3,3-diphenyl-2,3-dihydro-benzo[d]isothiazole 1,1-dioxide | 53983-81-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 3,3-diphenyl-2,3-dihydro-benzo[d]isothiazole 1,1-dioxide
• 英文别名: 3,3-Diphenyl-2,3-dihydro-1,2-benzisothiazole 1,1-dioxide；3,3-diphenyl-2H-1,2-benzothiazole 1,1-dioxide
• CAS: 53983-81-6
• 化学式: C₁₉H₁₅NO₂S
• 分子量: 321.4
• InChiKey: VAJAMNXSLLWPSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  54.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,3-diphenyl-2,3-dihydro-benzo[d]isothiazole 1,1-dioxide 在 对甲苯磺酸 、 sodium nitrite 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 生成 2-Nitroso-3,3-diphenyl-1,2-benzothiazole 1,1-dioxide
  参考文献：
  名称：

  [EN] NITROSATION REAGENTS AND METHODS
  [FR] RÉACTIFS ET PROCÉDÉS DE NITROSATION

  摘要：

  提供了可用作亚硝化试剂的化合物。提供了包括将底物与提供的亚硝化试剂之一反应，从而生成亚硝化产物的亚硝化方法。提供了包含亚硝化试剂的试剂盒。提供了其中亚硝化试剂富集在15N同位素的组合物。

  公开号：

  WO2021257849A1
• 作为产物：
  描述：

  2-苯基-2-丙醇 在 Lindlar's catalyst sodium azide 、 四甲基乙二胺 、 氢气 、 仲丁基锂 、 三乙胺 、 三氟乙酸 作用下， 以 四氢呋喃 、 乙醇 、 二氯甲烷 、 氯仿 、 环己烷 为溶剂， 反应 26.17h， 生成 3,3-diphenyl-2,3-dihydro-benzo[d]isothiazole 1,1-dioxide
  参考文献：
  名称：

  Directed Ortho Metalation−Cross Coupling Strategies. N-Cumyl Arylsulfonamides. Facile Deprotection and Expedient Route to 7- and 4,7-Substituted Saccharins

  摘要：

  By using the powerful N-cumylsulfonamide directed metalation group (DMG), a series of 2-substituted derivatives were prepared according to the directed ortho metalation (DoM) tactic (Table 1). Mild conditions for N-decumylation and other simple transformations of the products have been achieved (Scheme 2). The 3-silyloxy sultam 12 undergoes further DoM to give formyl, thiomethyl, iodo, and amide derivatives 13a-g of potential value for saccharin synthesis (Table 2). An effective route to target 7-aryl saccharins via Suzuki cross coupling (Table 3) followed by further metalation-carbamoylation and cyclization (Table 5) is described. 4,7-Disubstituted saccharins have been obtained by similar sequences (Scheme 3). Mild TFA-mediated N-decumylation furnishes substituted primary arylsulfonamides (Table 4).

  DOI：

  10.1021/jo062385v

文献信息

• AROMATIC SULFONIC ACID DERIVATIVE, SULFONIC ACID GROUP-CONTAINING POLYMER, BLOCK CO-POLYMER, POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MOLDED BODY, AND SOLID POLYMER FUEL CELL
  申请人：Izuhara Daisuke

  公开号：US20140213671A1

  公开（公告）日：2014-07-31

  Provided are an aromatic sulfonic acid derivative and a sulfonic acid group-containing polymer, each of which has excellent proton conductivity even under low humidification conditions, while having excellent mechanical strength and chemical stability, and enables a solid polymer fuel cell to achieve high output and excellent physical durability when used therein. This aromatic sulfonic acid derivative has a specific structure and is characterized in that a sulfonic acid group is introduced into more than 50% of all the phenyl groups. This sulfonic acid group-containing polymer is characterized by being obtained by polymerization using the aromatic sulfonic acid derivative, and is also characterized by having a specific structure.

  提供了一种芳香磺酸衍生物和含有磺酸基团的聚合物，它们在低湿化条件下具有优异的质子导电性，同时具有优异的机械强度和化学稳定性，可使固体聚合物燃料电池在其中使用时实现高输出和优异的物理耐久性。这种芳香磺酸衍生物具有特定结构，其特点是将磺酸基团引入到超过50%的苯基中。这种含有磺酸基团的聚合物的特点是通过使用芳香磺酸衍生物进行聚合得到，并且具有特定的结构。
• Penultimate group effects in free radical telomerizations of acrylamides
  作者：Ned A. Porter、Randall L. Carter、Christopher L. Mero、Michael G. Roepel、Dennis P. Curran

  DOI：10.1016/0040-4020(96)00077-4

  日期：1996.3

  The telomerizaton of several acrylamides, most containing chiral auxiliary groups, was investigated. The first-formed stereogenic center in the n=2 telomer (the penultimate center) has a significant effect on the configuration of the second (ultimate) center in the product. The penultimate chiral center of oxazolidine-derived acrylamides directs the configuration of the ultimate center such that the

  研究了几种丙烯酰胺的端粒，大多数含有手性辅助基团。n = 2端粒中的第一个形成的立体异构中心（倒数第二个中心）对产品中第二个（最终的）中心的构型有重大影响。恶唑烷衍生的丙烯酰胺的倒数第二个手性中心指导最终中心的构型，使得优选赤型n＝ 2的产物。另一方面，用Sultam取代的丙烯酰胺优先导致苏式产物或产生立体选择性低的产物。
• A new photochemical ring expansion of 1,2-benzisothiazole 1,1-dioxides
  作者：Ibrahim Elghamry、Dietrich Döpp

  DOI：10.1016/s0040-4039(01)00992-3

  日期：2001.8

  A new facile photoconversion of 1,2-benzisothiazole 1,1-dioxides into 1,3-2H-benzothiazine 1,1-dioxides upon 254 nm irradiation in methanol or acetonitrile is reported.

  据报道，在甲醇或乙腈中经254 nm照射后，1,2-苯并噻唑1,1-二氧化物可以轻松地光转换为1,3-2 H-苯并噻嗪1,1-二氧化物。
• POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MOLDED PRODUCT USING THE POLYMER ELECTROLYTE MATERIAL, AND METHOD FOR MANUFACTURING THE POLYMER ELECTROLYE MOLDED PRODUCT, MEMBRANE ELECTRODE COMPOSITE, AND SOLID POLYMER FUEL CELL
  申请人：Izuhara Daisuke

  公开号：US20100196782A1

  公开（公告）日：2010-08-05

  It is an object of the present invention to provide a polymer electrolyte material which has excellent proton conductivity even under the conditions of a low humidity or a low temperature and is excellent in mechanical strength and fuel barrier properties, and which moreover can achieve high output, high energy density and long-term durability in forming a polymer electrolyte fuel cell therefrom, and a polymer electrolyte form article using the same and a method for producing the same, a membrane electrode assembly and a polymer electrolyte fuel cell, each using the same. The present invention employs the following means. Namely, the polymer electrolyte material of the present invention is a polymer electrolyte material including a constituent unit (A1) containing an ionic group and a constituent unit (A2) substantially not containing an ionic group, wherein a phase separation structure is observed by a transmission electron microscope and a crystallization heat measured by differential scanning calorimetry is 0.1 J/g or more, or a phase separation structure is observed by a transmission electron microscope and the degree of crystallinity measured by wide angle X-ray diffraction is 0.5% or more. Also, the polymer electrolyte form article, the membrane electrode assembly and the polymer electrolyte fuel cell of the present invention are characterized by being composed of such polymer electrolyte materials.

  本发明的目的是提供一种聚合物电解质材料，即使在低湿度或低温条件下也具有优异的质子导电性，并且具有出色的机械强度和燃料屏障性能，而且可以在形成聚合物电解质燃料电池时实现高输出、高能量密度和长期耐久性，以及使用该材料的聚合物电解质形态物品和制备该物品的方法、膜电极组件和聚合物电解质燃料电池。本发明采用以下手段。即，本发明的聚合物电解质材料是一种聚合物电解质材料，包括含有离子基团的组分单元（A1）和基本不含离子基团的组分单元（A2），其中透射电子显微镜观察到相分离结构，差示扫描量热法测量的结晶热为0.1 J/g或更高，或透射电子显微镜观察到相分离结构，宽角X射线衍射测量的结晶度为0.5％或更高。此外，本发明的聚合物电解质形态物品、膜电极组件和聚合物电解质燃料电池的特点是由这种聚合物电解质材料组成。
• POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MOLDED PRODUCT USING THE POLYMER ELECTROLYTE MATERIAL AND METHOD FOR MANUFACTURING THE POLYMER ELECTROLYTE MOLDED PRODUCT, MEMBRANE ELECTRODE COMPOSITE, AND SOLID POLYMER FUEL CELL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150155582A1

  公开（公告）日：2015-06-04

  It is an object of the present invention to provide a polymer electrolyte material which has excellent proton conductivity even under the conditions of a low humidity or a low temperature and is excellent in mechanical strength and fuel barrier properties, and which moreover can achieve high output, high energy density and long-term durability in forming a polymer electrolyte fuel cell therefrom, and a polymer electrolyte form article using the same and a method for producing the same, a membrane electrode assembly and a polymer electrolyte fuel cell, each using the same. The present invention employs the following means. Namely, the polymer electrolyte material of the present invention is a polymer electrolyte material including a constituent unit (A1) containing an ionic group and a constituent unit (A2) substantially not containing an ionic group, wherein a phase separation structure is observed by a transmission electron microscope and a crystallization heat measured by differential scanning calorimetry is 0.1 J/g or more, or a phase separation structure is observed by a transmission electron microscope and the degree of crystallinity measured by wide angle X-ray diffraction is 0.5% or more. Also, the polymer electrolyte form article, the membrane electrode assembly and the polymer electrolyte fuel cell of the present invention are characterized by being composed of such polymer electrolyte materials.

  本发明的目的是提供一种聚合物电解质材料，即使在低湿度或低温条件下也具有优异的质子导电性能，且具有优异的机械强度和阻挡燃料的性能，而且可以实现高输出、高能量密度和长期耐久性，形成聚合物电解质燃料电池，以及使用相同的聚合物电解质形式的文章和生产方法，以及膜电极组件和聚合物电解质燃料电池。本发明采用以下手段。即，本发明的聚合物电解质材料是一种聚合物电解质材料，包括含有离子基团的构成单元（A1）和基本不含离子基团的构成单元（A2），其中透射电子显微镜观察到相分离结构，差示扫描量热法测量的结晶热为0.1 J/g或更高，或透射电子显微镜观察到相分离结构，广角X射线衍射测量的结晶度为0.5％或更高。此外，本发明的聚合物电解质形式的文章、膜电极组件和聚合物电解质燃料电池的特点是由这种聚合物电解质材料组成。