1,1,2,3,3-pentafluoro-3-(2,2,3,3-tetrafluoropropoxy)-1-propene | 1401322-33-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,1,2,3,3-pentafluoro-3-(2,2,3,3-tetrafluoropropoxy)-1-propene
• 英文别名: 1,1,2,3,3-Pentafluoro-3-(2,2,3,3-tetrafluoropropoxy)prop-1-ene；1,1,2,3,3-pentafluoro-3-(2,2,3,3-tetrafluoropropoxy)prop-1-ene
• CAS: 1401322-33-5
• 化学式: C₆H₃F₉O
• 分子量: 262.075
• InChiKey: YXUFTBQXPJKJCN-UHFFFAOYSA-N

物化性质

• 沸点：
  119.7±40.0 °C(Predicted)
• 密度：
  1.483±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,1,2,3,3-pentafluoro-3-(2,2,3,3-tetrafluoropropoxy)-1-propene 、 1,2,3,3,3-五氟-1-(2,2,3,3-四氟丙氧基)-1-丙烯 在 甲烷 氯 作用下， 生成 、
  参考文献：
  名称：

  WO2006/123563

  摘要：

  公开号：
• 作为产物：
  描述：

  六氟丙烯 、 四氟丙醇 在 氢氧化钾 作用下， 以 四乙二醇二甲醚 、 水 为溶剂， 35.0 ℃ 、200.0 kPa 条件下， 以82%的产率得到1,1,1,2,3,3-hexafluoro-3-(2,2,3,3-tetrafluoropropoxy)propane
  参考文献：
  名称：

  WO2006/123563

  摘要：

  公开号：

文献信息

• METHOD FOR PROCESSING FLUORINATED ALKYL ETHER
  申请人：Asahi Glass Company, Limited

  公开号：EP1882680A1

  公开（公告）日：2008-01-30

  To provide a method for producing a high purity fluorinated alkyl ether having a very low content of an impurity having an unsaturated bond at the industrial scale. A method for treating a fluorinated alkyl ether, which comprises bringing a reaction crude liquid containing a fluorinated alkyl ether obtained by reacting a fluorinated alkyl alcohol with a fluoroolefin in the presence of a basic catalyst, and an unsaturated impurity having an unsaturated bond formed as a by-product in the above reaction, into contact with a chlorine gas to convert the unsaturated impurity to a chlorine-added product, thereby to lower the content of the unsaturated impurity.

  提供一种在工业规模上生产高纯度氟化烷基醚的方法，这种醚中具有不饱和键的杂质含量极低。 一种处理氟化烷基醚的方法，包括将含有氟化烷基醇与氟化烯烃在碱性催化剂存在下反应得到的氟化烷基醚和在上述反应中作为副产物形成的具有不饱和键的不饱和杂质的反应粗液与氯气接触，将不饱和杂质转化为添加氯的产品，从而降低不饱和杂质的含量。
• METHOD FOR TREATING FLUORINATED ALKYL ETHER
  申请人：OKAMOTO Hidekazu

  公开号：US20080086019A1

  公开（公告）日：2008-04-10

  To provide a method for producing a high purity fluorinated alkyl ether having a very low content of an impurity having an unsaturated bond at the industrial scale. A method for treating a fluorinated alkyl ether, which comprises bringing a reaction crude liquid containing a fluorinated alkyl ether obtained by reacting a fluorinated alkyl alcohol with a fluoroolefin in the presence of a basic catalyst, and an unsaturated impurity having an unsaturated bond formed as a by-product in the above reaction, into contact with a chlorine gas to convert the unsaturated impurity to a chlorine-added product, thereby to lower the content of the unsaturated impurity.