Perfluoro-1,5-hexadiene | 356-35-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: Perfluoro-1,5-hexadiene
• 英文别名: perfluorohexadiene-1,5；1,1,2,3,3,4,4,5,6,6-decafluoro-hexa-1,5-diene；decafluorobiallyl；decafluoro-hexa-1,5-diene；Decafluor-hexa-1,5-dien；Perfluorhexa-1,5-dien；1,1,2,3,3,4,4,5,6,6-Decafluorohexa-1,5-diene
• CAS: 356-35-4
• 化学式: C₆F₁₀
• 分子量: 262.05
• InChiKey: TUPKEVIZDLRARX-UHFFFAOYSA-N

物化性质

• 沸点：
  60 °C
• 密度：
  1.609 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  Perfluoro-1,5-hexadiene 在 sodium hypochlorite 、 溴 、 锌 作用下， 以 1,4-二氧六环 、 乙腈 为溶剂， 反应 1.0h， 生成 三氟(1,1,2,2,3,4,4-七氟丁-3-烯基)环氧乙烷
  参考文献：
  名称：

  Filyakova, T. I.; Ilatovskii, R. E.; Zapevalov, A. Ya., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, # 10, p. 1818 - 1822

  摘要：

  DOI：
• 作为产物：
  描述：

  3-碘季戊四醇氟代丙烷-1 在 1,4-二氧六环 、 锌 作用下， 生成 Perfluoro-1,5-hexadiene
  参考文献：
  名称：

  Preferential Replacement Reactions of Highly Fluorinated Alkyl Halides. II.¹ Some Reactions of Fluorinated Allyl Iodides^2,3

  摘要：

  DOI：

  10.1021/ja01572a050

文献信息

• The synthesis of new bis/mono fluorinated sultones and their derivatives
  作者：J. Mohtasham、D.G. Cox、D.J. Burton、G.L. Gard

  DOI：10.1016/s0022-1139(00)83973-1

  日期：1989.1

  and are formed via the reaction of sulfur trioxide with 1,5-perfluorohexadiene. In the presence of NaF, and rearranged to give the isomeric products, CF2CF(CF2)2CF(SO2F)C(O)F and [FC(O)CF(SO2F)CF2]2, Respectively. New sulfonyl fluoride esters have been prepared from allyl alcohol and the sultones and ; polymerization of these esters has also been achieved.

  氟化双/单声道β磺内酯，[CF 2（ø 2）CF 2 ] 2和CF 2 CF（CF 2）2 CF（ ，并经由三氧化硫与1,5- perfluorohexadiene反应而形成。在氟化钠的存在下，和重排以得到异构体产物，CF 2 CF（CF 2）2 CF（SO 2 F）C（O）F和[FC（O）CF（SO 2 F）CF 2 ] 2，分别新磺酰氟酯已经从烯丙醇和磺内酯制备和; 这些酯的聚合也已经实现。
• Fluoroepoxides and a process for production thereof
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0100488A1

  公开（公告）日：1984-02-15

  A process for epoxidation of a fluoro-olefin is disclosed. The process comprises epoxidizing a fluoro-olefin represented by the general formula (I): wherein X1, X2 and X3 each represent a substituent selected from (a) -F, (b) a perfluoroalkyl group having 2 to 20 carbon atoms and (c) -CF2Y1, Y1 may be the same or different and represents a substituent selected from (d) a halogen atom selected from F, Cl, Br and I, (e) -OZ1 and (f) -Z1, wherein Z1 may be the same or different and represents a substituted or unsubstituted hydrocarbon group having not more than 20 carbon atoms, and X1, X2, X3 and Y1 may be combined with one another to form a cyclic compound, provided that all of X1, X2, X3 and Y1 do not represent - F; using a hypochlorite dissolved or suspended in an aqueous phase as an oxidizing agent in the presence or absence of an inorganic base. The reaction is performed in a two phase system (aqueous and organic phases) in the presence of at least one phase transfer catalyst selected from (i) quaternary ammonium salts, (ii) quaternary phosphonium salts, (iii) quaternary arsonium salts, (iv) sulfonium salts and (v) lipophilic complexing agents for cations contained in the hypochlorite.

  本发明公开了一种氟烯烃的环氧化工艺。该工艺包括将通式 (I) 所代表的氟烯烃环氧化： 其中 X1、X2 和 X3 各代表一个选自 (a) -F、(b) 具有 2 至 20 个碳原子的全氟烷基和 (c) -CF2Y1 的取代基，Y1 可以相同或不同，并代表一个选自 (d)选自 F、Cl、Br 和 I 的卤素原子、(e) -OZ1 和 (f) -Z1 的取代基、其中 Z1 可以相同或不同，并代表具有不超过 20 个碳原子的取代或未取代的烃基，且 X1、X2、X3 和 Y1 可相互结合形成环状化合物，条件是所有 X1、X2、X3 和 Y1 均不代表-F；在有或没有无机碱的情况下，使用溶解或悬浮在水相中的次氯酸盐作为氧化剂。反应在两相体系（水相和有机相）中进行，存在至少一种相转移催化剂，该催化剂选自(i) 季铵盐、(ii) 季鏻盐、(iii) 季砷盐、(iv) 锍盐和 (v) 次氯酸盐中所含阳离子的亲脂性络合剂。
• Process for the synthesis of perfluoroalkandienes
  申请人：AUSIMONT S.r.l.

  公开号：EP0270956A1

  公开（公告）日：1988-06-15

  Perfluorobutadiene and higher alkandienes, with terminal double bonds, are obtained from α,ω-dibromo or α,ω-bromo iodo per­fluoroalkanes by dehalofluorination carried out at limited reaction times by means of an organometallic compound in the presence of an aprotic solvent selected from the class of hyd­rocarbons or a polar aprotic solvent selected from the class of ethers.

  具有末端双键的全氟丁二烯和高碳烷二烯是由α,ω-二溴或α,ω-溴碘全氟烷烃在有限的反应时间内，通过有机金属化合物，在选自碳氢化合物类的钝性溶剂或选自醚类的极性钝性溶剂存在下进行脱卤氟化反应得到的。
• PROCESS FOR FLUORINATING CELLULOSIC MATERIALS AND FLUORINATED CELLULOSIC MATERIALS
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0890579A1

  公开（公告）日：1999-01-13

  In the fluorinated cellulosic material obtained by a method for fluorinating a cellulosic material by reacting a cellulosic material selected from the group consisting of cellulose material and lignocellulose material with at least one fluorine-containing compound selected from the group consisting of fluorine-containing olefin compound, fluorine-containing acrylate compound and fluorine-containing methacrylate compound in an organic solvent in the present of a catalyst, not only the surface but also the inside of the cellulose and/or lignocellulose materials are modified and high performance of the cellulose and/or lignocellulose materials is realized.

  将选自纤维素材料和木质纤维素材料组的纤维素材料与至少一种选自含氟烯烃化合物组的含氟化合物进行反应，通过使纤维素材料氟化的方法获得氟化纤维素材料、在有催化剂存在的情况下，在有机溶剂中使含氟丙烯酸酯化合物和含氟甲基丙烯酸酯化合物发生反应，从而不仅改变纤维素和/或木质纤维素材料的表面，而且改变其内部，实现纤维素和/或木质纤维素材料的高性能。
• METHOD OF DRY ETCHING, DRY ETCHING GAS AND PROCESS FOR PRODUCING PERFLUORO-2-PENTYNE
  申请人：Zeon Corporation

  公开号：EP1542268A1

  公开（公告）日：2005-06-15

  A dry etching method wherein a resist film is irradiated with radiation having a wavelength of not more than 195 nm to form a resist pattern having a minimum line width of not more than 200 nm, and the substrate having the resist pattern formed thereon is subjected to dry etching using a fluorine-containing compound having 4 to 6 carbon atoms and at least one unsaturated bond as an etching gas. As the fluorine-containing compound, perfuloro-2-pentyne, perfuloro-2-butyne, nonafluoro-2-pentene and perfluoro-2-pentene are preferably used. Perfuloro-2-pentyne is produced by a process wherein a 1,1,1-trihalo-2,2,2-trifluoroethane is allowed to react with pentafluoropropionaldehyde to give a 2-halo-1,1,1,4,4,5,5,5-octafluoro-2-pentene, and the thus-produced halo-octafluoro-2-pentene is dehydrohalogenated.

  一种干法蚀刻方法，其中用波长不超过 195 纳米的辐射照射抗蚀剂薄膜，以形成最小线宽不超过 200 纳米的抗蚀剂图案，并使用具有 4 至 6 个碳原子和至少一个不饱和键的含氟化合物作为蚀刻气体，对在其上形成了抗蚀剂图案的基板进行干法蚀刻。作为含氟化合物，最好使用全氟-2-戊炔、全氟-2-丁炔、非全氟-2-戊烯和全氟-2-戊烯。全氟-2-戊炔的生产工艺是：1,1,1-三卤-2,2,2-三氟乙烷与五氟丙醛反应生成 2-卤-1,1,1,4,4,5,5,5-八氟-2-戊烯，然后将生成的卤代八氟-2-戊烯进行脱氢卤化。