对叔丁氧基-Alpha-甲基苯乙烯 | 105612-78-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 对叔丁氧基-Alpha-甲基苯乙烯
• 中文别名: 对叔丁氧基-Α-甲基苯乙烯；P-叔丁氧基-alpha-甲基苯乙烯
• 英文名称: para-tertiary butoxy-α-methyl-styrene
• 英文别名: 4-tert-butoxy-α-methylstyrene；4-t-butoxy-α-methylstyrene；4-tert-butoxy-α-methylstyrene；p-tert-butoxy-α-methylstyrene；2-(4-tert-butoxyphenyl)propene；P-tert-Butoxy-alpha-methyl styrene；1-[(2-methylpropan-2-yl)oxy]-4-prop-1-en-2-ylbenzene
• CAS: 105612-78-0
• 化学式: C₁₃H₁₈O
• 分子量: 190.285
• InChiKey: LQDGDDQWVWZDCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2909309090

反应信息

• 作为反应物：
  描述：

  对叔丁氧基-Alpha-甲基苯乙烯 、 苯基羟胺 在 copper(l) chloride 、 copper dichloride 作用下， 以 1,2-二氯乙烷 为溶剂， 以88%的产率得到N-[2-[4-[(2-methylpropan-2-yl)oxy]phenyl]prop-2-enyl]aniline
  参考文献：
  名称：

  Cu(I)/Cu(II)-catalyzed allylic amination of alkenes

  摘要：

  Allylic hydrocarbons are selectively converted to the corresponding allyl amines in good to excellent yield by reaction with aryl hydroxylamines catalyzed by a 1:1 mixture of CuCl and CuCl(2) (10 mol %). Under these conditions unsymmetrical olefins react highly regioselectively with N-functionalization at the less substituted vinylic carbon. Trapping experiments indicate that a free nitrosoarene is not an intermediate in these reactions. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.04.119
• 作为产物：
  描述：

  对氯甲基苯乙烯 、 叔丁醇 在 C₄₇H₅₉ClNiO₅P₂ 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 18.0h， 以75%的产率得到对叔丁氧基-Alpha-甲基苯乙烯
  参考文献：
  名称：

  CgPhen-DalPhos 使镍催化的叔醇与（杂）芳基亲电试剂的 O-芳基化成为可能

  摘要：

  虽然已知脂肪族伯醇或仲醇与（杂）芳基亲电子试剂的 Ni 催化交叉偶联，但涉及脂肪叔醇的相关交叉偶联范围广泛，具有挑战性。在本文中，我们公开了一种以配体 CgPhen-DalPhos 为特征的Ni II预催化剂，它能够促进叔脂肪醇与（杂）芳基卤化物（Cl、Br 和 I）或苯酚衍生物的 C-O 交叉偶联。 OM 和 OPiv）。对底物范围和竞争实验的探索有助于阐明该催化剂体系的能力和反应偏好。

  DOI：

  10.1021/acscatal.1c03010

文献信息

• PHOTORESIST COMPOSITION, RESIST-PATTERN FORMING METHOD, POLYMER, AND COMPOUND
  申请人：SATO Mitsuo

  公开号：US20120258402A1

  公开（公告）日：2012-10-11

  A photoresist composition includes a polymer that includes a structural unit shown by the following formula (1), and a photoacid generator. R 1 in the formula (1) represents a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group, Z represents a group that forms a divalent alicyclic group having 3 to 20 carbon atoms together with a carbon atom bonded to X, X represents an alkanediyl group having 1 to 6 carbon atoms, Y represents a hydrogen atom or —CR 2 R 3 (OR 4 ), and R 2 to R 4 independently represent a hydrogen atom or a monovalent hydrocarbon group, provided that R 3 and R 4 optionally bond to each other to form a cyclic ether structure together with a carbon atom bonded to R 3 and an oxygen atom bonded to R 4 .

  一种光阻剂组合物包括一个聚合物，该聚合物包括下式（1）所示的结构单元，以及一个光酸发生剂。在式（1）中，R1代表氢原子、氟原子、甲基基团或三氟甲基基团，Z代表与与X键合的碳原子一起形成具有3到20个碳原子的二价脂环族基团，X代表具有1到6个碳原子的脂肪二基基团，Y代表氢原子或—CR2R3(OR4)，R2到R4独立地代表氢原子或一价烃基团，其中R3和R4可选择地相互键合以与与R3键合的碳原子和与R4键合的氧原子一起形成环状醚结构。
• Polymer for photoresist, method of production thereof and photoresist composition containing polymer
  申请人：——

  公开号：US20020015906A1

  公开（公告）日：2002-02-07

  A polymer for a photoresist composition is given by the formula (I): 1 wherein R 1 is a hydrogen atom or a methyl group, R 2 is a C 1-12 linear or branched alkyl, haloalkyl or alkoxycarbonyl group, a C 5-12 cyclic alkyl, cyclic haloalkyl or cyclic alkoxycarbonyl group, a phenyl group or a naphthyl group, R 3 is a C 1-12 linear or branched alkyl or haloalkyl group, a C 5-12 cyclic alkyl or cyclic haloalkyl group, a phenyl group, or a naphthyl group, R 4 and R 5 are independently a hydrogen atom, a C 1-6 linear or branched alkyl, or a C 5-6 cyclic alkyl group, R′ and R″ are independently a hydrogen atom, a halogen atom, a C 1-8 alkyl or alkoxy group, a hydroxy group, a carbonate group or a phenyl group, and m, n, p and q are independently an integer provided that m and q are not zero, at least one of n and p are not zero, 0.4≦m/(m+n+p+q)≦0.9, 0≦n/(m+n+p+q)≦0.5, 0≦p/(m+n+p+q)≦0.5, and 0.01≦q/(m+n+p+q)≦0.3.

  给出了一种用于光阻组合物的聚合物，其化学式为（I）：其中R1是氢原子或甲基基团，R2是C1-12线性或支链烷基，卤代烷基或烷氧羰基基团，C5-12环烷基，环卤代烷基或环烷氧羰基基团，苯基或萘基，R3是C1-12线性或支链烷基或卤代烷基，C5-12环烷基或环卤代烷基，苯基或萘基，R4和R5分别是氢原子，C1-6线性或支链烷基或C5-6环烷基基团，R'和R"分别是氢原子，卤素原子，C1-8烷基或烷氧基团，羟基，碳酸酯基或苯基，m，n，p和q是整数，其中m和q不为零，n和p中至少有一个不为零，0.4≤m/(m+n+p+q)≤0.9，0≤n/(m+n+p+q)≤0.5，0≤p/(m+n+p+q)≤0.5，0.01≤q/(m+n+p+q)≤0.3。
• Photoresist compositions containing t-substituted organomethyl vinylaryl
  申请人：General Electric Company

  公开号：US04603101A1

  公开（公告）日：1986-07-29

  t-Butylvinylaryl ethers are provided which can be used to make t-butyl substituted polyaryl ethers and photoresist compositions. The photoresist compositions can be made by combining the t-butylpolyaryl ethers with aromatic onium salts.

  提供了t-叔丁基乙烯基芳基醚，可用于制备t-叔丁基取代的聚芳醚和光刻胶组合物。光刻胶组合物可通过将t-叔丁基聚芳醚与芳香族铵盐组合而成。
• Production Method of Polymers By Using Living Anionic Polymerization Method
  申请人：Takahashi Eiji

  公开号：US20070225457A1

  公开（公告）日：2007-09-27

  An anionic polymerizable monomer is added to a reaction system in which an anion species which is incapable of initiating polymerization but may react with polymerization inhibiting substances to convert them into compounds that do not inhibit polymerization is present, and then an anion species capable of initiating polymerization is added thereto. It becomes possible to produce high molecular weight polymers and to precisely control the molecular weight thereof even if polymerization inhibiting substances are present in the system or when polymerization inhibiting substances enter from outside.

  在反应系统中加入一种阴离子可聚合单体，该反应系统中存在一种无法启动聚合但可与聚合抑制物质反应将其转化为不抑制聚合的阴离子物种，然后加入一种能够启动聚合的阴离子物种。即使系统中存在聚合抑制物质或当聚合抑制物质从外部进入时，也可以生产高分子量聚合物并精确控制其分子量。
• PRODUCTION METHOD OF POLYMERS BY USING LIVING ANIONIC POLYMERIZATION METHOD
  申请人：Takahashi Eiji

  公开号：US20080045677A2

  公开（公告）日：2008-02-21

  An anionic polymerizable monomer is added to a reaction system in which an anion species which is incapable of initiating polymerization but may react with polymerization inhibiting substances to convert them into compounds that do not inhibit polymerization is present, and then an anion species capable of initiating polymerization is added thereto. It becomes possible to produce high molecular weight polymers and to precisely control the molecular weight thereof even if polymerization inhibiting substances are present in the system or when polymerization inhibiting substances enter from outside.

  在反应系统中加入一种阴离子可聚合单体，该反应系统中存在一种无法启动聚合但可以与聚合抑制物质反应将其转化为不抑制聚合的阴离子物种，然后加入一种能够启动聚合的阴离子物种。即使系统中存在聚合抑制物质或聚合抑制物质从外部进入，也可以生产高分子量聚合物并精确控制其分子量。