(E/Z)-deca-7,9-dien-1-yl acetate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E/Z)-deca-7,9-dien-1-yl acetate
• 英文别名: Deca-7,9-dienyl acetate；deca-7,9-dienyl acetate
• 化学式: C₁₂H₂₀O₂
• 分子量: 196.29
• InChiKey: WZPZAOAOPMQYAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  丁烯 、 (E/Z)-deca-7,9-dien-1-yl acetate 在 Z-selective cross-metathesis catalyst 作用下， 生成 (7Z,9e)-7,9-乙酸十二二烯酯
  参考文献：
  名称：

  [EN] SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS
  [FR] SYNTHÈSE DE PHÉROMONES ET DE MATÉRIAUX APPARENTÉS PAR MÉTATHÈSE D'OLÉFINES

  摘要：

  公开号：

  WO2018150379A3
• 作为产物：
  描述：

  1,8-辛二醇 在 aluminum oxide 、 sodium acetate 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 甲苯 、 苯 为溶剂， 反应 28.0h， 生成 (E/Z)-deca-7,9-dien-1-yl acetate
  参考文献：
  名称：

  [EN] SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS
  [FR] SYNTHÈSE DE PHÉROMONES ET DE MATÉRIAUX APPARENTÉS PAR MÉTATHÈSE D'OLÉFINES

  摘要：

  公开号：

  WO2018150379A3

文献信息

• Synthesis of pheromones and related materials via olefin metathesis
  申请人：Provivi, Inc.

  公开号：US11155505B2

  公开（公告）日：2021-10-26

  Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.

  描述了通过基于过渡偏合成的合成路线制备烯烃（包括 8-和 11-不饱和单烯和多烯）的方法。方法中的偏合成反应由过渡金属催化剂催化，包括钨基、钼基和钌基催化剂。这些烯烃包括一些农业应用中有用的昆虫信息素。
• Sustained releaser comprising sex pheromone substances and pest control method
  申请人：Hojo Tatsuya

  公开号：US20060057177A1

  公开（公告）日：2006-03-16

  Provided are a sustained releaser of sex pheromone substances and a method for controlling insect pest by using the releaser, each enabling to control the simultaneous release of a mixture of sex pheromone substances having different chemical structures of one insect pest or a mixture of sex pheromone substances of insect pests, and each enabling to release the sex pheromone substances at a fixed rate or greater during the infestation period or periods of the respective insect pest or pests. More specifically, provided is a sustained releaser of sex pheromone substances comprising one or more first sex pheromone substances selected from linear aliphatic aldehyde having 10 to 18 carbon atoms, one or more second sex pheromone substances selected from aldehyde-free aliphatic derivatives having 7 to 20 carbon atoms, and first and second chambers each made of polymer material, wherein all of the first sex pheromone substances or all of the first sex pheromone substances and some of the second sex pheromone substances are enclosed in the first chamber and the remainder of the sex pheromone substances is enclosed in the second chamber.

  本发明提供了一种性信息素物质持续释放剂和一种使用该释放剂控制害虫的方法，每种释放剂都能控制一种害虫或一种害虫的性信息素物质混合物具有不同化学结构的性信息素物质的同时释放，并且每种释放剂都能在相应害虫的一种或多种侵扰期间以固定或更大的速率释放性信息素物质。更具体地说，本发明提供了一种性信息素物质持续释放器，包括一种或多种选自具有 10 至 18 个碳原子的线性脂族醛的第一性信息素物质、一种或多种选自具有 7 至 20 个碳原子的无醛脂族衍生物的第二性信息素物质、以及各自由聚合物材料制成的第一和第二腔室，其中所有第一性信息素物质或所有第一性信息素物质和部分第二性信息素物质被封闭在第一腔室中，其余性信息素物质被封闭在第二腔室中。
• JPH0232002A
  申请人：——

  公开号：JPH0232002A

  公开（公告）日：1990-02-01
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.
• SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS
  申请人：Provivi, Inc.

  公开号：US20200039900A1

  公开（公告）日：2020-02-06

  Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.