diphenylsulfur diimide | 3839-89-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenylsulfur diimide
• 英文别名: 1,3-di(phenyl)-2-thia-1,3-dazaallene；1,3-diphenyl-2-thia-1,3-diazaallene；N,N'-bis(phenyl)sulphur di-imide；N,N'-bisphenylsulphurdiimide；Z/E-Diphenyl sulphur diimide；Z/Z-Diphenyl sulphur diimide；Bis(phenylimino)-lambda4-sulfane；bis(phenylimino)-λ4-sulfane
• CAS: 3839-89-2；66085-13-0；66085-14-1；66085-15-2
• 化学式: C₁₂H₁₀N₂S
• 分子量: 214.291
• InChiKey: DRNRMWYQJNNPBV-UHFFFAOYSA-N

物化性质

• 沸点：
  97 °C(Press: 0.3 Torr)
• 密度：
  1.190 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  diphenylsulfur diimide 在 间氯过氧苯甲酸 作用下， 以 氯仿 、 苯 为溶剂， 25.0~110.0 ℃ 、133.32 Pa 条件下， 反应 24.5h， 生成 2,4,4-Triphenyl-1,2-thiazetidin-3-on-1-oxid
  参考文献：
  名称：

  Reactions of sulfur diimides with ketenes

  摘要：

  DOI：

  10.1021/jo00797a010
• 作为产物：
  描述：

  N-亚磺酰苯胺 在 potassium tert-butylate 作用下， 生成 diphenylsulfur diimide
  参考文献：
  名称：

  Carpanelli, Corrado; Gaiani, Giovanni, Gazzetta Chimica Italiana, 1983, vol. 113, # 7/8, p. 503 - 506

  摘要：

  DOI：

文献信息

• Rapid and Effective Synthesis of Diarylsulfur Diimides from Substituted Anilines and Sulfur Monochloride
  作者：Oleg Rakitin、Lidia Konstantinova、Kirill Lysov

  DOI：10.1055/s-0032-1318140

  日期：——

  Abstract A one-pot and effective procedure has been developed for the synthesis of symmetrical diarylsulfur diimides from anilines, sulfur monochloride, and DABCO in good yields (70–90%). A plausible mechanism for this transformation has been proposed. A one-pot and effective procedure has been developed for the synthesis of symmetrical diarylsulfur diimides from anilines, sulfur monochloride, and DABCO

  摘要 已经开发了一种一锅有效的方法，可以以良好的收率（70-90％）从苯胺，一氯化硫和DABCO合成对称的二芳基硫二酰亚胺。已经提出了这种转变的合理机制。 已经开发了一种一锅有效的方法，可以以良好的收率（70-90％）从苯胺，一氯化硫和DABCO合成对称的二芳基硫二酰亚胺。已经提出了这种转变的合理机制。
• Novel Palladium(II)-Catalyzed Cyclization of Aziridines and Sulfur Diimides
  作者：Jin-Ook Baeg、Howard Alper

  DOI：10.1021/ja00083a007

  日期：1994.2

  cyclization reaction of aziridines and sulfur diimides, in toluene, affording imidazolidinethiones in 52-70% yield. Reaction of an aziridine, labels with 13 C at one of the ring carbons, with a sulfur diimide resulted in incorporation of the label at the 2- and 5-positions of the imidazolidinethione. Thiazolidinimine formation results from the palladium(II)-catalyzed reaction of an aziridine with phenyl isothiocyanate

  双（苯甲腈）二氯化钯是氮丙啶和二亚胺硫在甲苯中环化反应的有效催化剂，以 52-70% 的产率得到咪唑烷硫酮。氮丙啶（在环碳之一上带有 13 C 标记）与二亚胺硫的反应导致在咪唑烷硫酮的 2 位和 5 位引入标记。噻唑烷亚胺的形成是由钯 (II) 催化的氮丙啶与异硫氰酸苯酯的反应产生的
• One-electron reduction of di-imidosulphur compounds, S(NR)2, and some complexes of Group 6A metal carbonyl derivatives containing S(NR)2 ligands: studies of the radical products by electron spin resonance spectroscopy
  作者：John A. Hunter、Boyd King、W. Edward Lindsell、Margaret A. Neish

  DOI：10.1039/dt9800000880

  日期：——

  Reduction of the di-imidosulphur compounds, S(NR)2(R = But, Ph, 4-MeC6H4, or 4-O2NC6H4), in 1,2-dimethoxyethane solution with a potassium mirror in vacuo gives fairly stable solutions of the corresponding anion radicals [S(NR)2]– which have been studied by e.s.r. spectroscopy. The frozen-solution e.s.r spectrum of K[S(NBut)2] has also been recorded. Isotropic coupling constants A(14N), A(1H) and, for

  在带有钾镜的1,2-二甲氧基乙烷溶液中还原二亚氨基硫化合物S（NR）2（R = Bu t，Ph，4-MeC 6 H 4或4-O 2 NC 6 H 4）在真空中得到相应的阴离子自由基[S（NR）的相当稳定的解决方案2 ] -已经研究了通过ESR光谱。还记录了K [S（NBu t）2 ]的冷冻溶液esr光谱。各向同性耦合常数A（14 N），A（1 H），并且对于R = Bu t，A（33 S）已根据经验的电子密度关系根据自由基的电子结构进行了推导和分析。已经进行了一些CNDO / 2和INDO计算，并对实验和计算出的电子自旋密度进行了比较。可变温度esr测量未提供溶液中阴离子存在不同几何异构体的迹象。模型计算表明，E / E构象最稳定，并且相互转换可以得到E / Z或Z / Z形式是不可能的。在所有情况下的实验证据表明两个氮原子在磁性上是等价的。物种M I [S（NBu t）2 ]（M I =
• REACTION OF KETENIMINE AND SULFUR DIIMIDE
  作者：Nobuyuki Murai、Mitsuo Komatsu、Yoshiki Ohshiro、Toshio Agawa

  DOI：10.1246/cl.1976.1379

  日期：1976.12.5

  The reaction of diphenylketene-N-phenylimine (1) and diphenylsulfur diimide (2) gave the 2-aminoindole 4 as a major product together with the benzothiatriazepine 3 and the amidine 5.

  二苯基乙烯酮-N-苯基亚胺 (1) 和二苯基硫二亚胺 (2) 的反应得到 2-氨基吲哚 4 作为主要产物以及苯并硫三氮卓 3 和脒 5。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。