3-methyl-4-(2-phenylethyl)furazan | 627904-50-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-methyl-4-(2-phenylethyl)furazan
• 英文别名: 3-methyl-4-phenethyl-1,2,5-oxadiazole；3-Methyl-4-(2-phenylethyl)-1,2,5-oxadiazole
• CAS: 627904-50-1
• 化学式: C₁₁H₁₂N₂O
• 分子量: 188.229
• InChiKey: VZGSTCHMUAXAFO-UHFFFAOYSA-N

物化性质

• 沸点：
  115 °C(Press: 20 Torr)
• 密度：
  1.117±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  38.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-methyl-4-(2-phenylethyl)furazan 在 正丁基锂 、 copper(l) chloride 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 反应 10.83h， 以43%的产率得到1,2-bis[4-(2-phenylethyl)furazan-3-yl]ethane
  参考文献：
  名称：

  摘要：

  The reactions of Li derivatives of methylfurazans with electrophilic reagents and oxidants were investigated. A series of functionalized furazanylethane derivatives were prepared.

  DOI：

  10.1023/a:1023967008642
• 作为产物：
  描述：

  3,4-二甲基-1,2,5-噁二唑 、 氯化苄 在 正丁基锂 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 反应 1.83h， 以80%的产率得到3-methyl-4-(2-phenylethyl)furazan
  参考文献：
  名称：

  摘要：

  The reactions of Li derivatives of methylfurazans with electrophilic reagents and oxidants were investigated. A series of functionalized furazanylethane derivatives were prepared.

  DOI：

  10.1023/a:1023967008642

文献信息

• Organometallic synthesis in the furazan series. 3. Silyl derivatives of methylfurazans
  作者：A. B. Sheremetev、E. A. Ivanova

  DOI：10.1023/b:rucb.0000009646.85254.27

  日期：2003.9

  The reactions of (lithiomethyl)furazans with chlorosilanes were investigated and a number of silyl derivatives of methylfurazans were prepared. The reactivity of these compounds was studied.
• ——
  作者：A. B. Sheremetev

  DOI：10.1023/a:1023967008642

  日期：——

  The reactions of Li derivatives of methylfurazans with electrophilic reagents and oxidants were investigated. A series of functionalized furazanylethane derivatives were prepared.