isopropenyl acetoacetate | 93304-66-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 酮酸及其衍生物
• 英文名称: isopropenyl acetoacetate
• 英文别名: acetoacetic acid isopropenyl ester；Acetessigsaeure-isopropenylester；Prop-1-en-2-yl 3-oxobutanoate
• CAS: 93304-66-6
• 化学式: C₇H₁₀O₃
• 分子量: 142.155
• InChiKey: DYXMYVMKZYLWIX-UHFFFAOYSA-N

物化性质

• 沸点：
  77 °C(Press: 4 Torr)
• 密度：
  1.0769 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  isopropenyl acetoacetate 在 丙酮 作用下， 以 xylene 为溶剂， 反应 1.0h， 以100%的产率得到2,2,6-三甲基-4H-1,3-二英-4-酮
  参考文献：
  名称：

  Kinetic and spectroscopic studies on the thermal decomposition of 2,2,6-trimethyl-4H-1,3-dioxin-4-one. Generation of acetylketene

  摘要：

  DOI：

  10.1021/ja00188a037
• 作为产物：
  描述：

  2-甲基-5-降冰片烯-2-基内-乙酰乙酸酯 生成 isopropenyl acetoacetate
  参考文献：
  名称：

  HYATT, J. A., J. ORG. CHEM., 1984, 49, N 26, 5102-5105

  摘要：

  DOI：

文献信息

• Reactive oligomers
  申请人：3M Innovative Properties Company

  公开号：US20030212210A1

  公开（公告）日：2003-11-13

  The present invention provides melt-processible adhesive compositions prepared from a first oligomer containing reactive functional groups capable of reaction at effective rates (at normal processing temperatures) with a co-reactive second component oligomer possessing functionality that is complementary to that of the first oligomer. The compositions may be used as coatings, including hard surface coatings, clear coatings, powder coatings and pattern coatings; as adhesives, including pressure sensitive adhesives and hot melt adhesives; as sealants; as optical coatings; as blown microfibers (BMF); as high refractive index optical materials; as barrier films; in microreplication; as low adhesion backsizes, (LABs) and as release coatings.

  本发明提供了可熔性粘合剂组合物，该组合物由第一低聚物制备而成，该低聚物含有反应性功能基团，能够在正常加工温度下与具有与第一低聚物相补充的功能性的共反应第二组分低聚物以有效速率发生反应。该组合物可用作涂层，包括硬表面涂层、透明涂层、粉末涂层和图案涂层；作为粘合剂，包括压敏粘合剂和热熔粘合剂；作为密封剂；作为光学涂层；作为吹塑微纤维（BMF）；作为高折射率光学材料；作为障碍膜；在微复制中使用；作为低粘附背面（LABs）和作为脱模涂层。
• Pressure sensitive adhesives possessing high load bearing capability
  申请人：3M Innovative Properties Company

  公开号：US20020132927A1

  公开（公告）日：2002-09-19

  Pressure sensitive adhesives are provided which possess high load bearing capabilities at elevated temperatures. The adhesives are prepared by polymerization of a syrup polymer composition having a first solute polymer having reactive, pendant functional groups, a second component having co-reactive functional groups, and a monomer mixture. The syrup polymer contains reactive electrophilic or nucleophilic functional groups that can subsequently crosslink by reaction with a second component having co-reactive functional groups.

  提供了具有高承载能力的压敏粘合剂，在高温下使用。该粘合剂是通过聚合糖浆聚合物组成物制备而成，其中第一溶质聚合物具有反应性的、悬挂的功能基团，第二组分具有共同反应的功能基团，以及单体混合物。糖浆聚合物含有反应性亲电性或亲核性功能基团，可以随后通过与具有共同反应功能基团的第二组分反应交联。
• Hardenable self-supporting structures and methods
  申请人：3M Innovative Properties Co.

  公开号：EP2272485A2

  公开（公告）日：2011-01-12

  The present invention relates to a preformed dental product comprising a hardenable composition, wherein the hardenable composition comprises a resin system, a filler system, and an initiator system; wherein the hardenable composition is in the form of a hardenable, self-supporting structure having a first shape and sufficient malleability to be reformed into a second shape at a temperature of about 15°C to 38°C.

  本发明涉及一种由可硬化组合物组成的预成型牙科产品，其中可硬化组合物包括树脂系统、填料系统和引发剂系统； 其中，可硬化组合物为可硬化的自支撑结构形式，具有第一种形状和足够的延展性，可在约 15°C 至 38°C 的温度下重塑为第二种形状。
• Oligomeric dyes and use thereof
  申请人：3M Innovative Properties Company

  公开号：US20040059044A1

  公开（公告）日：2004-03-25

  The invention provides a method for preparing an oligomeric dye by reacting a first component oligomer, having a carbon-carbon backbone, comprising a plurality of polymerized monomer units comprising pendant reactive nucleophilic or electrophilic functional groups; and a dye component having a co-reactive functional group. These oligomeric dyes are suitable for use as additives to impart coloration or fluorescence to thermoplastic polymers, particularly olefinic polymers. The oligomeric dyes of the present invention advantageously are compatible in polymers where conventional dyes often have poor compatibility or solubility.

  本发明提供了一种制备低聚染料的方法，该方法通过使具有碳-碳骨架的第一组分低聚物与具有共反应官能团的染料组分发生反应来制备低聚染料，第一组分低聚物由多个聚合单体单元组成，单体单元含有悬垂反应性亲核或亲电官能团。这些低聚染料适合用作添加剂，以赋予热塑性聚合物，特别是烯烃聚合物着色或荧光。本发明的低聚染料在聚合物中具有良好的相容性，而传统染料通常在聚合物中的相容性或溶解性较差。
• Oligomeric dyes and preparation thereof
  申请人：3M Innovative Properties Company

  公开号：US20040063848A1

  公开（公告）日：2004-04-01

  The invention provides a method for preparing an oligomeric dye by reacting a first component oligomer, having a carbon-carbon backbone, comprising a plurality of polymerized monomer units comprising pendant reactive nucleophilic or electrophilic functional groups; and a dye component having a co-reactive functional group. These oligomeric dyes are suitable for use as additives to impart coloration or fluorescence to thermoplastic polymers, particularly olefinic polymers. The oligomeric dyes of the present invention advantageously are compatible in polymers where conventional dyes often have poor compatibility or solubility.

  本发明提供了一种制备低聚染料的方法，该方法通过使具有碳-碳骨架的第一组分低聚物与具有共反应官能团的染料组分发生反应来制备低聚染料，第一组分低聚物由多个聚合单体单元组成，单体单元含有悬垂反应性亲核或亲电官能团。 这些低聚染料适合用作添加剂，以赋予热塑性聚合物，特别是烯烃聚合物着色或荧光。本发明的低聚染料在聚合物中具有良好的相容性，而传统染料通常在聚合物中的相容性或溶解性较差。