3,5-bis(ferrocenyl)pyridine | 1365840-05-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3,5-bis(ferrocenyl)pyridine
• 英文别名: cyclopenta-1,3-diene;3,5-di(cyclopenta-2,4-dien-1-yl)pyridine;iron(2+)
• CAS: 1365840-05-6
• 化学式: C₂₅H₂₁Fe₂N
• 分子量: 447.142
• InChiKey: JLHINKFOEKXORV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  双(乙腈)氯化钯(II) 、 3,5-bis(ferrocenyl)pyridine 、 水 以 氯仿 为溶剂， 以60%的产率得到[PdCl2(3,5-bis(ferrocenyl)pyridine)2]*H2O
  参考文献：
  名称：

  3,5-Diferrocenylpyridine: Synthesis, characterisation, palladium(II) dichloride complex and electrochemistry

  摘要：

  3,5-Diferrocenylpyridine was synthesised from 3,5-dibromopyridine and ferroceneboronic acid, in respectable yield (48%), using a microwave-enhanced Suzuki cross-coupling reaction. This novel ligand and its palladium(II) dichloride complex have been fully characterised using elemental analysis. HR-ESI-MS, IR, UV and NMR spectroscopy. Additionally, the molecular structures of 3,5-diferrocenylpyridine and [Pd(3,5-diferrocenylpyridine)(2)Cl-2] were confirmed by X-ray crystallography. A comprehensive study of the electrochemistry of 3-ferrocenylpyridine, 3,5-diferrocenylpyridine and their palladium(II) dichloride complexes was performed using traditional hexafluorophosphate and weakly-coordinating fluorinated aryl borate anions. Electronic communication between the two proximal ferrocenyl centres of 3,5-diferrocenylpyridine and its palladium complex is only observed when the weakly-coordinating fluorinated aryl borate anions are used as the supporting electrolyte. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.01.028
• 作为产物：
  描述：

  3,5-二溴吡啶 、 ferrocene boronic acid 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride Na₂CO₃ 、 NaOH 作用下， 以 1,4-二氧六环 、 乙二醇二甲醚 、 水 为溶剂， 以48%的产率得到3,5-bis(ferrocenyl)pyridine
  参考文献：
  名称：

  3,5-Diferrocenylpyridine: Synthesis, characterisation, palladium(II) dichloride complex and electrochemistry

  摘要：

  3,5-Diferrocenylpyridine was synthesised from 3,5-dibromopyridine and ferroceneboronic acid, in respectable yield (48%), using a microwave-enhanced Suzuki cross-coupling reaction. This novel ligand and its palladium(II) dichloride complex have been fully characterised using elemental analysis. HR-ESI-MS, IR, UV and NMR spectroscopy. Additionally, the molecular structures of 3,5-diferrocenylpyridine and [Pd(3,5-diferrocenylpyridine)(2)Cl-2] were confirmed by X-ray crystallography. A comprehensive study of the electrochemistry of 3-ferrocenylpyridine, 3,5-diferrocenylpyridine and their palladium(II) dichloride complexes was performed using traditional hexafluorophosphate and weakly-coordinating fluorinated aryl borate anions. Electronic communication between the two proximal ferrocenyl centres of 3,5-diferrocenylpyridine and its palladium complex is only observed when the weakly-coordinating fluorinated aryl borate anions are used as the supporting electrolyte. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.01.028