trimethylammonium perchlorate | 15576-35-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: trimethylammonium perchlorate
• 英文别名: trimethyl-amine; perchlorate；Trimethyl-amin; Perchlorat；Trimethyl ammonium perchlorate；trimethylazanium;perchlorate
• CAS: 15576-35-9
• 化学式: C₃H₁₀N*ClO₄
• 分子量: 159.57
• InChiKey: PNLVIPVKIAPZTP-UHFFFAOYSA-N

物化性质

• 沸点：
  146.4°C (estimate)
• 密度：
  1.4351 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  -3.95
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  74.7
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  Au(acetylacetonato)(P(C6H5)3) 、 trimethylammonium perchlorate 以 丙酮 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  Synthesis of complexes [Au(PPh₃)L]⁺(L = primary, secondary or tertiary amine). Crystal structure of [Au(PPh₃)(NMe₃)][ClO₄]·CH₂Cl₂

  摘要：

  The 1:1 reaction of [Au(acac)(PPh(3))] (Hacac = acetylacetone) with ammonium salts [HL]X (X = CF3SO3, L = 2-nitroaniline, 4-methoxyaniline. NHPh(2) or NHEt(2); X = ClO4, L = NMe(3)) in diethyl ether gave complexes [Au(PPh(3))L]X and acety]acetone. The crystal structure of [Au(PPh(3))(NMe(3))][ClO4] was determined; orthorhombic, space group P2(1)2(1)2(1), a = 9.498(2), b = 10.322(2) c = 26.154(4) Angstrom, wR(F-2) 0.091. The gold atom is linearly co-ordinated to both ligands [AU-P 2.231 (2). Au-N 2.108(7) Angstrom, P-Au-N 179.3(2)degrees] and no intermolecular Au..Au contacts exist.

  DOI：

  10.1039/dt9950001251
• 作为产物：
  描述：

  三甲胺盐酸盐 在 sodium perchlorate 作用下， 以 丙酮 为溶剂， 反应 0.5h， 以92%的产率得到trimethylammonium perchlorate
  参考文献：
  名称：

  Synthesis of complexes [Au(PPh₃)L]⁺(L = primary, secondary or tertiary amine). Crystal structure of [Au(PPh₃)(NMe₃)][ClO₄]·CH₂Cl₂

  摘要：

  The 1:1 reaction of [Au(acac)(PPh(3))] (Hacac = acetylacetone) with ammonium salts [HL]X (X = CF3SO3, L = 2-nitroaniline, 4-methoxyaniline. NHPh(2) or NHEt(2); X = ClO4, L = NMe(3)) in diethyl ether gave complexes [Au(PPh(3))L]X and acety]acetone. The crystal structure of [Au(PPh(3))(NMe(3))][ClO4] was determined; orthorhombic, space group P2(1)2(1)2(1), a = 9.498(2), b = 10.322(2) c = 26.154(4) Angstrom, wR(F-2) 0.091. The gold atom is linearly co-ordinated to both ligands [AU-P 2.231 (2). Au-N 2.108(7) Angstrom, P-Au-N 179.3(2)degrees] and no intermolecular Au..Au contacts exist.

  DOI：

  10.1039/dt9950001251

文献信息

• Fischer,G.W., Zeitschrift fur Chemie, 1968, vol. 8, p. 269 - 270
  作者：Fischer,G.W.

  DOI：——

  日期：——
• Fischer,G.W., Journal fur praktische Chemie (Leipzig 1954), 1977, vol. 319, p. 1042 - 1045
  作者：Fischer,G.W.

  DOI：——

  日期：——
• New Carbenegold(I) Complexes Synthesized by the “Acac Method”
  作者：José Vicente、María-Teresa Chicote、María Dolores Abrisqueta、Miguel M. Alvarez-Falcón、M. Carmen Ramírez de Arellano、Peter G. Jones

  DOI：10.1021/om030372r

  日期：2003.10.1

  The reaction of [AuClC(NEt2)(NHBu)-Bu-t}] with Tl(acac)] (1:1) gives [Au(C-acac)C(NEt2)-(NHBu)-Bu-t}] (1). Complex 1 reacts with 2-pyridinethiol (HSpy-2), C6H4(Cequivalent toCH)(2)-1,3 (2:1), [Ph3PCH2CO2Me]ClO4, [Me3S(O)]ClO4, or [Me3NH]ClO4 to give, respectively, [Au(Spy-2)-C(NEt2)(NHBu)-Bu-t}] (2), [AuC(NEt2)(NHBu)-Bu-t}(2)(mu-Cequivalent toCC(6)H(4)Cequivalent toC-3)] (3), [AuC(NEt2)(NHBu)-Bu-t}-CH(PPh3)CO2Me}]ClO4 (4), [AuC(NEt2)(NHBu)-Bu-t}CH2S(O)Me-2}]ClO4 (5), or [AuC(NEt2)(NHBu)-Bu-t}(NMe3)]ClO4 (6). The crystal structures of 1, 3, and 5 have been determined.
• Sato, Akane; Kobayashi, Hayao; Naito, Toshio, Inorganic Chemistry, 1997, vol. 36, # 23, p. 5262 - 5269
  作者：Sato, Akane、Kobayashi, Hayao、Naito, Toshio、Sakai, Fumiko、Kobayashi, Akiko

  DOI：——

  日期：——
• FISCHER G. W., J. PRAKT. CHEM. <JPCE-AO>, 1977, 319, NO 6, 1042-1045
  作者：FISCHER G. W.

  DOI：——

  日期：——