二乙基芴-9,9-二羧酸酯 | 139022-32-5

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 中文名称: 二乙基芴-9,9-二羧酸酯
• 英文名称: diethyl fluorene-9,9-dicarboxylate
• 英文别名: diethyl 9H-fluorene-9,9-dicarboxylate；fluorene-9,9-dicarboxylic acid diethyl ester；Fluoren-9,9-dicarbonsaeure-diaethylester；9H-Fluorene-9,9-dicarboxylic acid, diethyl ester
• CAS: 139022-32-5
• 化学式: C₁₉H₁₈O₄
• 分子量: 310.35
• InChiKey: VVMZITZGPXEVIM-UHFFFAOYSA-N

物化性质

• 沸点：
  412.0±45.0 °C(Predicted)
• 密度：
  1.217±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二乙基芴-9,9-二羧酸酯 、 alkaline earth salt of/the/ methylsulfuric acid 生成 芴丁酯 、 9-羟基-9-芴甲酸甲酯
  参考文献：
  名称：

  Adickes et al., Journal fur praktische Chemie (Leipzig 1954), 1932, vol. <2>133, p. 313

  摘要：

  DOI：
• 作为产物：
  描述：

  芴 、 氯甲酸乙酯 在 正丁基锂 、 二异丙胺 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 0.5h， 生成 二乙基芴-9,9-二羧酸酯
  参考文献：
  名称：

  CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST CONTAINING CATALYST COMPONENT AND USE THEREOF

  摘要：

  一种用于烯烃聚合的催化剂组分，包括Mg、Ti、卤素和电子给体，其中电子给体至少为一种不饱和环取代二酸酯化合物。还提供了含有该催化剂组分的催化剂以及在烯烃聚合中使用该催化剂，例如丙烯聚合。

  公开号：

  US20170088642A1

文献信息

• Synthesis of 9,9-Disubstituted Fluorenes from 2-Iodobiphenyls and α-Diazoesters under Palladium Catalysis
  作者：Ding Ma、Guangfa Shi、Zhuo Wu、Xiaoming Ji、Yanghui Zhang

  DOI：10.1021/acs.joc.7b02885

  日期：2018.1.19

  9,9-Disubstituted fluorenes are widely employed in materials science. We have developed a straightforward approach for the synthesis of 9,9-disubstituted fluorenes from 2-iodobiphenyls and α-diazoesters. The reaction proceeds via a tandem palladium-catalyzed C(sp2)–H activation/carbenoid insertion sequence.

  9,9-二取代芴在材料科学中被广泛使用。我们已经开发出一种简单的方法，可以从2-碘代联苯和α-重氮酯合成9,9-二取代的芴。反应通过串联钯催化的C（sp 2）–H活化/类胡萝卜素插入序列进行。
• Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates
  作者：Yanying Zhang、Song Tu、Koichi Mitsudo、Hideo Tanaka、Shunzo Suematsu、Kenji Machida、Daisuke Horii、Shuichi Ishimoto、Kenji Tamamitsu

  DOI：10.1016/j.tetlet.2009.08.052

  日期：2009.11

  Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the Surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from -2.5 to 1.5 V vs Ag/Ag+), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials. (C) 2009 Elsevier Ltd. All rights reserved.
• OLEFIN POLYMERIZATION CATALYST CARRIER, SOLID CATALYST COMPONENT AND USE THEREOF
  申请人：Renqiu Lihe Technology Ltd.

  公开号：US20170355792A1

  公开（公告）日：2017-12-14

  Provided is an olefin polymerization catalyst carrier with a general structure formula of Mg(OR I ) n (OR II ) 2-n , wherein: 0≦n≦2, and R I and R II can be the same or different and are each independently selected from a C 1 -C 20 hydrocarbon group. In the X-ray diffraction pattern of the catalyst carrier, there are a set of diffraction peaks in the range of a 2θ diffraction angle of 5°-15°, and the set of diffraction peaks contain 1-4 main diffraction peaks. Also disclosed is an olefin polymerization solid catalyst component which is prepared from the carrier Mg(OR I ) n (OR II ) 2-n , a titanium compound, and at least one electron donor compound. In addition, also disclosed is an olefin polymerization catalyst containing the solid catalyst component, at least one organic aluminum compound, and optionally, an external electron donor compound.