silver cyclohexanecarboxylate | 13126-82-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: silver cyclohexanecarboxylate
• 英文别名: silver(I) cyclohexanoate；silver cyclohexanoate；cyclohexanecarboxylic acid ; silver (I)-compound；Cyclohexancarbonsaeure; Silber(I)-Verbindung；Silver;cyclohexanecarboxylate
• CAS: 13126-82-4
• 化学式: Ag*C₇H₁₁O₂
• 分子量: 235.031
• InChiKey: MQHGEVXQSFWXCE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.31
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916209090

反应信息

• 作为反应物：
  描述：

  silver cyclohexanecarboxylate 在 亚硝酰氯 作用下， 反应 2.0h， 以83%的产率得到nitrosyl cyclohexanecarboxylate
  参考文献：
  名称：

  苯甲酸亚硝基酯和对苯二甲酸二亚硝基酯与四取代烯烃反应合成亚硝基和二亚硝基化合物

  摘要：

  苯甲酸亚硝基酯与四取代烯烃在 0 °C 下反应以高产率生成单体 C-亚硝基化合物。类似地，对苯二甲酸二亚硝基酯与 2,3-二甲基丁-2-烯反应得到单体二亚硝基化合物。扩展到其他亚硝基酯可得到类似的高产率。

  DOI：

  10.1055/s-2006-942392
• 作为试剂：
  描述：

  1-甲基吲哚 、 碘苯 在 水 、 palladium diacetate 、 silver cyclohexanecarboxylate 作用下， 反应 16.0h， 以93%的产率得到1-甲基-2-苯基吲哚
  参考文献：
  名称：

  “在水上”，无磷的钯催化的室温C ？吲哚的H化

  摘要：

  掌握化学反应！一个“水”，钯-催化的，游离的膦直接Ç  ħ吲哚的在25-30℃的芳基化，与iodoarenes，公开了（参见方案; TBDMS = ñ -叔丁基二甲基醚; SEM = Ñ -2 -（三甲基甲硅烷基）乙氧基甲基; Bn =苄基，Piv =吡巴贝基）。反应条件温和性使得各种N1的宽容-保护的吲哚类化合物。

  DOI：

  10.1002/chem.201302838

文献信息

• Reactivity of polynuclear palladium carboxylate complexes towards acetonitrile: synthesis and X-ray study of Pd2(C6H4-o-C(NH)CH3)2(CH3CO2)2 and Pd5(CH3C(N)OC(N)CH3)(NO)(NO2)x(RCO2)7−x
  作者：Oleg N. Shishilov、Nailya S. Akhmadullina、Yaroslavna N. Rezinkova、Roman E. Podobedov、Andrei V. Churakov、Inessa A. Efimenko

  DOI：10.1039/c2dt32407e

  日期：——

  Reactions of the polynuclear palladium carboxylate complexes (binary palladium carboxylates and palladium nitrosyl carboxylates) with acetonitrile in some common organic solvents are described. It was found that reaction of palladium acetate Pd3(μ-CH3CO2)6 with acetonitrile and benzene leads to the formation of a binuclear complex Pd2(C6H4-o-C(NH)CH3)2(CH3CO2)2 containing molecules of orthometallated 1-phenylethanimine formed as a result of C–C-coupling of acetonitrile and benzene. Nitrosyl carboxylate complexes Pd4(NO)2(RCO2)6 promote more complicated transformations of acetonitrile that leads to the formation of coordinated acetimidic anhydride, which was found in Pd5(CH3C(N)OC(N)CH3)(NO)(NO2)x(RCO2)7−x clusters. Structures of all the complexes contained products of acetonitrile transformations and a new palladium nitrosyl carboxylate Pd4(NO)2(cyclo-C6H11CO2)6 was studied with XRD. Analysis of the structures allowed finding a “building block” of palladium nitrosyl carboxylate clusters, that is a 4-nuclear metal chain –Pd(μ-RCO2)2Pd(μ-NO)(μ-RCO2)Pd(μ-RCO2)2Pd–.

  本文描述了多核钯羧酸盐复合物（二元钯羧酸盐和钯亚硝基羧酸盐）在某些常见有机溶剂中与乙腈的反应。研究发现，钯乙酸盐Pd3(μ-CH3CO2)6与乙腈和苯反应生成双核复合物Pd2(C6H4-o-C(NH)CH3)2(CH3CO2)2，该复合物含有通过乙腈和苯的C-C偶联形成的手性联二亚乙基酰胺分子。亚硝基羧酸盐复合物Pd4(NO)2(RCO2)6促进更复杂的乙腈转化，生成配位的乙酰亚胺酸酐，这一发现存在于Pd5(CH3C(N)OC(N)CH3)(NO)(NO2)x(RCO2)7−x簇中。所有复合物的结构都包含了乙腈转化的产物，一种新的钯亚硝基羧酸盐Pd4(NO)2(cyclo-C6H11CO2)6通过XRD进行了研究。通过对结构的分析，发现了一个钯亚硝基羧酸盐簇的“构建模块”，即一个4核金属链 −Pd(μ-RCO2)2Pd(μ-NO)(μ-RCO2)Pd(μ-RCO2)2Pd−。
• COMPOUND HAVING TAFIA INHIBITORY ACTIVITY
  申请人：Amada Hideaki

  公开号：US20110213143A1

  公开（公告）日：2011-09-01

  Provided are compounds having superior TAFIa inhibitory activity. Specifically, there are provided compounds represented by the following formula (I) or pharmaceutically acceptable salts thereof: wherein A is a benzene ring or a pyridine ring; X is the formula —(CH 2 )—, the formula —(CH 2 ) 2 —, an oxygen atom, a nitrogen atom or a single bond; Y is the formula —(CH 2 ) 3 —NH—R 3 , the formula —(CH 2 ) 4 —NH—R 3 or a 2-aminopyridyl group; R 3 is a hydrogen atom, a C 1-6 alkyl group, or the formula —CO 2 R 4 ; R 4 is a C 1-6 alkyl group, the formula —CHR 5 OC(O)R 6 , or a substituent having the structure represented by the following formula Ia; R 5 is a C 1-6 alkyl group; R 6 is a C 1-6 alkyl group, a C 3-8 cycloalkyl group, or a phenyl group; R 7 is a C 1-6 alkyl group or a phenyl group; R 1 is a hydrogen atom, a halogen atom, a C 1-4 alkyl group substituted by 1-3 halogen atoms, a C 1-10 alkyl group, a C 1-8 alkoxy group, a C 3-8 cycloalkyl group, a C 3-8 cycloalkoxy group, a C 4-14 cycloalkylalkyl group, or a phenyl group; R 2 is CO 2 R 8 , or a tetrazolyl group; R 8 is a hydrogen atom, a C 1-10 alkyl group, or a substituent having the structure represented by the following formula Ib or Ic; m and n are each an integer of zero or one.

  提供了具有优异的TAFIa抑制活性的化合物。具体而言，提供了以下公式（I）或其药学上可接受的盐所代表的化合物：其中A是苯环或吡啶环；X是公式—（CH2）—，公式—（CH2）2—，氧原子，氮原子或单键；Y是公式—（CH2）3—NH—R3，公式—（CH2）4—NH—R3或2-氨基吡啶基；R3是氢原子，C1-6烷基或公式—CO2R4；R4是C1-6烷基，公式—CHR5OC（O）R6或具有以下公式Ia所代表的结构的取代基；R5是C1-6烷基；R6是C1-6烷基，C3-8环烷基或苯基；R7是C1-6烷基或苯基；R1是氢原子，卤素原子，被1-3个卤素原子取代的C1-4烷基，C1-10烷基，C1-8烷氧基，C3-8环烷基，C3-8环烷氧基，C4-14环烷基烷基或苯基；R2是CO2R8或四唑基；R8是氢原子，C1-10烷基或具有以下公式Ib或Ic所代表的结构的取代基；m和n各自为零或一的整数。
• CONDUCTIVE INK
  申请人：MITSUI MINING & SMELTING CO., LTD.

  公开号：EP1847575A1

  公开（公告）日：2007-10-24

  It is an object of the present invention to provide a conductive ink which enables to form a circuit or the like having excellent adhesion to a substrate and to forma conductor having high film density and low electric resistance. Inorder to attain the obj ect, a conductive ink comprising metal powder or metal oxide powder dispersed in a dispersion medium, which is characterized in that the dispersion medium contains a metal salt or a metal oxide as a film density improver for increasing film density of a conductor formed by using the conductive ink is adopted. A main solvent constituting the dispersion medium is selected from one or a combination of two or more selected from the group consisting of water, alcohols, glycols and saturated hydrocarbons having a boiling point of 300 deg. C or less at normal pressure.

  本发明的目的是提供一种导电油墨，它能形成电路或类似电路，与基材有极好的附着力，并能形成具有高膜密度和低电阻的导体。为了实现上述目标，本发明采用了一种由分散在分散介质中的金属粉末或金属氧化物粉末组成的导电油墨，其特征在于分散介质中含有金属盐或金属氧化物作为膜密度改进剂，用于提高使用该导电油墨形成的导体的膜密度。构成分散介质的主溶剂选自水、醇、乙二醇和饱和碳氢化合物中的一种或两种以上的组合。在常压下沸点为 300 摄氏度或更低。
• CONDUCTIVE POLYMER SOLUTION, CONDUCTIVE COATING FILM, AND INPUT DEVICE
  申请人：Shin-Etsu Polymer Co. Ltd.

  公开号：EP2202754A1

  公开（公告）日：2010-06-30

  The conductive polymer solution of the present invention contains a π-conjugated conductive polymer, polyanions and a solvent, at least one of specific metal ions, silver halide, conductive carbon black and conductive metal oxide particles, and a reducing agent and/or neutralizing agent as necessary. The conductive polymer solution of the present invention can be used a conductive coating film having both superior transparency and being suitable for use a transparent electrode of a touch panel electrode sheet. In addition, the conductive coating film of the present invention has superior transparency that enables it to be used as a transparent electrode of a touch panel electrode sheet.

  本发明的导电聚合物溶液含有π-共轭导电聚合物、聚阴离子和溶剂、特定金属离子、卤化银、导电碳黑和导电金属氧化物颗粒中的至少一种，以及必要的还原剂和/或中和剂。本发明的导电聚合物溶液可用于导电涂膜，该涂膜具有极佳的透明度，适合用作触控板电极片的透明电极。此外，本发明的导电涂膜具有优异的透明度，可用作触控板电极片的透明电极。
• conductive polymer solution, conductive coating film and input device
  申请人：Shin-Etsu Polymer Co. Ltd.

  公开号：EP2400508A1

  公开（公告）日：2011-12-28

  The conductive polymer solution of the present invention contains a π-conjugated conductive polymer, polyanions, a solvent, and 0,01-10% wt. based on a value of 100% for the total amount of the π-conjugated conductive polymer and the polyanion of a conductive carbon black. The conductive polymer solution of the present invention can be used a conductive coating film having both superior transparency and being suitable for use a transparent electrode of a touch panel electrode sheet. In addition, the conductive coating film of the present invention has superior transparency that enables it to be used as a transparent electrode of a touch panel electrode sheet.

  本发明的导电聚合物溶液含有π-共轭导电聚合物、聚阴离子、溶剂和 0.01-10%重量比（以π-共轭导电聚合物和导电炭黑的聚阴离子的总量的 100%值为基准）的导电炭黑。本发明的导电聚合物溶液可用于导电涂膜，该涂膜具有极佳的透明度，适合用作触控板电极片的透明电极。此外，本发明的导电涂膜具有优异的透明度，可用作触控板电极片的透明电极。