3,4-di(octyloxy)aniline | 4956-88-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,4-di(octyloxy)aniline
• 英文别名: 3,4-Dioctyloxy-anilin；3,4-Dioctyloxyaniline；3,4-dioctoxyaniline
• CAS: 4956-88-1
• 化学式: C₂₂H₃₉NO₂
• 分子量: 349.557
• InChiKey: QDYHDJSIBRPACG-UHFFFAOYSA-N

物化性质

• 沸点：
  465.7±25.0 °C(Predicted)
• 密度：
  0.942±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  25
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  44.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,4-di(octyloxy)aniline 在 tetraphosphorus decasulfide 作用下， 生成 N,N'-bis(3,4-dioctoxyphenyl)ethanedithioamide
  参考文献：
  名称：

  Mesomorphic Dithiooxamide Complexes of Platinum(II)

  摘要：

  Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)(2)]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12-16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies.

  DOI：

  10.1080/10587250008024795
• 作为产物：
  描述：

  4-硝基儿茶酚 在 tin(ll) chloride 作用下， 生成 3,4-di(octyloxy)aniline
  参考文献：
  名称：

  Mesomorphic Dithiooxamide Complexes of Platinum(II)

  摘要：

  Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)(2)]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12-16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies.

  DOI：

  10.1080/10587250008024795

文献信息

• Liquid crystalline properties of bis(salicylaldiminato)copper(II) complexes: the first columnar discotics derived from salicylaldimine Schiff bases
  作者：Chung K. Lai、Chung-hsiung Chang、Chun-hsien Tsai

  DOI：10.1039/a707091h

  日期：——

  The synthesis and mesomorphic properties of a homologous series ofN-(2-hydroxy-4-n-alkoxybenzylidene)-3′,4′-di-n-alkoxylanilines and their copper(ii) complexes bis[(N-3′,4′-dialkoxyphenyl)-4-n-alkoxylsalicylaldiminato]copper(ii) are reported. The disc-like copper complexes exhibited columnar hexagonal disordered mesophases, which were characterized by DSC analysis and optical polarized microscopy. The structure of the mesophases was confirmed by X-ray powder diffraction (XRD). The mesomorphic properties for these copper complexes were compared with other similar metallomesogenic bis(salicylaldiminato)copper(ii) complexes in terms of molecular structural differences.

  报道了一组N-(2-羟基-4-正烷氧基苯亚甲基)-3′,4′-二-正烷氧基苯胺及其铜(II)配合物双[(N-3′,4′-二烷氧基苯基)-4-正烷氧基水杨醛亚胺]铜(II)的合成与液晶性质。盘状铜配合物表现出无序的柱状六方相，通过差示扫描量热分析和偏光显微镜进行了表征。通过X射线粉末衍射(XRD)确定了其相结构。与其他类似的金属配位液晶双(水杨醛亚胺)铜(II)配合物相比，这些铜配合物的液晶性质与其分子结构差异有关。
• Novel dyes and use thereof in imaging members and methods
  申请人：——

  公开号：US20040191668A1

  公开（公告）日：2004-09-30

  There are described novel rhodamine dye compounds and imaging members and imaging methods, including thermal imaging members and imaging methods, utilizing the compounds. The dye compounds exhibit a first color when in the crystalline form and a second color, different from the first color, when in the liquid, amorphous form.

  本文描述了新型罗丹明染料化合物、成像材料和成像方法，包括利用这些化合物的热成像材料和成像方法。这些染料化合物在晶体形态下呈现第一种颜色，在液态非晶形态下呈现第二种颜色，与第一种颜色不同。
• Process for the preparation of novel dyes for use in imaging members
  申请人：Cheon Kap-Soo

  公开号：US20060234143A1

  公开（公告）日：2006-10-19

  There are described novel rhodamine dye compounds and imaging members and imaging methods, including thermal imaging members and imaging methods, utilizing the compounds. The dye compounds exhibit a first color when in the crystalline form and a second color, different from the first color, when in the liquid, amorphous form.

  这是一种新型罗丹明染料化合物，以及利用该化合物的成像成员和成像方法，包括利用该化合物的热成像成员和成像方法。该染料化合物在晶体形态下呈现第一种颜色，在液态非晶态下呈现不同于第一种颜色的第二种颜色。
• NOVEL DYES AND USE THEREOF IN IMAGING MEMBERS AND METHODS
  申请人：Cheon Kap-Soo

  公开号：US20080187866A1

  公开（公告）日：2008-08-07

  There are described novel rhodamine dye compounds and imaging members and imaging methods, including thermal imaging members and imaging methods, utilizing the compounds. The dye compounds exhibit a first color when in the crystalline form and a second color, different from the first color, when in the liquid, amorphous form.

  本文描述了一种新型的罗丹明染料化合物和成像元件以及成像方法，包括利用该化合物的热成像元件和成像方法。这些染料化合物在晶体形态下表现出第一种颜色，在液态非晶态下表现出第二种颜色，与第一种颜色不同。
• PROCESS FOR THE PREPARATION OF NOVEL DYES FOR USE IN IMAGING MEMBERS
  申请人：Cheon Kap-Soo

  公开号：US20070224552A1

  公开（公告）日：2007-09-27

  There are described novel rhodamine dye compounds and imaging members and imaging methods, including thermal imaging members and imaging methods, utilizing the compounds. The dye compounds exhibit a first color when in the crystalline form and a second color, different from the first color, when in the liquid, amorphous form.

  描述了一种新型罗丹明染料化合物、成像材料和成像方法，包括利用这些化合物的热成像材料和成像方法。这些染料化合物在晶体形态下呈现第一种颜色，在液态非晶态下呈现与第一种颜色不同的第二种颜色。