4,4,5,5,5-Pentafluoropentyl 4-(chloromethyl)benzoate | 1293408-08-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4,5,5,5-Pentafluoropentyl 4-(chloromethyl)benzoate
• 英文别名: 4,4,5,5,5-pentafluoropentyl 4-(chloromethyl)benzoate
• CAS: 1293408-08-8
• 化学式: C₁₃H₁₂ClF₅O₂
• 分子量: 330.682
• InChiKey: BIWNOZNZBOWLQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  甲基丙烯酸 、 4,4,5,5,5-Pentafluoropentyl 4-(chloromethyl)benzoate 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以97%的产率得到4,4,5,5,5-Pentafluoropentyl 4-(2-methylprop-2-enoyloxymethyl)benzoate
  参考文献：
  名称：

  Fluorinated compound, fluorinated polymer and fluorinated copolymer

  摘要：

  提供具有最多6个碳原子的RF基团的氟化合物，从而可以生产具有高耐久性的抗水/油性的氟化聚合物，并且环境负荷较小，通过聚合这种氟化合物可以获得具有高耐久性的抗水/油性和环境负荷较小的氟化聚合物和氟化共聚物。以下是用下式（I）表示的氟化合物及其聚合物：CH2═C(M)COO(CH2)nPhCOO(CH2)mCrF2r+1  (I)（在式（I）中，M是氢原子，甲基基团或卤素原子，n为0至2的整数，Ph为苯基团，m为1至4的整数，r为1至6的整数）。

  公开号：

  US08471056B2
• 作为产物：
  描述：

  4-氯甲基苯甲酰氯 、 4,4,5,5,5-五氟戊醇 在 三乙胺 作用下， 以 丙酮 为溶剂， 反应 2.0h， 以93%的产率得到4,4,5,5,5-Pentafluoropentyl 4-(chloromethyl)benzoate
  参考文献：
  名称：

  Fluorinated compound, fluorinated polymer and fluorinated copolymer

  摘要：

  提供具有最多6个碳原子的RF基团的氟化合物，从而可以生产具有高耐久性的抗水/油性的氟化聚合物，并且环境负荷较小，通过聚合这种氟化合物可以获得具有高耐久性的抗水/油性和环境负荷较小的氟化聚合物和氟化共聚物。以下是用下式（I）表示的氟化合物及其聚合物：CH2═C(M)COO(CH2)nPhCOO(CH2)mCrF2r+1  (I)（在式（I）中，M是氢原子，甲基基团或卤素原子，n为0至2的整数，Ph为苯基团，m为1至4的整数，r为1至6的整数）。

  公开号：

  US08471056B2

文献信息

• EP2497763
  申请人：——

  公开号：——

  公开（公告）日：——
• FLUORINATED COMPOUND, FLUORINATED POLYMER AND FLUORINATED COPOLYMER
  申请人：HOSHINO Taiki

  公开号：US20120184695A1

  公开（公告）日：2012-07-19

  To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer and a fluorinated copolymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COO(CH 2 ) n PhCOO(CH 2 ) m CF 2r+1 (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).
• FLUORINATED COMPOUND AND FLUORINATED POLYMER
  申请人：HOSHINO Taiki

  公开号：US20120190809A1

  公开（公告）日：2012-07-26

  To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COO(CH 2 ) n PhXPhZC r F 2r+1 (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, X is CH 2 O or OCH 2 , Z is a single bond, a C 1-4 alkylene group containing an etheric oxygen atom, or COO(CH 2 ) m (wherein m is an integer of from 1 to 4), and r is an integer of from 1 to 6).
• Fluorinated compound, fluorinated polymer and fluorinated copolymer
  申请人：Hoshino Taiki

  公开号：US08471056B2

  公开（公告）日：2013-06-25

  To provide a fluorinated compound having an RF group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer and a fluorinated copolymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH2═C(M)COO(CH2)nPhCOO(CH2)mCrF2r+1  (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).

  提供具有最多6个碳原子的RF基团的氟化合物，从而可以生产具有高耐久性的抗水/油性的氟化聚合物，并且环境负荷较小，通过聚合这种氟化合物可以获得具有高耐久性的抗水/油性和环境负荷较小的氟化聚合物和氟化共聚物。以下是用下式（I）表示的氟化合物及其聚合物：CH2═C(M)COO(CH2)nPhCOO(CH2)mCrF2r+1  (I)（在式（I）中，M是氢原子，甲基基团或卤素原子，n为0至2的整数，Ph为苯基团，m为1至4的整数，r为1至6的整数）。