bis(3,5-dimethylpyrazole)bis(trimethylacetato)bis(μ-N,N'-3,5-dimethylpyrazolato)dicobalt(II) | 615251-39-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: bis(3,5-dimethylpyrazole)bis(trimethylacetato)bis(μ-N,N'-3,5-dimethylpyrazolato)dicobalt(II)
• 英文别名: [Co2(trimetylacetate)2(μ-3,5-dimethylpyrazole(-1H))2(3,5-dimethylpyrazole)2]；Co2(μ-3,5-dimethylpyrazole(-1H))2(3,5-dimethylpyrazole)2(OOC(t-Bu))2；Co2(3,5-dimethylpyrazole)2(μ-3,5-dimethylpyrazolate)2(OOC(t-Bu))2；[Co2(μ-3,5-dimethylpyrazolato)2(3,5-dimethylpyrazole)(pivalato)2]；[Co2(pivalate)2(μ-dmpz)2(Hdmpz)2]；Co2(μ-dmpz)2(Hdmpz)2(OOC(t-Bu))2
• CAS: 615251-39-3
• 化学式: C₃₀H₄₈Co₂N₈O₄
• 分子量: 702.749
• InChiKey: MGDYZOHZCACMIM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(3,5-dimethylpyrazole)bis(trimethylacetato)bis(μ-N,N'-3,5-dimethylpyrazolato)dicobalt(II) 、 三甲基乙酸 在 air 作用下， 以 四氢呋喃 为溶剂， 以35%的产率得到[Co2(μ-trimetylacetate)2(μ-H2O)(μ-3,5-dimethylpyrazole(-1H))2(3,5-dimethylpyrazole)2]
  参考文献：
  名称：

  Transformations of cobalt trimethylacetate complexes with pyrazole upon oxidation by air in THF

  摘要：

  Synthetic routes to oxidation of cobalt atoms in cobalt trimethylacetate complexes containing coordinated pyrazole molecules have been considered.

  DOI：

  10.1134/s0036023606090063
• 作为产物：
  描述：

  3,5-二甲基吡唑 、 cobalt(II) acetate 、 三甲基乙酸 在 triethylamine 作用下， 以 正己烷 为溶剂， 以99%的产率得到bis(3,5-dimethylpyrazole)bis(trimethylacetato)bis(μ-N,N'-3,5-dimethylpyrazolato)dicobalt(II)
  参考文献：
  名称：

  Synthesis and structure of electron-deficient trimethylacetatocobalt(II) 3,5-dimethylpyrazole complexes, which are structural analogs of the active site of metalloenzymes

  摘要：

  The formation laws of [Co-2(mu-OOCR)(2)L-4](2+) binuclear complexes, which model the active site of metalloenzymes, are studied.

  DOI：

  10.1134/s0036023606090051

文献信息

• Binuclear transition-metal trimethylacetato complexes containing coordinated 3,5-dimethylpyrazole as structural analogues of the active site of natural metalloenzymes
  作者：S. E. Nefedov

  DOI：10.1134/s0036023606130031

  日期：2006.1

  Synthetic approaches are discussed to prepare binuclear trimethylacetato complexes of zinc, copper, cobalt, and nickel containing an M-2(mu-OOCR)(2)L-4 binuclear fragment, which is found in the active site of natural metalloenzymes.
• Synthesis and molecular structures of the Co3(μ-OOCPh)4(μ,η2-OOCPh)2[OC(Ph)OHNEt3]2 and Co(Hdmpz)2(OOCPh)2 complexes (Hdmpz = 3,5-dimethylpyrazole)
  作者：I. V. Anan’ev、M. A. Yakovleva、E. V. Perova、S. E. Nefedov

  DOI：10.1134/s0036023610070119

  日期：2010.7

  The product of the thermal reaction between cobalt acetate hydrate and benzoic acid reacts with a triethylamine excess to form the trinuclear complex Co-3(mu-OOCPh)(4)(mu,eta(2)-OOCPh)(2)[OC(Ph)OHNEt3](2), and its reaction with 3,5-dimethylpyrazole yields the mononuclear complex Co(Hdmpz)(2)(OOCPh)(2). The compound structures are discussed on the basis of X-ray crystallographic data.
• 10.1023/a:1023912318637
  作者：Denisova、Nefedov

  DOI：10.1023/a:1023912318637

  日期：——