4-benzamido-3-thiosemicarbazide | 13737-44-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-benzamido-3-thiosemicarbazide
• 英文别名: benzamidothiosemicarbazide；Benzoylthiocarbohydrazide；1-amino-3-benzamidothiourea
• CAS: 13737-44-5
• 化学式: C₈H₁₀N₄OS
• 分子量: 210.26
• InChiKey: PTGTZRYWKYSESS-UHFFFAOYSA-N

物化性质

• 熔点：
  210 °C
• 密度：
  1.347±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  111
• 氢给体数：
  4
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-benzamido-3-thiosemicarbazide 在 potassium chloride 、 gelatin 作用下， 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Ansari, M. M.; Jain, M. C.; Malik, Wahid U., Journal of the Indian Chemical Society, 1980, vol. 57, # 9, p. 909 - 912

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium 3-benzoyldithiocarbazinate 在 一水合肼 作用下， 生成 4-benzamido-3-thiosemicarbazide
  参考文献：
  名称：

  Synthesis and characterization of Mn(II) complexes of 4-phenyl(phenyl-acetyl)-3-thiosemicarbazide, 4-amino-5-phenyl-1,2,4-triazole-3-thiolate, and their application towards electrochemical oxygen reduction reaction

  摘要：

  DOI：

  10.1016/j.poly.2019.114125

文献信息

• Syntheses, spectral and structural characterization of Ni(II) complexes of 4-amino-5-phenyl/3-pyridyl/thiophen-2H-1,2,4-triazole-3-thione
  作者：M.K. Bharty、Pooja Bharati、A. Bharti、A. Singh、Sanjay Singh、N.K. Singh

  DOI：10.1016/j.molstruc.2013.10.057

  日期：2014.1

  New mixed ligand complexes [Ni(aptt)(2)(en)(2)] (1), [Ni(aptt)(2)(en)(2)]center dot CHCl3 (2) and Ni(aptt)(2)(en)(2)] (3) with 4-amino-5-phenyl-2H-1,2,4-triazole-3-thione (Haptt), 4-amino-5-(pyridin-3-yl)-4,5-dihydro-3H-1,2,4-triazole-3-thione (Hapytt) and 4-amino-5-thiophen-2H-1,2,4-triazole-3-thione (Hathtt) have been prepared containing en as the secondary ligand. The metal complexes have been characterized with the aid of elemental analyses, IR, magnetic susceptibility and single crystal X-ray data. All the complexes are bonded through two nitrogen atoms of two triazole ligands and four nitrogens of two ethylenediamine and the resulting complexes have distorted octahedral geometry. The triazole ligands behave as uninegative monodentate, bonding through triazole nitrogen due to the hard character of the nickel(11). The complexes contain extended hydrogen bonding providing supramolecular framework. The course of the thermal degradation of complex 2 has been investigated by TG-DTA which suggest the loss of CHCl3 molecule around 200 C and finally a residue of NiS is left behind. (C) 2013 Elsevier B.V. All rights reserved.
• Bekheit, M. M.; Ibrahim, K. M.; Elreash, G. M. Abu, Bulletin de la Societe Chimique de France, 1990, # 2, p. 153 - 156
  作者：Bekheit, M. M.、Ibrahim, K. M.、Elreash, G. M. Abu

  DOI：——

  日期：——
• Shallaby, A. M.; Abu El-Reash, G. M.; Moussa, M. N. H., Bulletin de la Societe Chimique de France, 1989, # 6, p. 776 - 779
  作者：Shallaby, A. M.、Abu El-Reash, G. M.、Moussa, M. N. H.、Khattab, M. A.

  DOI：——

  日期：——
• Sengupta, S. K.; Kumar, Shyam, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1983, vol. 22, # 3, p. 257 - 258
  作者：Sengupta, S. K.、Kumar, Shyam

  DOI：——

  日期：——
• Complexes of copper(I) and silver(I) with some thiocarbazide derivatives
  作者：N.K. Dutt、N.C. Chakder

  DOI：10.1016/s0020-1693(00)95983-8

  日期：1971.3