N-formyllycoposerramine-T | 1229626-44-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-formyllycoposerramine-T
• 英文别名: (7E,9aS,11S,13S,13aS)-4-formyl-2,3,4,5,6,8,9,9a,10,11,12,13-dodecahydro-11-methyl-8-oxo-1H-indeno[1,7a-c]azonine-11,13-diyl diacetate；[(1S,2S,4S,6S,9E)-4-acetyloxy-13-formyl-4-methyl-8-oxo-13-azatricyclo[7.7.0.01,6]hexadec-9-en-2-yl] acetate
• CAS: 1229626-44-1
• 化学式: C₂₁H₂₉NO₆
• 分子量: 391.464
• InChiKey: GZNSSKIGISHIIJ-QLBHIOJPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  90
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,2,2-三氟乙基甲酸酯 、 (+/-)-lycoposerramine T 以 甲基叔丁基醚 为溶剂， 反应 2.5h， 以52%的产率得到N-formyllycoposerramine-T
  参考文献：
  名称：

  一种新的石松生物碱，Lycoposerramine-R，具有新颖骨架和三新Fawcettimine相关生物碱蛇足石松

  摘要：

  Abstractmagnified imageA new Lycopodium alkaloid, lycoposerramine‐R, possessing an unusual tetracyclic ring system, was isolated from Lycopodium serratum. Its structure as well as those of three new co‐existing fawcettimine‐related alkaloids were elucidated by means of extensive spectroscopic analysis.

  DOI：

  10.1002/hlca.200800327

文献信息

• A New<i>Lycopodium</i>Alkaloid, Lycoposerramine-R, with a Novel Skeleton and Three New Fawcettimine-Related Alkaloids from<i>Lycopodium serratum</i>
  作者：Kazuaki Katakawa、Noriyuki Kogure、Mariko Kitajima、Hiromitsu Takayama

  DOI：10.1002/hlca.200800327

  日期：2009.3

  Abstractmagnified imageA new Lycopodium alkaloid, lycoposerramine‐R, possessing an unusual tetracyclic ring system, was isolated from Lycopodium serratum. Its structure as well as those of three new co‐existing fawcettimine‐related alkaloids were elucidated by means of extensive spectroscopic analysis.