[Au(C6F5)2(PPh2H)2]ClO4 | 323584-70-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Au(C6F5)2(PPh2H)2]ClO4
• CAS: 323584-70-9
• 化学式: C₃₆H₂₂AuF₁₀P₂*ClO₄
• 分子量: 1002.92
• InChiKey: UDPJLTGOSAAFPM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Ag(OTf)(PPh3) 、 [Au(C6F5)2(PPh2H)2]ClO4 、 silver trifluoromethanesulfonate 、 双(三苯基正膦基)氯化铵 在 PPN(acac) 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 以25%的产率得到[(Au(C6F5)2(μ-PPh2)AgPPh3)(μ-PPh3))2(μ-Ag)(μ3-Cl)]
  参考文献：
  名称：

  A Pentanuclear Mixed Gold(III)−Silver(I) Phosphide with an Unusual T-Frame μ₃-Cl Bridge

  摘要：

  The reaction of the mixed gold(III)-silver(I) diphenylphosphide complex [Au(C6F5)(2)(mu-PPh2)(2)Ag](2) (1) with an equimolecular amount of [AgCl(PPh3)(2)] leads to the formal insertion of the latter into 1, affording the pentanuclear derivative [{Au(C6F5)(2){(mu-PPh2)AgPPh3}(mu-PPh2)}(2)(mu-Ag)(mu(3)-Cl)] (2). Surprisingly, complex 2 is also obtained by treatment of [Au(C6F5)(2)(PPh2H)(2)]ClO4 with [Ag(TfO)(PPh3)] (TfO = trifluoromethanesulfonate) and AgTfO (2:2:1) in the presence of PPN(acac) (PPN = [N(PPh3)(2)](+), acac = acetylacetonate) and PPNCl. The crystal structure of 2 has been determined by X-ray diffraction studies, and it displays an unusual, perfectly planar T-frame mu(3)-Cl atom acting as a bridge between the three silver atoms.

  DOI：

  10.1021/om020142x