[Ru(η5-C5Me5)(PPh3)2(-C≡CH)] | 192517-32-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(η5-C5Me5)(PPh3)2(-C≡CH)]
• 英文别名: ethyne;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;ruthenium(2+);triphenylphosphane
• CAS: 192517-32-1
• 化学式: C₄₈H₄₆P₂Ru
• 分子量: 785.911
• InChiKey: VSYIYZMQVKUYDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(η5-C5Me5)(PPh3)2(-C≡CH)] 、 二叔丁基氯化膦 在 正丁基锂 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 以90%的产率得到ditert-butyl(ethynyl)phosphane;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;ruthenium(2+);triphenylphosphane
  参考文献：
  名称：

  Ethinylkomplexe des Rutheniums mit terminalen Hauptgruppenelement-Substituenten: Systematischer Aufbau metallgebundener Phosphoniumacetylid-Liganden R′R2P(+)-C≡C|(−)

  摘要：

  Treatment of Cp* RuL2Cl (Cp* = C5Me5; L = PPh3, PMe3) with Me3SiC=C:H in the presence of NH4[PF6] in CH2Cl2 yielded the expected vinylidene compounds [Cp *RuL2=C=CH2][PF6] with L = PPh3 (1) and PMe3 (1a), which were deprotonated by KOBut in THF to give the corresponding ethynyl complexes Cp*Ru(PPh3)(2)C=CH (2) and Cp*Ru(PMe3)(2)C=CH (2a). Metalation of 2 using n-BuLi or t-BuLi in THF-hexane, followed by reaction of the lithio intermediate Cp*Ru(PPh3)(2)C=CLi with CIER3 (E = Si, Ge, Sn) or ClPR2, resulted in the formation of substituted derivatives, Cp*Ru(PPh3)(2)C=CER3 [ER3 = SiMe3 (3), GeMe3 (4), SnBu3n (5)] and Cp*Ru(PPh3)(2)C=CPR2 [PR2 = PPh2 (6), PBu2t (7)] respectively. Quaternization of 6 and 7 by alkyl iodides in toluene smoothly produced phosphonioethynyl complexes, [Cp*Ru(PPh3)(2)C=CPR2R']I [PR2R' = PPh2Me (8), (PBu2Me)-Me-t (9), PPh2Prn (10), (PBu2Prn)-Pr-t(11)], the cations of which may be regarded as donor/acceptor-stabilized derivatives of dicarbon, C-2.

  DOI：

  10.1016/s0022-328x(97)00005-3
• 作为产物：
  描述：

  [(C5Me5)Ru(triphenylphosphine)2(vinylidene)][PF6] 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以77%的产率得到[Ru(η5-C5Me5)(PPh3)2(-C≡CH)]
  参考文献：
  名称：

  Ethinylkomplexe des Rutheniums mit terminalen Hauptgruppenelement-Substituenten: Systematischer Aufbau metallgebundener Phosphoniumacetylid-Liganden R′R2P(+)-C≡C|(−)

  摘要：

  Treatment of Cp* RuL2Cl (Cp* = C5Me5; L = PPh3, PMe3) with Me3SiC=C:H in the presence of NH4[PF6] in CH2Cl2 yielded the expected vinylidene compounds [Cp *RuL2=C=CH2][PF6] with L = PPh3 (1) and PMe3 (1a), which were deprotonated by KOBut in THF to give the corresponding ethynyl complexes Cp*Ru(PPh3)(2)C=CH (2) and Cp*Ru(PMe3)(2)C=CH (2a). Metalation of 2 using n-BuLi or t-BuLi in THF-hexane, followed by reaction of the lithio intermediate Cp*Ru(PPh3)(2)C=CLi with CIER3 (E = Si, Ge, Sn) or ClPR2, resulted in the formation of substituted derivatives, Cp*Ru(PPh3)(2)C=CER3 [ER3 = SiMe3 (3), GeMe3 (4), SnBu3n (5)] and Cp*Ru(PPh3)(2)C=CPR2 [PR2 = PPh2 (6), PBu2t (7)] respectively. Quaternization of 6 and 7 by alkyl iodides in toluene smoothly produced phosphonioethynyl complexes, [Cp*Ru(PPh3)(2)C=CPR2R']I [PR2R' = PPh2Me (8), (PBu2Me)-Me-t (9), PPh2Prn (10), (PBu2Prn)-Pr-t(11)], the cations of which may be regarded as donor/acceptor-stabilized derivatives of dicarbon, C-2.

  DOI：

  10.1016/s0022-328x(97)00005-3

文献信息

• [EN] FORMATION OF BONDS BY OUTER-SPHERE OXIDATIVE ELECTROPHILIC FLUORINATION<br/>[FR] FORMATION DE LIAISONS PAR FLUORATION ÉLECTROPHILE OXYDATIVE DE SPHÈRE EXTERNE
  申请人：UNIV YORK

  公开号：WO2016087879A1

  公开（公告）日：2016-06-09

  There is described a method of fluorination of an alkenyl, alkynyl, aryl or isonitrile compound which comprises reacting an alkenyl, alkynyl, aryl or isonitrile compound with a metal-mediated outer-sphere electrophilic fluorinating (OSEF) agent.

  描述了一种氟化烯丙基、炔丙基、芳基或异氰基化合物的方法，包括将烯丙基、炔丙基、芳基或异氰基化合物与金属介导的外层球电亲核氟化（OSEF）试剂反应。
• Some reactions of azides with diynyl-bis(phosphine)ruthenium-cyclopentadienyl complexes
  作者：Michael I. Bruce、Alexandre Burgun、Jonathan George、Brian K. Nicholson、Christian R. Parker、Brian W. Skelton、Nancy Scoleri、Christopher J. Sumby、Natasha N. Zaitseva

  DOI：10.1016/j.jorganchem.2015.08.019

  日期：2015.11

  Reactions of SiMe3(N3) with Ru(CCH)(PP)Cp’ [PP = (PPh3)2, Cp′ = Cp; PP = dppe, Cp′ = Cp*] afford Ru(N3)(PP)Cp′. Reactions of Ru(CCCCR)(dppe)Cp* with SiMe3(N3) give RuN3C(CN)CH2R}(dppe)Cp* (R = H 2, Ph 3). With RuCl(dppe)Cp* in the presence of [NH4]PF6, 2 gives binuclear [Cp*(dppe)RuN3C[(CN)Ru(dppe)Cp*]CMe}]PF6 4. The reaction between TsN3 and Ru(CCCCH)(dppe)Cp* gives Ru(NC)CNNTsCHC(NTs)}(dppe)Cp*

  SiMe 3（N 3）与Ru（C CH）（PP）Cp'[PP =（PPh 3）2，Cp'= Cp; PP ＝ DPPE，Cp′＝ Cp *]得到Ru（N 3）（PP）Cp′。Ru（C CC CR）（DPPE）Cp *与SiMe 3（N 3）的反应得到Ru N 3 C（CN）CH 2 R}（DPPE）Cp *（R = H 2，Ph 3）。在[NH 4 ] PF 6存在下，用RuCl（DPPE）Cp * ，2得到双核[Cp *（DPPE）Ru N 3 C [（CN）Ru（DPPE）Cp *] CMe}] PF 6 4。TsN 3与Ru（C.CC CH）（DPPE）Cp *给出Ru （NC）C NNTs CHC（NTs）}（DPPE）Cp * 5，并从一些反应中获得少量的TsN PPh 2 CH 2 CH 2 PPh 2 NTs 6。透视确定钌的结构（N 3）（DPPE）的Cp *和2 -