trans-undec-4-en-2-ol | 122552-37-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: trans-undec-4-en-2-ol
• 英文别名: undec-4-en-2-ol；(E)-undec-4-en-2-ol
• CAS: 122552-37-8
• 化学式: C₁₁H₂₂O
• 分子量: 170.295
• InChiKey: SCTZGEXBCVUJJT-CMDGGOBGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trans-undec-4-en-2-ol 在 sodium 、 三氟乙酸 作用下， 以 氨 为溶剂， 生成 (2S,4R,5R)-5-Benzyl-undecane-2,4-diol
  参考文献：
  名称：

  通过Prins环化和还原性裂解序列立体选择性合成包含抗-1,3-二醇系统的聚酮化合物前体

  摘要：

  描述了一种新的立体选择性合成聚酮化合物前体的方法，该前体包含通过Prins环化和还原性裂解序列侧接有多个烷基分支和官能团的抗-1,3-二醇单元。

  DOI：

  10.1016/j.tetlet.2006.05.015
• 作为产物：
  描述：

  4-diphenylphosphinoylundecane-2,5-diol 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以82%的产率得到trans-undec-4-en-2-ol
  参考文献：
  名称：

  Wallace, Paul; Warren, Stuart, Journal of the Chemical Society. Perkin transactions I, 1988, p. 2971 - 2978

  摘要：

  DOI：

文献信息

• [EN] 3'-KETOGLYCOSIDE COMPOUND FOR THE SLOW RELEASE OF A VOLATILE ALCOHOL<br/>[FR] COMPOSÉ 3'-CÉTOGLYCOSIDE POUR LA LIBÉRATION LENTE D'UN ALCOOL VOLATIL
  申请人：GLYCOSCIENCE S L

  公开号：WO2021160670A1

  公开（公告）日：2021-08-19

  The present invention relates to a 3'-ketoglycoside compound defined by formula (I) and its use for controlled release of alcohols, in particular alcohols showing an insect repellent effect. It relates also to a process for preparing the 3'-ketoglycoside compound of formula (I). It further relates to a composition comprising a 3'- ketoglycoside compound of formula (I). It relates also to the use of a 3'-ketoglycoside compound of formula (I) for the controlled release of alcohols. It related also to a method of use of such composition.

  本发明涉及由式(I)定义的3'-酮基糖苷化合物及其用于控制释放醇，特别是显示驱虫效果的醇。它还涉及制备式(I)的3'-酮基糖苷化合物的方法。此外，它还涉及包含式(I)的3'-酮基糖苷化合物的组合物。它还涉及使用式(I)的3'-酮基糖苷化合物来控制释放醇。它还涉及使用这种组合物的方法。
• CP 2 TiCl 2 -catalyzed hydroalumination of internal alkynes: an access to ( Z )-olefins
  作者：Arnaud Parenty、Jean-Marc Campagne

  DOI：10.1016/s0040-4039(01)02402-9

  日期：2002.2

  The reduction of alkynols with LiAlH4 in diglyme is a long known process leading to the formation of (E)-alkenols. We have, by serendipity, found that, in the presence of a catalytic amount (10%) of Cp2TiCl2. the stereoselectivity of the reaction is reversed, leading to the selective formation of the (Z)-alkenols. The scope and limitations of this methodology and a postulated catalytic cycle are also discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.
• Iodine as a versatile reagent for the Prins-cyclization: an expeditious synthesis of 4-iodotetrahydropyran derivatives
  作者：J.S. Yadav、B.V. Subba Reddy、G.G.K.S. Narayana Kumar、T. Swamy

  DOI：10.1016/j.tetlet.2007.01.076

  日期：2007.3

  Iodine is found to be an efficient reagent for the coupling of homoallylic alcohols with aldehydes under mild conditions to produce 4-iodotetrahydropyran derivatives in excellent yields in a short reaction time with high selectivity. The use of iodine makes this procedure simple, convenient and cost-effective. (c) 2007 Published by Elsevier Ltd.
• WALLACE, PAUL;WARREN, STUART, J. CHEM. SOC. PERKIN TRANS. PT 1,(1988) N1, C. 2971-2978
  作者：WALLACE, PAUL、WARREN, STUART

  DOI：——

  日期：——
• 3'-KETOGLYCOSIDE COMPOUND FOR THE SLOW RELEASE OF A VOLATILE ALCOHOL
  申请人：Glycoscience, S.L.

  公开号：EP4103576A1

  公开（公告）日：2022-12-21