methyldinonylsilane | 17591-37-6

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: methyldinonylsilane
• 英文别名: Dinonylmethylsilan；Methyldinonylsilan
• CAS: 17591-37-6
• 化学式: C₁₉H₄₂Si
• 分子量: 298.628
• InChiKey: YPBXRWNUHILERX-UHFFFAOYSA-N

物化性质

• 沸点：
  350.8±11.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.34
• 重原子数：
  20.0
• 可旋转键数：
  16.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  methyldinonylsilane 在 四氯化碳 、 palladium dichloride 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 methyldinonylsilylacetylene
  参考文献：
  名称：

  Trialkylsilylethynyl-substituted triphenylenes and hexabenzocoronenes: highly soluble liquid crystalline materials and their hole transport abilities

  摘要：

  Four triphenylene (TP) and four hexa-peri-hexabenzocoronene (HBC) derivatives with trialkylsilylethynyl groups were prepared and characterized by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction measurements. All compounds were highly soluble in less-polar organic solvents and exhibited a columnar phase, Col(h) or Col(r) for the TPs, and Col(h) for the HBCs. The hole transport ability in the HBCs' columnar phase, 0.4-1.5x10(-3) cm(2) V-1 s(-1) at 40-180 degrees C, and its temperature dependence were determined by the time-of-flight method using a solution technique. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.05.071
• 作为产物：
  描述：

  甲基二氯硅烷 、 1-溴壬烷 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 3.5h， 以86.1%的产率得到methyldinonylsilane
  参考文献：
  名称：

  Trialkylsilylethynyl-substituted triphenylenes and hexabenzocoronenes: highly soluble liquid crystalline materials and their hole transport abilities

  摘要：

  Four triphenylene (TP) and four hexa-peri-hexabenzocoronene (HBC) derivatives with trialkylsilylethynyl groups were prepared and characterized by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction measurements. All compounds were highly soluble in less-polar organic solvents and exhibited a columnar phase, Col(h) or Col(r) for the TPs, and Col(h) for the HBCs. The hole transport ability in the HBCs' columnar phase, 0.4-1.5x10(-3) cm(2) V-1 s(-1) at 40-180 degrees C, and its temperature dependence were determined by the time-of-flight method using a solution technique. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.05.071

文献信息

• Synthesis of triorganylchlorosilanes by catalytic reaction of triorganylsilanes with chlorobenzene
  作者：Yu. I. Khudobin、N. A. Andreeva、N. P. Kharitonov、M. G. Voronkov

  DOI：10.1007/bf00923508

  日期：1974.4
• Nitrogen-containing organosilicon compounds VI. Synthesis and antimicrobial action of trialkyl(3-aminopropyl)silanes
  作者：E. Lukevits、A. Ya. Zile、L. V. Kruzmetra、Yu. I. Khudobin、M. G. Voronkov

  DOI：10.1007/bf01145655

  日期：1975.1
• LUKEVITS EH.; GRANIN E. F.; CHARUJSKAYA L. P.; SOKOLOVA N. K.; ERCHAK N. +, LATVRSR ZINATNU AKAD. VESTIS. KIM. SER., IZV. AN LATVSSR. CEP. XIM., 1978+
  作者：LUKEVITS EH.、 GRANIN E. F.、 CHARUJSKAYA L. P.、 SOKOLOVA N. K.、 ERCHAK N. +

  DOI：——

  日期：——