(3-Methoxy-phenyl)-phenyl-phosphin | 92025-79-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (3-Methoxy-phenyl)-phenyl-phosphin
• 英文别名: (4-Methoxy-phenyl)-phenyl-phosphin；p-Methoxyphenyl-phenylphosphin；4-Methoxyphenyl-phenylphosphin；(4-methoxyphenyl)-phenylphosphane
• CAS: 92025-79-1
• 化学式: C₁₃H₁₃OP
• 分子量: 216.219
• InChiKey: GIBGICPSIBQCGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (4-methoxyphenyl)diphenylphosphane 在 氨 、 sodium 作用下， 反应 4.0h， 以27%的产率得到二苯基膦
  参考文献：
  名称：

  Doorn, Johannes A. van; Frijns, John H. G.; Meijboom, Nico, Recueil des Travaux Chimiques des Pays-Bas, 1991, vol. 110, # 11, p. 441 - 449

  摘要：

  DOI：

文献信息

• [EN] METHOD FOR SYNTHESIZING IODO- OR ASTATOARENES USING DIARYLIODONIUM SALTS<br/>[FR] PROCÉDÉ DE SYNTHÈSE D'IODO- OU D'ASTATOARÈNES EN UTILISANT DES SELS DE DIARYLIODONIUM
  申请人：INST NAT DE LA SANTE ET DE LA RECH MEDICALE (INSERM)

  公开号：WO2017089492A1

  公开（公告）日：2017-06-01

  The present invention concerns a method of synthesizing a iodo- or astatoarene comprising the reaction of a diaryliodonium compound with a iodide or astatide salt, respectively. The invention also relates to said iodo- or astatoarene and diaryliodonium compound as such. The invention also concerns a method of synthesizing a iodo- or astatolabelled biomolecule and/or vector using said iodo- or astatoarene.

  本发明涉及一种合成碘或氨基碘芳烃的方法，包括将二芳基碘化铵化合物分别与碘化物或氨基碘化物盐发生反应。该发明还涉及所述碘或氨基碘芳烃和二芳基碘化铵化合物本身。该发明还涉及使用所述碘或氨基碘芳烃合成碘或氨基碘标记的生物分子和/或载体的方法。
• Method for synthesizing iodo- or astatoarenes using diaryliodonium salts
  申请人：INSTITUT NATIONAL DE LA SANTE ET DE LA RECHERCHE MEDICALE (INSERM)

  公开号：US10703708B2

  公开（公告）日：2020-07-07

  The present invention concerns a method of synthesizing a iodo- or astatoarene comprising the reaction of a diaryliodonium compound with a iodide or astatide salt, respectively. The invention also relates to said iodo- or astatoarene and diaryliodonium compound as such. The invention also concerns a method of synthesizing a iodo- or astatolabelled biomolecule and/or vector using said iodo- or astatoarene.

  本发明涉及一种合成碘烷烃或砹烷烃的方法，包括二碘鎓化合物分别与碘化物或砹化盐反应。本发明还涉及上述碘烷烃或砹烷烃和二里碘鎓化合物本身。本发明还涉及使用所述碘或砹化合物合成碘或砹标记的生物分子和/或载体的方法。
• Process for preparing diaryl carbonate
  申请人：Ube Industries, Ltd.

  公开号：EP0834495B1

  公开（公告）日：2000-12-27
• Preparation of diaryl carbonate
  申请人：Ube Industries, Ltd.

  公开号：EP0834496B1

  公开（公告）日：2001-08-16
• METHOD FOR SYNTHESIZING IODO- OR ASTATOARENES USING DIARYLIODONIUM SALTS
  申请人：INSTITUT NATIONAL DE LA SANTE ET DE LA RECHEARCHE MEDICALE (INSERM)

  公开号：US20190023646A1

  公开（公告）日：2019-01-24

  The present invention concerns a method of synthesizing a iodo- or astatoarene comprising the reaction of a diaryliodonium compound with a iodide or astatide salt, respectively. The invention also relates to said iodo- or astatoarene and diaryliodonium compound as such. The invention also concerns a method of synthesizing a iodo- or astatolabelled biomolecule and/or vector using said iodo- or astatoarene.