIONIQUE
  申请人：DSM IP ASSETS BV

  公开号：WO2010089343A1

  公开（公告）日：2010-08-12

  The present invention provides a method for the synthesis of optically pure α-aryl propionic acid derivatives comprising subjecting the corresponding racemic α-aryl propionic acid derivatives to high sheer or impact forces, such as grinding.

  本发明提供了一种合成光学纯α-芳基丙酸衍生物的方法，包括将相应的混合的α-芳基丙酸衍生物暴露于高剪切或冲击力，例如研磨。
• Selective hydroxylation of methyl groups by platinum salts in aqueous medium. Direct conversion of ethanol to ethylene glycol
  作者：Jay A. Labinger、Andrew M. Herring、John E. Bercaw

  DOI：10.1021/ja00170a031

  日期：1990.7

  P-450 and models thereof. Shilov's Ptsup II}-Ptsup IV} system appears attractive in that the species involved will tolerate Osub 2}, although catalytic oxidation has not yet been achieved; nor is much known about detailed mechanism or selectivity. In an attempt to further delineate the mechanism they have examined oxidation of water-soluble model substrates and report here unexpected findings of

  在过去几年中，出现了许多有趣的例子，证明过渡金属配合物通常在非常温和的条件下激活烷烃中的 CH 键。大多数研究的系统与 Osub 2} 不相容，Osub 2} 是获得热力学有利、经济可行的催化反应的最理想的助剂。此外，潜在产品（醇类、烯烃等）通常比起始烷烃更具反应性，这限制了可实现的产率。当涉及氢原子提取路线时，后者尤其成问题，如 P-450 及其模型。Shilov 的 Ptsup II}-Ptsup IV} 系统看起来很有吸引力，因为所涉及的物种将耐受 Osub 2}，尽管尚未实现催化氧化；对详细的机制或选择性也知之甚少。
• Infrared ray absorbing composition or infrared ray absorbing composition kit, infrared ray cut filter using the same, method for producing the infrared ray cut filter, camera module, and method for producing the camera module
  申请人：FUJIFILM Corporation

  公开号：US10036838B2

  公开（公告）日：2018-07-31

  An infrared ray absorbing composition kit comprises: a composition containing a copper compound or pigment having a maximum absorption wavelength in the wavelength range of 700 nm to 1000 nm; and a composition containing a metal oxide having a maximum absorption wavelength in the wavelength range of 800 nm to 2000 nm.

  一种红外线吸收组合物套装包括：含有在700 nm至1000 nm波长范围内具有最大吸收波长的铜化合物或颜料的组合物；以及含有在800 nm至2000 nm波长范围内具有最大吸收波长的金属氧化物的组合物。
• Novel compositions of material, especially lubricants and pressure transmitting means, the production and use thereof
  申请人：——

  公开号：US20030186823A1

  公开（公告）日：2003-10-02

  The invention relates to novel compositions of matter which may advantageously be used as lubricants or pressure transfer media or else for functional liquids and lubricant additives. The lubricants according to the invention are the reaction products of an electro-philic addition of linear or branched, aliphatic or aromatic carboxylic acids, carboxylic anhydrides, carbonyl halides or novel neoacids to the double bonds of fatty acids, esters thereof and/or of other fatty acid derivatives and also of synthetic esters. Owing to their increased oxidation resistance compared to the starting materials and also their low toxicity, the novel class of synthetic esters based on oleochemicals may find use in novel environmentally compatible lubricants, pressure transfer systems, functional liquids and lubricant additives.

  本发明涉及一种新型物质组成，可优势地用作润滑剂或压力传递介质，或者用于功能液体和润滑剂添加剂。根据本发明，润滑剂是线性或支链的，脂肪族或芳香族羧酸，羧酸酐，羰基卤化物或新型新酸通过亲电加成反应与脂肪酸，其酯和/或其他脂肪酸衍生物以及合成酯的双键反应生成的产物。由于与起始材料相比具有较高的氧化抵抗性和低毒性，基于油脂化学的新型合成酯类可以用于新型环境兼容的润滑剂、压力传递系统、功能液体和润滑剂添加剂。