15,17-Diphenylhexacyclo[11.9.1.02,11.05,10.014,18.019,23]tricosa-1,3,5,7,9,11,13(23),14,17,19,21-undecaen-16-one | 1068155-35-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 15,17-Diphenylhexacyclo[11.9.1.02,11.05,10.014,18.019,23]tricosa-1,3,5,7,9,11,13(23),14,17,19,21-undecaen-16-one
• CAS: 1068155-35-0
• 化学式: C₃₅H₂₀O
• 分子量: 456.543
• InChiKey: OREDUESGJGYMKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  36
• 可旋转键数：
  2
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  15,17-Diphenylhexacyclo[11.9.1.02,11.05,10.014,18.019,23]tricosa-1,3,5,7,9,11,13(23),14,17,19,21-undecaen-16-one 、 邻氨基苯甲酸 在 亚硝酸异戊酯 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以80%的产率得到3,10-Diphenylheptacyclo[14.11.1.02,11.04,9.012,28.017,26.020,25]octacosa-1(28),2,4,6,8,10,12,14,16,18,20,22,24,26-tetradecaene
  参考文献：
  名称：

  [EN] BENZOINDENOCHRYSENE COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE USING THE SAME
  [FR] COMPOSÉ DE BENZOINDÉNOCHRYSÈNE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE UTILISANT CE COMPOSÉ

  摘要：

  有机发光器件具有高效率、高亮度、良好的色纯度和耐久性的光发射。有机发光器件包括阳极、阴极和位于阳极和阴极之间的有机化合物层，其中有机化合物层的至少一层包括至少一种由通用公式[1]表示的苯并吲哚基芴化合物，其中X1至X16分别独立地表示氢原子、卤素原子、氰基、硝基、取代或未取代的烷基、取代或未取代的烷氧基、取代或未取代的烯基、取代或未取代的炔基、取代或未取代的芳基、取代氨基、取代或未取代的芳基、取代或未取代的杂环基或取代或未取代的芳氧基。

  公开号：

  WO2010067757A1
• 作为产物：
  描述：

  Pentacyclo[11.6.1.02,11.05,10.016,20]icosa-1,3,5,7,9,11,13(20),16,18-nonaene-14,15-dione 、 二苄基甲酮 在 potassium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 生成 15,17-Diphenylhexacyclo[11.9.1.02,11.05,10.014,18.019,23]tricosa-1,3,5,7,9,11,13(23),14,17,19,21-undecaen-16-one
  参考文献：
  名称：

  [EN] BENZOINDENOCHRYSENE COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE USING THE SAME
  [FR] COMPOSÉ DE BENZOINDÉNOCHRYSÈNE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE UTILISANT CE COMPOSÉ

  摘要：

  有机发光器件具有高效率、高亮度、良好的色纯度和耐久性的光发射。有机发光器件包括阳极、阴极和位于阳极和阴极之间的有机化合物层，其中有机化合物层的至少一层包括至少一种由通用公式[1]表示的苯并吲哚基芴化合物，其中X1至X16分别独立地表示氢原子、卤素原子、氰基、硝基、取代或未取代的烷基、取代或未取代的烷氧基、取代或未取代的烯基、取代或未取代的炔基、取代或未取代的芳基、取代氨基、取代或未取代的芳基、取代或未取代的杂环基或取代或未取代的芳氧基。

  公开号：

  WO2010067757A1

文献信息

• [EN] NOVEL FUSED POLYCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME<br/>[FR] NOUVEAU COMPOSÉ POLYCYCLIQUE CONDENSÉ ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE COMPRENANT CELUI-CI
  申请人：CANON KK

  公开号：WO2010116661A1

  公开（公告）日：2010-10-14

  Provided is a fused polycyclic compound represented by general formula 1: (In general formula 1, at least one of R1 to R4 is a group selected from a substituted or unsubstituted aryl group and a substituted or unsubstituted heterocyclic group, and R1 to R4 may be the same as or different from each other.)

  提供的是由通式1表示的融合多环化合物：（在通式1中，R1至R4中至少有一个是从取代或未取代芳基团和取代或未取代杂环基团中选择的基团，且R1至R4可以相同也可以不同。）
• [EN] FUSED POLYCYCLIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE HAVING THE COMPOUND<br/>[FR] COMPOSÉ POLYCYCLIQUE FUSIONNÉ ET DISPOSITIF ÉMETTANT DE LA LUMIÈRE ORGANIQUE AYANT LE COMPOSÉ
  申请人：CANON KK

  公开号：WO2009142314A1

  公开（公告）日：2009-11-26

  Provided are a fused polycyclic compound by the following general formula (I), which obtained by expanding the conjugated system of a chrysene skeleton, and an organic light emitting device using the compound. The organic light emitting device has an optical output with high efficiency and high luminance, and is extremely durable. Formula (I) where R1 to R8 are each independently selected from the group consisting of a hydrogen atom, a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted aryl group, and a substituted or unsuhstituted heterocyclic group.

  提供了一个由下列通式（I）扩展花菁骨架的共轭系统融合多环化合物，以及使用该化合物的有机发光器件。该有机发光器件具有高效率和高亮度的光学输出，并且非常耐用。式（I）中R1至R8各自独立地选自氢原子、卤素原子、氰基、硝基、取代或未取代的烷基、取代或未取代的烷氧基、取代或未取代的烯基、取代或未取代的炔基、取代或未取代的芳基烷基、取代或未取代的氨基、取代或未取代的芳基和取代或未取代的杂环基的群。
• JP5774076
  申请人：——

  公开号：——

  公开（公告）日：——
• CONDENSED RING AROMATIC COMPOUND FOR ORGANIC LIGHT-EMITTING DEVICE AND ORGANIC LIGHT-EMITTING DEVICE HAVING THE SAME
  申请人：Negishi Chika

  公开号：US20100026171A1

  公开（公告）日：2010-02-04

  Provided are a condensed ring aromatic compound for an organic light-emitting device, and an organic light-emitting device having optical output with high efficiency and high luminescence and having durability. An organic light-emitting device including an anode and a cathode, and a layer made of an organic compound interposed between the anode and the cathode, wherein at least one layer of the layers made of the organic compound contains a condensed ring aromatic compound shown in the following general formula [1]: wherein R 1 to R 16 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted amino group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group, and may be the same or different.
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Okajima Maki

  公开号：US20100327274A1

  公开（公告）日：2010-12-30

  An organic blue-light-emitting device having a high emission efficiency and a long continuous driving lifetime is provided. An organic light-emitting device 20 includes an anode 2 , a cathode 5 , and a stacked body which is interposed between the anode 2 and the cathode 5 and includes at least a layer which forms a light-emitting region (emission layer 6 ). The layer which forms the light-emitting region includes at least one of each of below-mentioned compounds (a) and (b): (a) a first organic compound represented by the following general formula [1] or general formula [2]: (b) a second organic compound represented by the following general formula [3] or general formula [4]: