allyl dibromoacetate | 90448-98-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: allyl dibromoacetate
• 英文别名: prop-2-enyl 2,2-dibromoacetate
• CAS: 90448-98-9
• 化学式: C₅H₆Br₂O₂
• 分子量: 257.909
• InChiKey: BQKSBGWDSUKUDU-UHFFFAOYSA-N

物化性质

• 沸点：
  66-67 °C(Press: 10 Torr)
• 密度：
  1.4500 g/cm3
• 保留指数：
  1114

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  allyl dibromoacetate 、 六氯环戊二烯 反应 10.0h， 以78.2%的产率得到1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-enylmethyl dibromoacetate
  参考文献：
  名称：

  Synthesis of hexachlorobicyclo[2.2.1]hept-5-enylmethyl haloacetates

  摘要：

  The possibility of preparing hexachlorobicyclo[2.2.1]hept-5-enylmethyl haloacetates by reactions of hexachlorocyclopentadiene with allyl haloacetates was examined. The optimal conditions for preparing the esters were found. The structures of the compounds prepared were proved by IR and H-1 NMR spectroscopy.

  DOI：

  10.1134/s1070427209020220
• 作为产物：
  描述：

  二溴乙酸 、 烯丙醇 在 硫酸 作用下， 以 苯 为溶剂， 以60%的产率得到allyl dibromoacetate
  参考文献：
  名称：

  Synthesis of 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hept-5-enylmethyl haloacetates

  摘要：

  The possibility of preparing 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1] hept-5-enylmethyl haloacetates by the reaction of tetrachlorodimethoxycyclopentadiene with allyl haloacetates was examined. The effect of various factors on the product yield was studied, and the optimal synthesis conditions were found.

  DOI：

  10.1134/s1070427209010194

文献信息

• Radical cyclization of allyl α-bromocarboxylates into λ-butyrolactones. Effect of the ester structure on the cyclization
  作者：A. B. Terent'ev、T. T. Vasil'eva、N. A. Kuz'mina、N. S. Ikonnikov、S. A. Orlova、E. I. Mysov、Yu. N. Belokon'

  DOI：10.1007/bf02495259

  日期：1997.12

  Allyl dibromoacetate, allyl α-bromopropionate, and allyl phenylbromoacetate undergo cyclization in benzene in the presence of increased concentration of Fe(CO)5—DMF as the initiating system to give the corresponding bromo-substituted butyrolactones.

  二溴乙酸烯丙酯、α-溴丙酸烯丙酯和苯基溴乙酸烯丙酯在浓度增加的 Fe(CO)5-DMF 作为引发体系的存在下在苯中发生环化反应，得到相应的溴代丁内酯。
• Synthesis of bicyclo[2.2.1]hept-5-enyl methyl esters of haloacetic acids
  作者：T. G. Kyazimova、E. G. Mamedbeili、A. V. Nagiev、E. I. Suleimanova、Kh. S. Khalilov

  DOI：10.1134/s1070427208100182

  日期：2008.10

  Synthesis of norbornenyl methyl esters of a number of haloacetic acids via [4+2] cycloaddition of cyclopentadiene to allyl esters of these acids was examined. The yield and isomer composition of the synthesized compounds were examined in relation to the reaction conditions, and the best conditions for their preparation were found.
• KYAZIMOVA, T. G.;BABAEV, R. S., ISSLED. V OBL. SINTEZA MONOMER. I POLIMER. PRODUKTOV, BAKU,(1987) 57-61
  作者：KYAZIMOVA, T. G.、BABAEV, R. S.

  DOI：——

  日期：——
• Synthesis of 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hept-5-enylmethyl haloacetates
  作者：T. G. Kyazymova、E. G. Mamedbeili、O. B. Abdiev、Z. M. Nagiev、S. T. Alieva、A. V. Nagiev

  DOI：10.1134/s1070427209010194

  日期：2009.1

  The possibility of preparing 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1] hept-5-enylmethyl haloacetates by the reaction of tetrachlorodimethoxycyclopentadiene with allyl haloacetates was examined. The effect of various factors on the product yield was studied, and the optimal synthesis conditions were found.
• Synthesis of hexachlorobicyclo[2.2.1]hept-5-enylmethyl haloacetates
  作者：E. G. Mamedbeili (Mamedov)、T. G. Kyazimova、Kh. I. Gasanov、O. B. Abdiev、I. M. Mamedova

  DOI：10.1134/s1070427209020220

  日期：2009.2

  The possibility of preparing hexachlorobicyclo[2.2.1]hept-5-enylmethyl haloacetates by reactions of hexachlorocyclopentadiene with allyl haloacetates was examined. The optimal conditions for preparing the esters were found. The structures of the compounds prepared were proved by IR and H-1 NMR spectroscopy.