2-[2-(三氯甲硅烷基)乙基]吡啶 | 17082-69-8

• 物质功能分类: 化学试剂 - 硅烷试剂
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 2-[2-(三氯甲硅烷基)乙基]吡啶
• 中文别名: 2-[2-(三氯硅基)乙基]嘧啶；2-[2-(三氯硅基)乙基]吡啶
• 英文名称: 2-trichlorosilylethylpyridine
• 英文别名: trichloro-(2-[2]pyridyl-ethyl)-silane；Trichlor-(2-[2]pyridyl-aethyl)-silan；2-[2-(trichlorosilyl)ethyl]pyridine；trichloro(2-pyridin-2-ylethyl)silane
• CAS: 17082-69-8
• 化学式: C₇H₈Cl₃NSi
• mdl: MFCD00023532
• 分子量: 240.592
• InChiKey: GNXIZLXABHCZPO-UHFFFAOYSA-N

物化性质

• 熔点：
  280°C (dec.)
• 沸点：
  280°C
• 密度：
  1.297±0.06 g/cm3(Predicted)
• 闪点：
  >65°C

计算性质

• 辛醇/水分配系数(LogP)：
  2.73
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.285
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• TSCA：
  Yes
• 危险类别码：
  R34
• 危险品运输编号：
  UN 2987
• 海关编码：
  2933399090
• 安全说明：
  S26
• 储存条件：
  存储条件：2-8°C，需密封并保持干燥。

SDS

Name:	2-(2-(Trichlorosilyl)ethyl)pyridine 96% Material Safety Data Sheet
Synonym:
CAS:	17082-69-8

Section 1 - Chemical Product MSDS Name:2-(2-(Trichlorosilyl)ethyl)pyridine 96% Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
17082-69-8	2-(2-(Trichlorosilyl)ethyl)pyridine	96%	241-137-8

Hazard Symbols: C
Risk Phrases: 14 34

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May cause contact dermatitis.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Not available.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water Reactive. Material will react with water and may release a flammable and/or toxic gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

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Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area. Store under argon.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 17082-69-8: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 280 deg C (dec.)
Autoignition Temperature: Not available.
Flash Point: > 65 deg C (> 149.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density:
Molecular Formula: C7H8Cl3NSi
Molecular Weight: 240.59

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, silicon dioxide.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 17082-69-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-(2-(Trichlorosilyl)ethyl)pyridine - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 17082-69-8: No information available.
Canada
CAS# 17082-69-8 is listed on Canada's NDSL List.
CAS# 17082-69-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 17082-69-8 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  甲醇 、 2-[2-(三氯甲硅烷基)乙基]吡啶 在 三乙胺 作用下， 以 乙腈 为溶剂， 生成 2-(2-吡啶基)乙基三甲氧基硅烷
  参考文献：
  名称：

  调整离子纳米粒子网络中的光致发光性质

  摘要：

  为了研究离子纳米粒子网络（INN）的原始和有前途的发光特性，研究了各种材料成分。在这项工作中，用于使二氧化硅纳米颗粒形成网络的连接基发生了变化。提出了许多取代或未取代的咪唑，吡唑和吡啶鎓连接基。在INN杂化材料上进行的光致发光实验表明，在光谱的可见光区域内，很宽的范围内都具有很强的发射带。由于π-π堆积相互作用，使咪唑单元之间的芳族连接基发生变化，导致最大发射峰出现明显的位移，直至100 nm。在芳族单元上引入的取代基的立体位阻和诱导效应，通过修饰咪唑环之间的π-π堆积，也强烈影响了材料的发光性能。小和广角X射线散射（SAXS，WAXS）实验揭示了所获得的结构参数（短程有序参数和杂化材料中芳族单元的距离）与INN材料的发光量子产率之间存在明显的趋势。

  DOI：

  10.1002/chem.201400392
• 作为产物：
  描述：

  2-乙烯基吡啶 在 三氯硅烷 作用下， 以 乙腈 为溶剂， 反应 2.0h， 生成 2-[2-(三氯甲硅烷基)乙基]吡啶
  参考文献：
  名称：

  调整离子纳米粒子网络中的光致发光性质

  摘要：

  为了研究离子纳米粒子网络（INN）的原始和有前途的发光特性，研究了各种材料成分。在这项工作中，用于使二氧化硅纳米颗粒形成网络的连接基发生了变化。提出了许多取代或未取代的咪唑，吡唑和吡啶鎓连接基。在INN杂化材料上进行的光致发光实验表明，在光谱的可见光区域内，很宽的范围内都具有很强的发射带。由于π-π堆积相互作用，使咪唑单元之间的芳族连接基发生变化，导致最大发射峰出现明显的位移，直至100 nm。在芳族单元上引入的取代基的立体位阻和诱导效应，通过修饰咪唑环之间的π-π堆积，也强烈影响了材料的发光性能。小和广角X射线散射（SAXS，WAXS）实验揭示了所获得的结构参数（短程有序参数和杂化材料中芳族单元的距离）与INN材料的发光量子产率之间存在明显的趋势。

  DOI：

  10.1002/chem.201400392

文献信息

• Addition of Trichlorosilane to Styrene, 2 Vinylpyridine, Allylcyanide and Octene-1
  作者：Shun’ichi Nozakura

  DOI：10.1246/bcsj.29.784

  日期：1956.7

  Addition reactions of trichlorosilane to styrene, 2-vinylpyridine, allylcyanide, and octene-1 were attempted in the presence of bases such as pyridine and in the presence of tetrapyridine nickel(II) chloride. The structures of the reaction products were established. In the presence of bases, trichlorosilane was added to 2-vinylpyridine and allylcyanide, yielding 2-β-trichlorosilylethylpyridine and

  在吡啶等碱和四吡啶氯化镍 (II) 存在下，尝试了三氯硅烷与苯乙烯、2-乙烯基吡啶、烯丙基氰化物和辛烯-1 的加成反应。建立了反应产物的结构。在碱存在下，将三氯硅烷加入到 2-乙烯基吡啶和烯丙基氰化物中，分别生成 2-β-三氯甲硅烷基乙基吡啶和 β-三氯甲硅烷基丁腈。另一方面，在四吡啶氯化镍存在下，对所有检测的乙烯基化合物进行添加。(没有尝试2-乙烯基吡啶。)然而，在这种情况下，证明加成产物由两种位置异构体组成，其发生是由于加成方向不同，对于每种起始乙烯基化合物。
• Reaction of the SiCl bond with trialkyl orthoformates preparation of alkoxy-substituted silanes
  作者：U Herzog、N Schulze、K Trommer、G Roewer

  DOI：10.1016/s0022-328x(97)00204-0

  日期：1997.11

  Trialkyl orthoformates in the presence of aluminium chloride represent quite useful reagents to generate silicon alkoxides from chlorosilanes. 3-Cyanopropyltrichlorosilane and 2-[(2-trichlorosily)ethyl]-pyridine give the triethoxy compounds 3-cyanopropyltriethoxysilane and 2-[(2-triethoxysilyl)ethyl]-pyridine respectively. Via this route, in methylchlorooligosilanes a partial or complete exchange of

  在氯化铝存在下的原甲酸三烷基酯代表了非常有用的试剂，可以从氯硅烷生成烷氧基硅。3-氰丙基三氯硅烷和2-[（（2-三氯甲硅烷基）乙基]-吡啶分别得到三乙氧基化合物3-氰基丙基三乙氧基硅烷和2-[（2-三乙氧基甲硅烷基）乙基]-吡啶。通过这种途径，在甲基氯代低聚硅烷中，取决于硅烷∶HC （OR）3的起始摩尔比（RMe，Et），发生氯取代基对烷氧基的部分或完全交换。在形成SiMe（OR）2基之前，SiCl 2 Me基首先与SiClMe（OR）反应。（Si）2 SiClMe单元不受HC（OR）3的影响。
• Silica intercalated crystalline zirconium phosphate-type materials
  申请人：Shell Oil Company

  公开号：US04717513A1

  公开（公告）日：1988-01-05

  The present invention relates to intercalated crystalline zirconium phosphate-types compositions wherein the interlayers of said composition have been intercalated with three-dimensional silicon oxide pillars whereby the pillars comprise at least two silicon atom layers parallel to the clay interlayers.

  本发明涉及插层晶体锆磷酸盐型化合物，其中所述化合物的插层已经插入三维硅氧柱，该柱包含至少两个与粘土插层平行的硅原子层。
• Silica-clay complexes
  申请人：Shell Oil Company

  公开号：US04510257A1

  公开（公告）日：1985-04-09

  The present invention relates to intercalated clay compositions wherein the interlayers of said clay have been intercalated with three-dimensional silicon oxide pillars whereby the pillars comprise at least two silicon atom layers parallel to the clay interlayers. These materials have useful catalytic and adsorbent properties.

  本发明涉及插层粘土组合物，其中所述粘土的插层已插入三维硅氧柱，其中柱包含至少两个平行于粘土插层的硅原子层。这些材料具有有用的催化和吸附性能。
• ORGANIC CHLOROHYDROSILANE AND METHOD FOR PREPARING THEM
  申请人：Jung Il Nam

  公开号：US20120114544A1

  公开（公告）日：2012-05-10

  Provided is an organic chlorohydrosilane, a useful starting material for preparing silicon polymers and a method for preparing the same. More particularly, the present invention enables the synthesis of various novel organic chlorohydrosilanes in high yield by an exchange reaction between an Si—H bond of a chlorosilane which can be obtained in an inexpensive and easy manner and an Si—Cl bond of an another organic chlorosilane using a quaternary organic phosphonium salt compound as a catalyst. Since the catalyst can be recovered after its use and reused, the present invention is very economical and thus effective for mass-producing silicon raw materials.

  提供了一种有机氯硅烷，可用作制备硅聚合物的有用起始物，并提供了一种制备方法。特别地，本发明通过使用四元有机磷盐化合物作为催化剂，使得可以在廉价且易得的氯硅烷的Si-H键和另一种有机氯硅烷的Si-Cl键之间进行交换反应，从而高产率地合成各种新型有机氯硅烷。由于催化剂可以回收并重复使用，因此本发明非常经济实惠，对于大规模生产硅原材料非常有效。