3-溴-2-碘-9,9-二甲基-9H-芴 | 1346635-65-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 中文名称: 3-溴-2-碘-9,9-二甲基-9H-芴
• 英文名称: 3-bromo-2-iodo-9,9-diimethyl-9H-fluorene
• 英文别名: 3-bromo-2-iodo-9,9-dimethyl-9H-fluorene；3-bromo-2-iodo-9,9-dimethylfluorene
• CAS: 1346635-65-1
• 化学式: C₁₅H₁₂BrI
• 分子量: 399.069
• InChiKey: DWYKLFPUSWLWOQ-UHFFFAOYSA-N

物化性质

• 沸点：
  414.4±40.0 °C(Predicted)
• 密度：
  1.773±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为反应物：
  描述：

  3-溴-2-碘-9,9-二甲基-9H-芴 在 1,1'-双(二苯基膦)二茂铁 、 异丙基氯化镁 、 palladium diacetate 、 sodium t-butanolate 、 tri tert-butylphosphoniumtetrafluoroborate 作用下， 以 四氢呋喃 、 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 1.08h， 生成 9,9-dimethyl-2-(propyl-2-yl-1,1,1,3,3,3-d6)-N-(4-(propyl-2-yl-1,1,1,3,3,3-d6)-[1,1'-biphenyl]-3-yl)-9H-fluorene-3-amine
  参考文献：
  名称：

  芳香族アミン誘導体、およびそれを含む有機エレクトロルミネセント素子

  摘要：

  为了获得更高的器件效率、更长的器件寿命以及更蓝的发光等，进一步开发荧光发光材料。本发明揭示了芳香族胺衍生物以及包含其的有机电致发光器件。所述芳香族胺衍生物引入了具有醌基的芴/硅芴基于其结构，并可用作有机电致发光器件的发光层中的发光材料。这些新化合物可以提供更好的器件性能。【选项图】无

  公开号：

  JP2021031496A
• 作为产物：
  描述：

  3-bromo-9,9-dimethyl-9H-fluoren-2-amine 在 盐酸 、 sodium nitrite 、 potassium iodide 作用下， 以 水 为溶剂， 反应 0.5h， 以80%的产率得到3-溴-2-碘-9,9-二甲基-9H-芴
  参考文献：
  名称：

  用于高效绿色磷光有机发光二极管的 2,3-二取代芴支架

  摘要：

  2,3-二取代芴平台用于构建绿色磷光有机发光二极管的高效主体材料。

  DOI：

  10.1002/chem.202200756

文献信息

• [EN] NOVEL ORGANIC COMPOUND<br/>[FR] NOUVEAU COMPOSÉ ORGANIQUE
  申请人：CANON KK

  公开号：WO2011138907A1

  公开（公告）日：2011-11-10

  There are provided a novel organic compound that has an excellent luminescent hue and that can produce high-efficiency, high-intensity, and long light output, and an organic light-emitting device containing the novel organic compound. There are provided an organic compound represented by the following general formular (I), which can emit green light with high color purity, and an organic light device containing this compound. [wherein X1 to X3 independently denote a hydrogen atom, an alkyl groups, or an aryl groups.]

  提供了一种新型的有机化合物，具有优异的发光色调，能够产生高效、高强度和长时间的光输出，并且提供了一种含有该新型有机化合物的有机发光器件。提供了一种由以下通式（I）表示的有机化合物，该化合物能够以高色纯度发射绿光，并且提供了一种含有该化合物的有机发光器件。【其中X1至X3独立地表示氢原子、烷基或芳基。】
• NOVEL ORGANIC COMPOUND
  申请人：Yamada Naoki

  公开号：US20130043463A1

  公开（公告）日：2013-02-21

  There are provided a novel organic compound that has an excellent luminescent hue and that can produce high-efficiency, high-intensity, and long-life light output, and an organic light-emitting device containing the novel organic compound. There are provided 12,12-dimethyl-12H-benzo[5,6]-s-indaceno[1,2,3-cd]pyrene having a substituent at a particular position, which can emit green light with high color purity, and an organic light-emitting device containing this compound. The substituent at a particular position is selected from a hydrogen atom, substituted and unsubstituted alkyl groups, and substituted and unsubstituted aryl groups.
• NOVEL CONDENSED POLYCYCLIC COMPOUND
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20140110687A1

  公开（公告）日：2014-04-24

  Provided is a novel indenochrysene compound serving as a guest compound suitable for a guest material. In particular, the novel indenochrysene compound is represented by Formula (1), where R 1 to R 14 are independently selected from hydrogen atoms and alkyl groups containing one to four carbon atoms, one of X 1 and X 2 is an aryl group, and the other one is a hydrogen atom.
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICES CONTAINING THE SAME
  申请人：BEIJING SUMMER SPROUT TECHNOLOGY CO., LTD.

  公开号：US20210066595A1

  公开（公告）日：2021-03-04

  Disclosed are an aromatic amine derivative and an organic electroluminescent device including the same. A fluorenyl/silafluorenyl group having an ortho-substituted group is introduced into the structure of the aromatic amine derivative. The aromatic amine derivative may be used as a light-emitting material in a light-emitting layer of an organic electroluminescent device. These novel compounds can provide better device performance.
• METAL COMPLEXES
  申请人：Merck Patent GmbH

  公开号：US20210175441A1

  公开（公告）日：2021-06-10

  The present invention relates to iridium complexes suitable for use in organic electroluminescent devices, especially as emitters.