溴化氢-乙炔络合物 | 73787-83-4

• 分子结构分类: 有机化合物 - 碳化物
• 中文名称: 溴化氢-乙炔络合物
• 英文名称: hydrogen bromide-acetylene complex
• 英文别名: Ethyne hydrogen bromide；acetylene;hydrobromide
• CAS: 73787-83-4
• 化学式: BrH*C₂H₂
• 分子量: 106.95
• InChiKey: YXWSUHSVMWUGFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.83
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  溴乙烯 以 solid matrix 为溶剂， 生成 溴乙炔 、 溴化氢-乙炔络合物
  参考文献：
  名称：

  Photochemistry and Dynamics of Vinyl Bromide and Vinyl Iodide in Rare Gas Matrixes

  摘要：

  Dilute solid solutions of vinyl bromide in krypton and vinyl iodide in argon were photolyzed at 10 K with a medium pressure mercury lamp. When the vinyl bromide is photolyzed, both hydrogen bromide-acetylene complexes and bromoacetylene are observed as photolysis products. Kinetic analysis shows that the hydrogen bromide-acetylene complexes are the only primary photolysis products and that the bromoacetylene is formed by secondary photolysis of the hydrogen bromide-acetylene complexes. Similar results are observed for the photolysis of vinyl iodide, with hydrogen iodide-acetylene complexes the only primary products and iodoacetylene observed as a secondary photolysis product of the hydrogen iodide-acetylene complex. We present the first reported vibrational frequencies for the HI-acetylene complex.

  DOI：

  10.1021/j100026a012

文献信息

• Infrared spectra of hydrogen-bonded .pi. complexes between hydrogen halides and acetylene
  作者：Stephen A. McDonald、Gary L. Johnson、Brian W. Keelan、Lester Andrews

  DOI：10.1021/ja00529a004

  日期：1980.4