4-(di(4-methoxyphenyl)amine)benzaldehyde-N-(2-ethylhexyl)-1,8-naphthalimide hydrazone | 1301254-53-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(di(4-methoxyphenyl)amine)benzaldehyde-N-(2-ethylhexyl)-1,8-naphthalimide hydrazone
• CAS: 1301254-53-4
• 化学式: C₄₁H₄₂N₄O₄
• 分子量: 654.809
• InChiKey: YAURDGMCKXJRSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.59
• 重原子数：
  49.0
• 可旋转键数：
  14.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  83.47
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  4-(di(4-methoxyphenyl)amine)benzaldehyde-N-(2-ethylhexyl)-1,8-naphthalimide hydrazone 、 碘乙烷 在 四丁基溴化铵 、 potassium hydroxide 作用下， 以 丙酮 为溶剂， 反应 0.67h， 以80%的产率得到4-(di(4-methoxyphenyl)amine)benzaldehyde-N-ethyl-N-(2-ethylhexyl)-1,8-naphthalimide hydrazone
  参考文献：
  名称：

  Hydrazones containing electron-accepting and electron-donating moieties

  摘要：

  Hydrazones containing electron-accepting 1,8-naphthalimide species and electron-donating triphenylamino moieties were synthesized and characterized by nuclear magnetic resonance, infrared spectroscopy, and mass spectrometry. Thermal, optical, electrochemical and photophysical properties of the synthesized derivatives were investigated, their, optical and electrochemical band-gap energies and ionization potentials were established. The hydrazones exhibit initial mass loss temperatures in the range of 268-348 degrees C and can form glasses with glass transition temperatures in the range of 46-142 degrees C as established by differential scanning calorimetry. Room temperature time-of-flight hole mobilities in the solid solutions of the derivatives in the polymeric host bisphenol-Z polycarbonate (50%) exceeded 10(-5) cm(2)/V s at high applied electric Fields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.02.002
• 作为产物：
  描述：

  2-乙基己胺 在 一水合肼 作用下， 以 甲醇 、 甲乙醚 、 N,N-二甲基甲酰胺 为溶剂， 反应 4.5h， 生成 4-(di(4-methoxyphenyl)amine)benzaldehyde-N-(2-ethylhexyl)-1,8-naphthalimide hydrazone
  参考文献：
  名称：

  Hydrazones containing electron-accepting and electron-donating moieties

  摘要：

  Hydrazones containing electron-accepting 1,8-naphthalimide species and electron-donating triphenylamino moieties were synthesized and characterized by nuclear magnetic resonance, infrared spectroscopy, and mass spectrometry. Thermal, optical, electrochemical and photophysical properties of the synthesized derivatives were investigated, their, optical and electrochemical band-gap energies and ionization potentials were established. The hydrazones exhibit initial mass loss temperatures in the range of 268-348 degrees C and can form glasses with glass transition temperatures in the range of 46-142 degrees C as established by differential scanning calorimetry. Room temperature time-of-flight hole mobilities in the solid solutions of the derivatives in the polymeric host bisphenol-Z polycarbonate (50%) exceeded 10(-5) cm(2)/V s at high applied electric Fields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.02.002