Described herein is a method to synthesize a perfluorinated allyl ether compound of formula (I) or a perfluorinated allyl amine compound of formula (II) Where Rf 1 and Rf 2 are (i) independently selected from a perfluorinated alkyl group comprising 1-7 carbon atoms, a perfluorinated aryl group comprising a 5- or 6-membered ring, or combinations thereof, and optionally comprising one or more catenated heteroatoms selected from N or O; or (ii) bonded together to form a perfluorinated ring structure having 4-8 ring carbon atoms, optionally comprising at least one catenated O or N atom; and Rf 3 is a perfluorinated alkyl group comprising 1-3 carbon atoms. The resulting perfluorinated allyl ether compounds disclosed herein may be used in polymer synthesis.
本文描述了一种合成化合物的方法,该化合物为式(I)的
全氟烯基醚化合物或式(II)的
全氟烯基胺化合物,其中Rf1和Rf2分别为:(i)独立选择自
全氟烷基组分,包括1-7个碳原子的,或
全氟芳基组分,包括5-或6-元环,或两者的组合,并可选地包含一个或多个被链状杂原子所选的N或O;或(ii)结合在一起形成一个含有4-8个环碳原子的
全氟环结构,可选地包含至少一个链状O或N原子;Rf3是一个含有1-3个碳原子的
全氟烷基组分。本文所披露的结果为
全氟烯基醚化合物可用于聚合物的合成。