3-(对壬基苯氧基)丙烷-1,2-二醇 | 7598-63-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 3-(对壬基苯氧基)丙烷-1,2-二醇
• 英文名称: 3-(4-n-nonylphenoxy)-propane-1,2-diol
• 英文别名: 3-(p-nonylphenoxy)propane-1,2-diol；1-p-Nonylphenyl glycerol ether；3-(4-nonylphenoxy)propane-1,2-diol
• CAS: 7598-63-2
• 化学式: C₁₈H₃₀O₃
• 分子量: 294.434
• InChiKey: IHMSRKRQXGKFCB-UHFFFAOYSA-N

物化性质

• 沸点：
  448.2±30.0 °C(Predicted)
• 密度：
  1.014±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  对壬基酚 、 3-氯-1,2-丙二醇 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 反应 2.0h， 生成 3-(对壬基苯氧基)丙烷-1,2-二醇
  参考文献：
  名称：

  甘油的手性对烷基苯基醚：手性驱动的结晶，液晶和胶凝性能的合成和测试

  摘要：

  合成了一系列对映纯和外消旋对烷基苯甘油醚1a - k。开发了一种新的，灵敏的，图形的固体对映体纯和外消旋样品红外光谱比较的方法，以获得有关这些化合物的结晶类型的初步信息。为了检测手性固相组织中的细微差异，一种新的易于实施的方法是基于色谱法，该方法测量单一溶液中对映体的相对丰度，该溶液与任意（0

  DOI：

  10.1016/j.tetasy.2013.05.017

文献信息

• Thermoplastic saturated norbornene group polymer composition
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0498564A2

  公开（公告）日：1992-08-12

  Provided is a resin composition based on a thermoplastic saturated norbornene group polymer which is excellent in adhesion to the recording film of optical disks and adhesion to a hard coating film or a protective film formed by coating an acrylic ultraviolet curing coating material or like films without deteriorating excellent heat resistance and transparency inherent to thermoplastic saturated norbornene group polymers. Also provided are optical disk substrates and optical disks by using said composition. A composition comprising a thermoplastic saturated norbornene group polymer and a partially etherified product of a polyhydric alcohol having 3 or more hydroxyl groups incorporated thereinto. An optical disk substrate formed of said composition and an optical disk comprising said optical disk substrate and an information recording film and/or a light reflecting film and a protective film laminated thereon.

  本发明提供了一种基于热塑性饱和降冰片烯基聚合物的树脂组合物，该组合物与光盘记录膜的粘合性以及与硬涂膜或通过涂覆丙烯酸紫外线固化涂层材料或类似薄膜而形成的保护膜的粘合性极佳，且不会降低热塑性饱和降冰片烯基聚合物固有的优异耐热性和透明度。此外，还提供了使用所述组合物的光盘基板和光盘。 一种组合物，由热塑性饱和降冰片烯基聚合物和含有 3 个或 3 个以上羟基的多元醇的部分醚化产物组成。由所述组合物形成的光盘基板，以及由所述光盘基板和信息记录膜和/或光反射膜以及层压在其上的保护膜组成的光盘。
• Medical implement, polymer composition and optical material
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0559146A1

  公开（公告）日：1993-09-08

  A polymer composition comprising a thermoplastic norbornene polymer which preferably has a number average molecular weight of 10,00 - 200,000 as determined by gel permeation chromatography in toluene solvent and calculated as styrene and a content of norbornene polymer components having a number average molecular weight of 2,000 or less of 1% by weight or less, and a compounding ingredient, such as a rubber-like polymer, wherein the compounding ingredient is preferably dispersed in the form of microdomains in the norbornene polymer; and medical implements and optical naturals formed essentially of the composition.

  一种聚合物组合物，它包含一种热塑性降冰片烯聚合物（在甲苯溶剂中通过凝胶渗透色谱法测定，其平均分子量最好在 10,00 - 200,000 之间，并以苯乙烯计算），以及一种平均分子量在 2,000 或以下的降冰片烯聚合物成分，其含量为 1%（按重量计）或更少；还包含一种复合成分，如橡胶类聚合物，其中复合成分最好以微域的形式分散在降冰片烯聚合物中；以及主要由该组合物形成的医疗器械和光学天然材料。
• HYDROGENATED RING-OPENING POLYMER
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0784066A1

  公开（公告）日：1997-07-16

  A thermoplastic norbornene resin having a number-average molecular weight (Mn) of 12,000 or more in terms of polyisoprene value measured by gel permeation chromatography and excellent in low birefringence property and resistance to deterioration with greases and oils is obtained by ring-opening polymerizing a polycyclic norbornene monomer containing at least 70% by weight of a norbornene monomer represented by the following formula I (for example, 1,4-methano-1,4,4a,9a-tetrahydrofluorene): (wherein the lower 6-membered ring structure may have a double bond) and hydrogenating the polymer so that the hydrogenation rate of double bond in the main chain is at least 98% and the hydrogenation rate of the 6-membered ring structure is at least 90%.

  一种热塑性降冰片烯树脂，用凝胶渗透色谱法测定其平均分子量（Mn）为 12、一种热塑性降冰片烯树脂，其通过凝胶渗透色谱法测量的聚异戊二烯值的数均分子量（Mn）为 12,000 或以上，并具有优异的低双折射特性和抗油脂劣化性能，其方法是将含有至少 70%（重量）由下式 I 代表的降冰片烯单体（例如，1,4-甲桥-1,4,4a,9a-四氢芴）的多环降冰片烯单体开环聚合： (其中下部 6 元环结构可能有一个双键），并对聚合物进行氢化，使主链中双键的氢化率至少为 98%，6 元环结构的氢化率至少为 90%。
• RESIN COMPOSITION CONTAINING VINYLIC CYCLIC HYDROCARBON POLYMER AND PRODUCT OF MOLDING THEREOF
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP1000974A1

  公开（公告）日：2000-05-17

  A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65°C in temperature and 90% in relative humidity satisfy the relationship of the equation (1):[(b)/(a)] x 100 ≥ 70 and a resin composition.

  一种通过模塑或成型树脂组合物获得的模塑或成型产品，该树脂组合物包含(A)至少一种乙烯基环烃聚合物，该聚合物选自由芳香族乙烯基聚合物的氢化产物、乙烯基环己烯聚合物或其氢化产物和乙烯基环己烷聚合物组成的组；以及(B)至少一种物质，该物质选自由与聚合物不相容的复合添加剂、具有至少一个醇羟基和至少一个醚键的有机化合物组成的组；以及具有至少一个醇羟基和至少一个酯键的有机化合物、其中模塑或成型产品在 400 至 800 纳米范围内的任选波长下的初始透光率 (a) 和模塑或成型产品在温度为 65°C 和相对湿度为 90% 的环境中保持 1,000 小时后的透光率 (b) 满足公式 (1) 的关系：[(b)/(a)] x 100 ≥ 70 和树脂成分。
• HYDROGENATED POLYMERS, RESIN COMPOSITION, AND PROCESS FOR PRODUCING SUBSTRATE FOR INFORMATION-RECORDING MEDIUM
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP1193274A1

  公开（公告）日：2002-04-03

  A hydrogenated product of an aromatic vinyl polymer, wherein the hydrogenation rate of the aromatic rings thereof is at least 97%, a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is at most 2.0, the weight average molecular weight (Mw) is 100,000 to 300,000, and the content of a component having a molecular weight (M) of at most 10,000 is at most 2% by weight based on the total weight of the polymer; a hydrogenated product of an aromatic vinyl polymer, wherein the content of foreign matter having a particle diameter of at least 0.5 µm in the hydrogenated polymer is at most 3.0 x 104 particles/g; and a substrate for information recording media obtained by molding a resin material containing a hydrogenated product of an aromatic vinyl polymer, wherein the hydrogenation rate of the aromatic rings thereof is at least 97%, a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is at most 2.0, and the weight average molecular weight (Mw) is 100,000 to 300,000, and production process thereof.

  一种芳香族乙烯基聚合物的氢化产品，其中芳香环的氢化率至少为 97%，重量平均分子量（Mw）与数量平均分子量（Mn）之比（Mw/Mn）最多为 2.0，重量平均分子量(Mw)为 100,000 至 300,000，分子量(M)至多为 10,000 的组分的含量至多为聚合物总重量的 2% (按重量计)；芳香族乙烯基聚合物的氢化产物，其中在氢化聚合物中颗粒直径至少为 0.5 µm 的异物含量最多为 3.0 x 104 个颗粒/克；以及通过模塑含有芳香族乙烯基聚合物氢化产物的树脂材料而获得的信息记录介质基底，其中芳香环的氢化率至少为 97%，重量平均分子量（Mw/Mn）与数量平均分子量（Mn）之比（Mw/Mn）最多为 2.0，重量平均分子量（Mw）为 100,000 至 300,000 及其生产工艺。