N,N'-1,3-phenylenebis(methanesulfonamide) | 6966-38-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-1,3-phenylenebis(methanesulfonamide)
• 英文别名: N-{3-[(methylsulfonyl)amino]phenyl}methanesulfonamide；N,N'-(1,3-Phenylene)dimethanesulfonamide；N-[3-(methanesulfonamido)phenyl]methanesulfonamide
• CAS: 6966-38-7
• 化学式: C₈H₁₂N₂O₄S₂
• mdl: MFCD02371679
• 分子量: 264.326
• InChiKey: PXOGNCFAMBPAMU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-1,3-phenylenebis(methanesulfonamide) 在 sodium acetate 、 一氯化碘 、 溶剂黄146 作用下， 以86%的产率得到N,N'-(4,6-diiodo-1,3-phenylene)di(methanesulfonamide)
  参考文献：
  名称：

  Efficient Synthesis of Aminomethylated Pyrroloindoles and Dipyrrolopyridines via Controlled Copper-Catalyzed Domino Multicomponent Coupling and Bis-cyclization

  摘要：

  Efficient methods for the synthesis of pyrrole-fused indole derivatives via domino copper-catalyzed multicomponent coupling and bis-cyclization have been developed. The mono- or bis-aminomethylated pyrroloindoles and dipyrrolopyridines were selectively obtained in moderate to excellent yields by a controlled Mannich-type reaction-cyclization of 4,6-diethynyl-1,3-phenylenediamine or its pyridine congener with paraformaldehyde and a secondary amine. The high-yielding bis-cyclization of terminal alkynes without using Mannich-type reactions is also presented.

  DOI：

  10.1021/jo900681p
• 作为产物：
  描述：

  间苯二胺 、 甲基磺酰氯 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 以97%的产率得到N,N'-1,3-phenylenebis(methanesulfonamide)
  参考文献：
  名称：

  Methanesulfonanilides and the Mannich reaction

  摘要：

  DOI：

  10.1021/jo00228a041

文献信息

• NOVEL COMPOUND HAVING MULTIMER STRUCTURE OF XANTHENE DERIVATIVE, COLORING COMPOSITION, INK FOR INKJET RECORDING, METHOD OF INKJET RECORDING, COLOR FILTER, AND COLOR TONER
  申请人：FUJIFILM CORPORATION

  公开号：US20140176653A1

  公开（公告）日：2014-06-26

  There is provided a compound represented by formula (1): in formula (1), L represents a divalent to tetravalent linking group; D represents a residue obtained by removing 1 to 5 hydrogen atoms from a compound represented by formula (2); m represents an integer of 1 to 10, however, each L may be the same with or different from every other L; n represents an integer of 2 to 10, however, each D may be the same with or different from every other D; and in formula (2), each of R 4 to R 24 independently represents a hydrogen atom or a substituent, provided that formula (2) has at least one or more ionic hydrophilic groups.

  提供了一种由公式(1)表示的化合物：在公式(1)中，L代表二价到四价的连接基团；D代表通过从由公式(2)表示的化合物中去除1到5个氢原子获得的残基；m代表1到10的整数，但是，每个L可以相同也可以不同于其他L；n代表2到10的整数，但是，每个D可以相同也可以不同于其他D；在公式(2)中，R4到R24中的每一个独立地代表一个氢原子或一个取代基，前提是公式(2)至少有一个或更多的离子亲水基团。
• TRIAZINE-BASED COMPOUND AND ULTRAVIOLET ABSORBER
  申请人：AMASAKI Ichiro

  公开号：US20120053343A1

  公开（公告）日：2012-03-01

  A compound represented by the following formula (1): wherein each of R 1b , R 1c , R 1d , R 1g , R 1h , R 1i , R 1k , R 1m , R 1n and R 1p independently represents a hydrogen atom or a monovalent substituent, the monovalent substituents may combine with each other to form a ring, provided that at least one of R 1c and R 1h represents a hydrogen atom or a substituent having a positive σp value of the Hammett's rule, each of R 1a , R 1e , R 1f and R 1j independently represents a hydrogen atom or a monovalent substituent excluding —NHY 1 and —OH, Y 1 represents —COR 1q or —SO 2 R 1r , and each of R 1q and R 1r independently represents a monovalent substituent.

  以下公式（1）所代表的化合物：其中R1b、R1c、R1d、R1g、R1h、R1i、R1k、R1m、R1n和R1p中的每一个独立地代表氢原子或一价取代基，这些一价取代基可以相互结合形成环，前提是R1c和R1h中至少有一个代表氢原子或具有Hammett规则的正σp值的取代基，R1a、R1e、R1f和R1j中的每一个独立地代表氢原子或一价取代基，但不包括—NHY1和—OH，Y1代表—COR1q或—SO2R1r，R1q和R1r中的每一个独立地代表一价取代基。
• SULFONAMIDES. A NEW CLASS OF CHELATING AGENTS OF POTENTIAL UTILITY IN ANALYTICAL AND SEPARATION CHEMISTRY
  作者：Makoto Takagi、Takashi Omori、Shuji Matsuo、Shugo Matsuno、Keihei Ueno、Shunsuke Ide

  DOI：10.1246/cl.1980.387

  日期：1980.4.5

  New sulfonamide chelating agents were synthesized, and the complexation behavior was studied by solvent extraction method. The metal selectivity is strikingly different from the conventional solvent extraction agents. The outlook of this class of reagents in analytical and separation chemistry is discussed.

  合成了新型磺酰胺螯合剂，并采用溶剂萃取法研究了其络合行为。金属选择性明显不同于传统的溶剂萃取剂。讨论了该类试剂在分析分离化学中的应用前景。
• LIS, RANDALL;MARISCA, ANTHONY J., J. ORG. CHEM., 52,(1987) N 19, 4377-4379
  作者：LIS, RANDALL、MARISCA, ANTHONY J.

  DOI：——

  日期：——
• Triazine-based compound and ultraviolet absorber
  申请人：Fujifilm Corporation

  公开号：EP2423202B1

  公开（公告）日：2013-01-16