{(1,4,8,12-tetraazacyclopentadecane)nickel(II)}(ClO4)2 | 71882-19-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: {(1,4,8,12-tetraazacyclopentadecane)nickel(II)}(ClO4)2
• CAS: 71882-19-4
• 化学式: C₁₁H₂₆N₄Ni*2ClO₄
• 分子量: 471.945
• InChiKey: AFCCUBRIXONLKE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {(1,4,8,12-tetraazacyclopentadecane)nickel(II)}(ClO4)2 在 H₂O 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Preparation and characterization of transition metal complexes of 1,4,8,12-tetra-azacyclopentadecane ([15]aneN4)

  摘要：

  The preparation and characterization of a variety of transition metal complexes of the macrocycle 1,4,8,12-tetra-azacyclopentadecane ([15]aneN(4)) with Cr-III, Mn-III, Fe-III, Ni-II, Zn-II and Rh-III are described. IR and visible spectra of the complexes are reported. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00545-1
• 作为产物：
  描述：

  1,4,8,12-四氮杂环十五烷 、 nickel(II) perchlorate hexahydrate 以 甲醇 为溶剂， 以80%的产率得到{(1,4,8,12-tetraazacyclopentadecane)nickel(II)}(ClO4)2
  参考文献：
  名称：

  (Monomethyl Carbonato)-镍(II)、-铜(II)和-钴(II)配合物与从CO2吸收获得的四氮杂环烷烃的合成、表征和结构

  摘要：

  已经合成了一系列新的镍 (II)、钴 (II) 和铜 (II) 的单甲基碳酸盐配合物，其中含有四氮杂环烷烃 (L)，并对其进行了表征： Ni(L)(O2COCH3)(ClO4) (L=[14] aneN4 (1); L=[15]aneN4 (2); L=iso-[14]aneN4 (3); L=RSRS-Me4[14]aneN4 (4)), [Ni(RRSS-Me4[14] aneN4)(O2COCH3)2]·HNEt3ClO4 (5), Cu([14]aneN4)(O2COCH3)(ClO4) (6), [Cu(Me4[14]aneN4)(O2COCH3)](ClO4)·CH3OH (7) ), 和 Co(L)(O2COCH3)(ClO4) (L=[15]aneN4 (8); L=Me4[14]aneN4 (9))，其中 [14]aneN4=1,4,8,11-四氮杂环十四烷，[15]aneN4=1

  DOI：

  10.1246/bcsj.59.285

文献信息

• Nickel(II) complexes with tetraaza macrocyclic ligands
  作者：Linfeng Chen、F.Albert Cotton

  DOI：10.1016/s0022-2860(98)00478-5

  日期：1998.10

  Abstract The Ni(II) complexes of 1,5,9,13-tetraazacyclohexadecane ([16]aneN 4 ) and 1,4,8,12 tetraazacyclopentadecane ([15]aneN 4 ) ligands have been synthesized and characterized by X-ray crystallography. Crystal data for orange [Ni([16]aneN 4 )](ClO 4 ) 2 ( 1 ) at 213 K: monoclinic space group P 2 1 / c , a =13.38(1), b =17.818(6), c =16.579(6) A, β=90.80(6)°, V =3952(4) A3; for [Ni([15]aneN 4 )[ClO

  摘要 合成了 1,5,9,13-四氮杂环十六烷 ([16]aneN 4 ) 和 1,4,8,12 四氮杂环十五烷 ([15]aneN 4 ) 配体的 Ni(II) 配合物并通过 X 射线表征晶体学。橙色 [Ni([16]aneN 4 )](ClO 4 ) 2 ( 1 ) 在 213 K 的晶体数据：单斜空间群 P 2 1 / c , a =13.38(1), b =17.818(6), c =16.579(6)A，β=90.80(6)°，V=3952(4)A3；对于 [Ni([15]aneN 4 )[ClO 4 ) 2 ] (3) 在 173 K: 单斜空间群 P 2 1 / n , a =8.072(2), b =17.857(2), c =12.923( 2) A，β=95.92(1)°，V=1852.8(7) A3。化合物 1 在 ch,ch,ch,ch,+-+- 构象中具有配体，但氮原子实际上是共面的。在图
• Oxidation of tetraaza macrocyclic complexes of nickel(II) with peroxobisulfate ions
  作者：S. V. Rosokha、Ya. D. Lampeka

  DOI：10.1007/bf00534421

  日期：——

  oxidation of some tetraaza macrocyclic complexes of nickel (II) with peroxobisulfate ions in perchloric and sulfuric acid solutions. A scheme of the processes taking place has been proposed and the activation parameters of the reactions determined. The influence of different factors (pH value, ionic strength of the solution, temperature) on the kinetic parameters of the oxidation reactions has been studied

  分光光度法已用于研究镍 (II) 的某些四氮杂大环配合物与过硫酸氢根离子在高氯和硫酸溶液中的氧化动力学。已经提出了发生的过程的方案并确定了反应的活化参数。研究了不同因素（pH 值、溶液的离子强度、温度）对氧化反应动力学参数的影响。已经注意到复合物中大环配体的构象对过程速率的显着影响。
• Radical-ion salts obtained from tetraazaderivatives of nickel and copper and tetracyanoquinodimethane: structural and magnetic characterization
  作者：Loreto Ballester、Angel Gutiérrez、M Felisa Perpiñán、Ana E Sánchez、M Teresa Azcondo、M Jesús González

  DOI：10.1016/j.ica.2003.09.022

  日期：2004.3

  Several derivatives of formulae [M(N-4)(TCNQ)(2)] and [M(N-4)(TCNQ)(2)](TCNQ) (M = Ni, Cu; N-4 = 1,4,7,10-tetraazacyclododecane ([12] aneN(4)), 1,4,8,11-tetraazacyclotetradecane ([14] aneN(4)), 1,4,8,12-tetraazacyclopentadecane ([15] aneN(4)), 1,4,7,10-tetraazadecane (trien), N,N,N-tris(2-aminoethyl)amine (tren), 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,14-diene (trans-dieneN(4))) have been obtained by metathesis reaction of the corresponding perchlorate or nitrate derivatives and LiTCNQ or (Et3NH)(TCNQ)(2). The compounds [M(aneN(4))(TCNQ)(2)] have a six coordinated metal atom surrounded by the four macrocyclic nitrogens and two nitrogens from sigma coordinated TCNQ(-). The overlap with a neighbouring 7,7,8,8-tetracyanoquinodimethane (TCNQ) forms the diamagnetic dianion [TCNQ](2)(2-), and the whole structure can be seen as chains of metallomacrocyclic cations and TCNQ dianions alternating in the solid. The crystal structure of [Cu([15] aneN(4))(TCNQ)(2)] confirms this fact. With open chain tetraamines the derivatives [Cu(trien)(TCNQ)(2)] and [Cu(tren)(TCNQ)(2)] are proposed to have the copper in a pentacoordinated environment, with only one coordinated TCNQ. In [M(trans-dieneN(4))](TCNQ)(2) both TCNQ(-) are uncoordinated and dimerized, as the crystal structure of the nickel derivative confirms. The derivatives with three TCNQ [M(aneN4)(TCNQ)2](TCNQ) are proposed to have a structure derived from that of the analogous [M(aneN(4))(TCNQ)(2)], based on the metallomacrocycle-[TCNQ](2) chains connected through the extra TCNQ which remains uncoordinated and overlaps with the coordinated anions. This fact lowers the antiferromagnetic coupling inside the dimers and a small contribution for a thermally activated triplet state is observed in the magnetic susceptibility of these compounds. (C) 2003 Elsevier B.V. All rights reserved.
• Micheloni, Mauro; Paoletti, Piero; Sabatini, Antonio, Journal of the Chemical Society, Dalton Transactions, 1983, p. 1189 - 1192
  作者：Micheloni, Mauro、Paoletti, Piero、Sabatini, Antonio

  DOI：——

  日期：——
• Jubran, Nusrallah; Meyerstein, Dan; Koresh, Jacob, Journal of the Chemical Society, Dalton Transactions, 1986, p. 2509 - 2514
  作者：Jubran, Nusrallah、Meyerstein, Dan、Koresh, Jacob、Cohen, Haim

  DOI：——

  日期：——