1-(1-cyclopentylethyl)-4-methoxybenzene | 1221406-64-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(1-cyclopentylethyl)-4-methoxybenzene
• CAS: 1221406-64-9
• 化学式: C₁₄H₂₀O
• 分子量: 204.312
• InChiKey: PEBSZOQKUUESHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.99
• 重原子数：
  15.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  1-(1-cyclopentylvinyl)-4-methoxybenzene 在 rac-dihexyl 3-pentylcyclohexa-1,4-diene-1,2-dicarboxylate 、 三苯碳四(五氟苯基)硼酸盐 作用下， 以 甲苯 为溶剂， 生成 1-(1-cyclopentylethyl)-4-methoxybenzene
  参考文献：
  名称：

  采用基于环己二烯的手性氢化物源区分结构无偏碳正离子的对映体面

  摘要：

  基于手性环己二烯的二氢替代物可以区分苄基碳正离子的对映体面（参见方案）。不需要共价相互作用，而是通过计算验证色散控制面部辨别。

  DOI：

  10.1002/anie.202305295

文献信息

• Bisoxazoline-pincer ligated cobalt-catalyzed hydrogenation of alkenes
  作者：Mikhaila D. Ritz、Astrid M. Parsons、Philip N. Palermo、William D. Jones

  DOI：10.1016/j.poly.2020.114416

  日期：2020.4

  The efficient and atom economical hydrogenation of alkenes using a novel bisoxazoline ligated cobalt complex has been developed. The hydrogenation of a variety of alkenes containing electron neutral and electron-donating groups proceeds in high yield, while electron-withdrawing and sterically hindered groups are not tolerated. Heterocycles and internal alkenes were also hydrogenated in moderate to high yields. While the catalyst is enantiopure, no enantioinduction was observed suggesting that other factors are involved in achieving enantiocontrol. (C) 2020 Elsevier Ltd. All rights reserved.
• Intermolecular Dehydrative Coupling Reaction of Aryl Ketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium−Hydride Complex: A Novel Ketone Olefination Method via Vinyl C−H Bond Activation
  作者：Chae S. Yi、Do W. Lee

  DOI：10.1021/om100051h

  日期：2010.4.26

  The cationic ruthenium hydride complex[(eta(6)-C(6)H(6))-(PCy(3))(CO)RuH](+)BF(4)(-) was found to be a highly effective catalyst for the intermolecular olefination reaction of aryl ketones with cycloalkenes. The preliminary mechanistic analysis revealed that an electrophilic ruthenium vinyl complex is the key species fir mediating both vinyl C-H bond activation and the dehydrative olefination steps of the coupling reaction.