1H,1H-perfluorohexyl acrylate | 376-56-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1H,1H-perfluorohexyl acrylate
• 英文别名: acrylic acid-(1H,1H-undecafluoro-hexyl ester)；1-Acryloyloxy-1H,1H-undecafluor-hexan；Acrylsaeure-(1H,1H-undecafluor-hexylester)；2,2,3,3,4,4,5,5,6,6,6-Undecafluorohexyl prop-2-enoate
• CAS: 376-56-7
• 化学式: C₉H₅F₁₁O₂
• 分子量: 354.12
• InChiKey: JFDAGRQBXXAVSD-UHFFFAOYSA-N

物化性质

• 沸点：
  62 °C(Press: 20 Torr)
• 密度：
  1.540 g/cm3(Temp: 30 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  十一氟正己烷-1-醇 、 丙烯酰氯 在 喹啉 、 硝基苯 作用下， 生成 1H,1H-perfluorohexyl acrylate
  参考文献：
  名称：

  含氟聚合物。二、1、1-二氢全氟烷基丙烯酸酯：单体的制备1

  摘要：

  已经合成了七种 n-1,1-二氢全氟烷醇的丙烯酸酯。酯是： 1,1-二氢全氟乙基-；1,1-二氢全氟丙基-；1,1-二氢全氟丁基-；1,1-二氢全氟戊基-；1,1-二氢全氟己基-；1,1-二氢全氟辛基-；和 1,1-二氢全氟癸基丙烯酸酯。由于这些醇类难以使用常规方法酯化，因此在这项工作中使用了丙烯酰氯或丙烯酸加全氟乙酸酐。

  DOI：

  10.1002/pol.1955.120158018

文献信息

• Synthesis of Fluorinated Polymers and Evaluation of Wettability
  作者：Tamami Kimura、Maria Kasuya、Kenichi Hatanaka、Koji Matsuoka

  DOI：10.3390/molecules21030358

  日期：——

  Two kinds of fluorinated polymers were synthesized: an acrylate polymer having a fluorinated triethylene glycol as a pendant group (2a) and a fluoroalkyl acrylate polymer (2b). The contact angle of these fluorinated polymers against water, non-fluorinated alcohols and fluorinated alcohols were evaluated. As compared with the fluoroalkyl polymer (2b), fluoroethylene glycol polymer (2a) showed smaller

  合成了两种氟化聚合物：具有氟化三甘醇作为侧基的丙烯酸酯聚合物(2a)和丙烯酸氟烷基酯聚合物(2b)。评估了这些氟化聚合物对水、非氟化醇和氟化醇的接触角。与氟烷基聚合物(2b)相比，氟乙二醇聚合物(2a)对水和非氟化醇的接触角较小。这支持了这样的主张：将烷基链改变为乙二醇型链会在醚氧和水或非氟化醇之间产生一些相互作用。此外，丙烯酸氟烷基酯聚合物(2b)显示出非常低的临界表面张力值。
• Fluorine-containing graft copolymer and adhesive and composite membrane made thereof
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0183989A2

  公开（公告）日：1986-06-11

  A graft copolymer consisting essentially of a main chain polymer having a glass transition temperature (Tg) of at least 30°C and a graft chain fluorine-containing polymer having a repeating unit of the formula: wherein R1 is a hydrogen atom or a lower alkyl group, and R2 is a polyfluoroalkyl group.

  一种接枝共聚物，主要由玻璃化转变温度（Tg）至少为 30°C 的主链聚合物和具有以下重复单元的接枝链含氟聚合物组成： 其中 R1 为氢原子或低级烷基，R2 为多氟烷基。
• Graft copolymers containing polydiorganosiloxane and polybutylene grafts
  申请人：DOW CORNING CORPORATION

  公开号：EP1013682A1

  公开（公告）日：2000-06-28

  Graft copolymers containing polydiorganosiloxane and polybutylene grafts are disclosed. More particularly, this invention provides a graft copolymer having a backbone and two or more polymeric side chains, the copolymer formed from the copolymerization of at least one acryloxyalkyl-functional polydiorganosiloxane macromonomer, at least one acryl-terminated, carboxyl-functional polybutylene macromonomer and at least one ethylenically unsaturated monomer which is copolymerizable with the polydiorganosiloxane and polybutylene macromonomers. A method of making graft copolymers containing polydiorganosiloxane and polybutylene grafts is also disclosed herein.

  本发明公开了含有聚二有机硅氧烷和聚丁烯接枝的接枝共聚物。更具体地说，本发明提供了一种接枝共聚物，它具有一条主链和两条或两条以上的聚合物侧链，该共聚物由至少一种丙烯酰氧基官能团聚二甘硅氧烷大单体、至少一种丙烯酰基封端、羧基官能团聚丁烯大单体和至少一种可与聚二甘硅氧烷和聚丁烯大单体共聚的乙烯基不饱和单体共聚而成。本文还公开了一种制造含有聚二有机硅氧烷和聚丁烯接枝的接枝共聚物的方法。
• FLUORORESIN FILM AND FLUORORESIN-LAMINATED ACRYLIC RESIN FILM
  申请人：Kaneka Corporation

  公开号：EP2292692A1

  公开（公告）日：2011-03-09

  An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component; and a fuororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型单层和多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和耐污性，例如耐乳酸性和耐晒性。本发明涉及一种由(C)氟树脂形成的氟树脂薄膜，该氟树脂包含(B)含氟(甲基)丙烯酸烷基酯聚合物成分的含氟(甲基)丙烯酸树脂；以及一种氟树脂层压丙烯酸树脂薄膜，其中氟树脂薄膜层层压在包含(A)丙烯酸树脂的薄膜层的至少一个面上。
• Fluororesin-laminated acrylic resin film
  申请人：KANEKA CORPORATION

  公开号：EP2325005A2

  公开（公告）日：2011-05-25

  An object of the present invention is to provide a novel multilayer film that can be employed also for use in interior and exterior members of vehicles, and that has excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin-laminated acrylic resin film, wherein a fluororesin film layer comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和抗污性，例如抗乳酸和抗防晒性。本发明涉及一种氟树脂层压丙烯酸树脂薄膜，其中，在由丙烯酸树脂（A）组成的薄膜层的至少一个面上，层压了由含有含氟烷基（甲基）丙烯酸酯聚合物成分的氟化（甲基）丙烯酸树脂（B）组成的氟树脂薄膜层。