6-(9'-O-7β-glucopyranosyl-non-7'-(E)-ene-3',5'-diynyl)-pyran-2-one-3,5-diene | 1227632-76-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 6-(9'-O-7β-glucopyranosyl-non-7'-(E)-ene-3',5'-diynyl)-pyran-2-one-3,5-diene
• 英文别名: 6-[(E)-9-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxynon-7-en-3,5-diynyl]pyran-2-one
• CAS: 1227632-76-9
• 化学式: C₂₀H₂₂O₈
• 分子量: 390.39
• InChiKey: PJJLHWAFPLDXCO-KIJCZZANSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  126
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  6-(9'-O-7β-glucopyranosyl-non-7'-(E)-ene-3',5'-diynyl)-pyran-2-one-3,5-diene 在 盐酸 、 水 作用下， 反应 8.0h， 生成 可得然胶
  参考文献：
  名称：

  A C14-polyacetylenic glucoside with an α-pyrone moiety and four C10-polyacetylenic glucosides from Mediasia macrophylla

  摘要：

  Polyacetylenic glucosides (1-5) were isolated from the MeOH extract of Mediasia macrophylla, and their structures were established by spectroscopic analyses. Compounds 2-4 were the first examples of C-10-polyacetylenic glucosides found in the family Umbelliferae, while compound 1 was a unique polyacetylenic glucoside possessing an alpha-pyrone moiety. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.phytochem.2009.12.007

文献信息

• A C14-polyacetylenic glucoside with an α-pyrone moiety and four C10-polyacetylenic glucosides from Mediasia macrophylla
  作者：Shin-ichiro Kurimoto、Mamoru Okasaka、Yoshiki Kashiwada、Olimjon K. Kodzhimatov、Yoshihisa Takaishi

  DOI：10.1016/j.phytochem.2009.12.007

  日期：2010.4

  Polyacetylenic glucosides (1-5) were isolated from the MeOH extract of Mediasia macrophylla, and their structures were established by spectroscopic analyses. Compounds 2-4 were the first examples of C-10-polyacetylenic glucosides found in the family Umbelliferae, while compound 1 was a unique polyacetylenic glucoside possessing an alpha-pyrone moiety. (C) 2009 Elsevier Ltd. All rights reserved.