1,4-dilithio-1,3-butadiyne | 65864-08-6

• 分子结构分类: 有机化合物 - 乙炔化物 - 碳化物
• 英文名称: 1,4-dilithio-1,3-butadiyne
• 英文别名: 1,4-dilithiobutadiyne；Li2 butadiynediyl；dilithiobutadiyne
• CAS: 65864-08-6
• 化学式: C₄Li₂
• 分子量: 61.926
• InChiKey: DNIRZXBLRJXGQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,4-dilithio-1,3-butadiyne 、 三乙基溴化锗 以 四氢呋喃 为溶剂， 以76%的产率得到1,4-bis(triethylgermyl)-1,3-butadiyne
  参考文献：
  名称：

  新型聚[（亚甲硅基）二乙炔]和聚[（亚甲二基）二乙炔]：合成与导电性能

  摘要：

  The reaction of dilithiobutadiyne (or the corresponding di-Grignard reagent) with various dichlorosilanes and dibromogermanes in THF at room temperature afforded poly[(silylene)diacetylenes] and poly[(germylene)diacetylenes], respectively, in high yields. The polymers have a regular alternating arrangement of diyne and silylene or germylene units. When they are doped with FeCl3, these polymers show conductivity values in the range 10(-5)-10(-3) S.cm-1. The values depend greatly on the electronic character of the substituents bonded to silicon or germanium.

  DOI：

  10.1021/om00043a037
• 作为产物：
  描述：

  六氯-1,3-丁二烯 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 2.0h， 生成 1,4-dilithio-1,3-butadiyne
  参考文献：
  名称：

  Extended Silapericyclynes

  摘要：

  通过二锂硫代丁二炔与二氯二异丙基硅烷的反应合成中至大元环状硅丁二炔化合物（“扩展硅杂环炔”）。环状四聚体、五聚体、六聚体和七聚体的产率分别为8%、5%、4%和2%。确定了四聚体的结构，并观察到柱状堆积。还显示了所有化合物的紫外光谱。

  DOI：

  10.1246/cl.2001.340
• 作为试剂：
  描述：

  正丁基锂 、 六氯-1,3-丁二烯 、 二甲基二甲氨基氯硅烷 在 乙醚 、 1,4-dilithio-1,3-butadiyne 、 正戊烷 作用下， 反应 19.17h， 以to give 2.91 g (96%) of 1,4-bis(dimethylaminodimethylsilyl)butadiyne 206 as a viscous red liquid的产率得到1,4-bis(dimethylaminodimethylsilyl)-butadiyne
  参考文献：
  名称：

  Synthesis of oligomeric poly(silarylene-siloxane-acetylene)'s and their conversion to high temperature plastics, elastomers, and coatings

  摘要：

  本发明涉及一种网络聚合物，其化学式为：1其中n≥1；其中n是通过对网络聚合物的所有重复单元进行平均获得的平均值；其中m≥1；其中Y是含有一个或多个乙炔基，一个或多个乙烯基交联或两者的二价基团；其中z是交联密度；其中Ar1和Ar2是独立选择的芳香基团；每个R独立选择自烷基，芳基，烷基芳基，卤代烷基，卤代芳基及其组合的群。本发明还包括制备网络聚合物所需的预聚物和前体以及制备上述所有物的过程。本发明还包括通过网络聚合物的热解制备的陶瓷组合物。

  公开号：

  US20030158362A1

文献信息

• Facile electronic communication between bimetallic termini bridged by elemental carbon chains
  作者：Tong Ren、Gang Zou、Julio C. Alvarez

  DOI：10.1039/b002777o

  日期：——

  Rich electrochemistry and strong electronic couplings across the carbon bridges are revealed for compounds composed of two tetra(μ-N,N′-2-anilinopyridinate)diruthenium(II ,III) termini bridged by either butadiynediyl (1) or ethynediyl (2) ligands.

  由丁炔二基（1）或乙炔二基（2）配体桥接的两个四(μ-N,N′-2-anilinopyridinate)二钌(II,III)端子组成的化合物具有丰富的电化学特性和碳桥上的强电子耦合。
• The preparation of HfC/C ceramics via molecular design
  作者：Kathrin Inzenhofer、Thomas Schmalz、Bernd Wrackmeyer、Günter Motz

  DOI：10.1039/c0dt01817a

  日期：——

  Polymer derived ceramics have received lots of attention throughout the last few decades. Unfortunately, only a few precursor systems have been developed, focusing on silicon based polymers and ceramics, respectively. Herein, the synthesis of novel hafnium containing organometallic polymers by two different approaches is reported. Dialkenyl substituted hafnocene monomers were synthesized and subsequently polymerized via a free radical mechanism. Salt metathesis reactions of hafnocene dichloride with bifunctional linkers led to the formation of polymeric materials. NMR spectroscopic methods – in solution as well as in the solid state – were used to characterize the organometallic polymers. Ceramics were finally obtained after cross-linking and thermal treatment under argon (Tmax = 1800 °C). SEM investigations, elemental analyses, Raman spectroscopy and XRD investigations identified the pyrolyzed products as partially crystalline HfC/C mixed phases.

  过去几十年来，聚合物衍生陶瓷受到了广泛关注。遗憾的是，目前仅开发出几种前驱体系统，分别侧重于硅基聚合物和陶瓷。本文报告了通过两种不同方法合成新型含铪有机金属聚合物的情况。合成了二苯乙烯取代的铪单体，随后通过自由基机制进行聚合。二氯化铪与双官能团连接体的盐偏合成反应导致了聚合物材料的形成。利用核磁共振光谱方法（溶液和固态）对有机金属聚合物进行了表征。经过交联和氩气热处理（Tmax = 1800 °C）后，最终获得了陶瓷。通过 SEM 研究、元素分析、拉曼光谱和 XRD 研究，确定热解产物为部分结晶的 HfC/C 混合相。
• Polymeric organosilicon system VIII. Synthesis of poly[(disilanylene)diethynylene] with highly conducting properties
  作者：Mitsuo Ishikawa、Yutaka Hasegawa、Atsutaka Kunai、Toru Yamanaka

  DOI：10.1016/0022-328x(90)80071-7

  日期：1990.1

  of methyllithium, followed by 1,2-dichloro-1,2-dimethyldiphenyl- or 1,2-dichloro-1,2-diethyldimethyldisilane gives poly[(1,2-dimethyldiphenyldisilanylene)diethynylene] (II) or poly[(1,2- diethyldimethyldisilanylene)diethynylene] (III), respectively. Films of II and III become conducting when treated with SbF5 vapor.

  双（三甲基甲硅烷基）丁二炔与2当量的反应 甲基锂，然后用1,2-二氯-1,2-二甲基二苯基-或1,2-二氯-1,2-二乙基二甲基二硅烷制得聚[（1,2-二甲基二苯基二亚硅烷基）二乙炔]（II）或聚[（1， [2-二乙基二甲基二亚硅烷基] [二亚乙炔基]（III）。当用SbF 5蒸气处理时，II和III的薄膜开始导电。
• Polyyn-diyls Capped by Diruthenium Termini:  A New Family of Carbon-Rich Organometallic Compounds and Distance-Dependent Electronic Coupling Therein
  作者：Guo-Lin Xu、Gang Zou、Yu-Hua Ni、Maria C. DeRosa、Robert J. Crutchley、Tong Ren

  DOI：10.1021/ja035434j

  日期：2003.8.1

  Polyyn-diyls capped by Ru-2(ap)(4) termini (ap = 2-anilinopyridinate), that is, [Ru-2(ap)(4)](mu-C,C'-C-2m)[Ru-2(ap)(4)] (compounds 1-5 with m = 1-4 and 6), were synthesized through either a metathesis reaction between Ru-2(ap)(4)Cl and LiC2mLi or a Glaser homocoupling reaction of Ru-2(ap)(4)(CmH) under Eglinton/Hay conditions. X-ray diffraction studies of compounds 2 and 4 revealed both the linear rigid rod topology of these compounds and the fine structural details about the Ru-2 cores and polyyn-diyl chains. Cyclic and differential pulse voltammetric (CV and DPV) measurements and spectroelectrochemical studies show that reduced and oxidized forms of 1, 2, 4, and 5 are donor-acceptor systems in which the Ru-2 termini are coupled to varying degrees depending upon the length of the polyyn-diyl bridge.
• Wong, Andrew; Kang, Peter C. W.; Tagge, Christopher D., Organometallics, 1990, vol. 9, # 7, p. 1992 - 1994
  作者：Wong, Andrew、Kang, Peter C. W.、Tagge, Christopher D.、Leon, David R.

  DOI：——

  日期：——